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Formation and catalytic properties of water-soluble phosphine complexes

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Abstract

Using sulfonated triphenylphosphine, a number of water-soluble platinum metal — phosphine complexes were prepared. Some of them show a pronounced reactivity towards small molecules and the ruthenium compound catalyzes the hydrogenation of ketocarboxylic acids.

Abstract

Используя сульфонированный трифенилфосфин, были приготовлены несколяко водорастворимых комплексов между металлической платиной и фосфином. Некоторые из них обладают явной реакционностью по отношению к малым молекулам. Соединения рутения катализируют гидрирование кетокарбоксильных кислот.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Kossuth Lajos University, H 4010, Debrecen

    F. Joó & M. T. Beck

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  1. F. Joó
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  2. M. T. Beck
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Joó, F., Beck, M.T. Formation and catalytic properties of water-soluble phosphine complexes. React Kinet Catal Lett 2, 257–263 (1975). https://doi.org/10.1007/BF02068199

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  • DOI: https://doi.org/10.1007/BF02068199

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