Abstract
Calculating caloric properties from a thermal equation of state requires information such as isobaric heat capacities in the ideal-gas state as a function of temperature. In this work, values for the parameters of thec 0p correlation proposed by Aly and Lee were newly determined for 21 pure gases which are compounds of natural gas mixtures. The values of the parameters were adjusted to selectedc 0p data calculated from spectroscopic data for temperatures ranging from 10 to 1000 K. The data sources used are discussed and compared with literature data deduced from theoretic models and caloric measurements. The parameters presented will be applied in a current GERG project for evaluating equations of state (e.g., the AGA 8 equation) for their suitability for calculating caloric properties.
Similar content being viewed by others
References
A. P. Laughton and A. E. Humphreys,Improvements in the Formulation of Ideal Gas Thermodynamic Properties for Natural Gas Applications, Proc. 4th IGRC, Tokyo, 1989 (Government Institutes Inc., Rockville, MD, 1990), pp. 1769–1778.
J. L. Savidge and J. J. S. Shen,Sound Speed of Natural Gas, Proc. 4th IGRC, Tokyo, 1989 (Government Institutes Inc., Rockville, MD, 1990), pp. 511–519.
F. A. Aly and L. L. Lee,Fluid Phase Equil. 6:169 (1981).
K. E. Starling and J. L. Savidge,Compressibility Factors of Natural Gas and Other Related Hydrocarbon Gases [American Gas Association (AGA) Transmission Measurement Committee Report No. 8, 2nd ed., 1992).
R. S. McDowell and F. H. Kruse,J. Chem. Eng. Data 8:547 (1963).
J. Hilsenrath, C. W. Beckett, W. C. Benedict, L. Fano, H. J. Hodge, I. F. Masi, R. L. Nutall, Y. S. Touloukian, and H. W. Woolley, Tables of thermal properties of gases.NBS Circ. 564:473 (1955).
J. Chao, personal communication to R. Span (Ruhr-UniversitÄt, Bochum).
J. Chao, R. C. Wilhoit, and B. J. Zwolinski,J. Phys. Chem. Ref. Data 2:427 (1973).
S. S. Chen, R. C. Wilhoit, and B. J. Zwolinski,J. Phys. Chem. Ref. Data 4:859 (1975).
TRC,Thermodynamic Tables (Thermodynamic Research Center, Texas A&M University, College Station, 1972–1993).
K. SchÄfer and W. Auer,Values for the Thermodynamic Functions at Standard Pressures as a Function of Temperature for Selected Substances (Werte der thermodynamischen Funktionen bei Standarddrücken in AbhÄngigkeit von der Temperatur für ausgewÄhlte Stoffe) (Springer, Berlin, 1961).
H. D. Baehr, H. Hartmann, H. C. Pohl, and H. SchomÄcker,Thermodynamic Functions of Ideal Gases for Temperatures up to 6000 K (Thermodynamische Funktionen idealer Gase für Temperaturen bis 6000 K) (Springer, Berlin, 1968).
H. W. Woolley, inWater and Steam, Their Properties and Current Industrial Applications (Pergamon, Elmsford, NY, 1980), pp. 166–175.
H. W. Woolley,J. Res. NBS 92:35 (1987).
JANAF,Thermodynamic Tables (3rd. ed.), M. W. Chase, J. L. Curnutt, J. R. Downey, R. A. McDonald, A. N. Syverud, and E. A. Valenzuela,J. Phys. Chem. Ref. Data 14:Suppl. 1 (1985).
W. Lemming,Experimental Determination of Acoustic and Thermal Virial Coefficients for Working Fluids in Chemical Engineering (Experimentelle Bestimmung akustischer und thermischer Virialkoffizienten von Arbeitsstoffen der Energietechnik) (VDI Fortschritt-Berichte, Reihe 19, Nr. 32, VDI-Verlag, Düsseldorf, 1989).
J. P. M. Trusler and M. Zarari,J. Chem. Thermodyn. 24:973 (1992).
M. B. Ewing and A. R. H. Goodwin,J. Chem. Thermodyn. 24:1257 (1992).
W. Beckermann,Speed of Sound Measurements on Working Fluids in Chemical Engineering (Messung der Schallgeschwindigkeiten an Arbeitsstoffen der Energietechnik) (VDI-Fortschritt-Berichte, Reihe 19, Nr. 67, VDI-Verlag, Düsseldorf, 1993).
J. A. Goff and S. Gratch,Trans. ASME 72:741 (1950)
H. W. Woolley, personal communication to V. V. Sychev, A. A. Vasserman, A. D. Kozlov, G. A. Spiridonov, and V. A. Tsymarny,Thermodynamic Properties of Nitrogen (Springer, Berlin, 1970).
L. V. Gurvich,Thermodynamic Properties of Characteristic Substances, Vol. II, Part 2 (Nauka, Moscow, 1979).
J. P. M. Trusler,Physica A 184:415 (1992).
H. W. Woolley,J. Res. NBS 52:289 (1954).
J. F. Masi and B. Petkof,J. Res. NBS 48:179 (1952).
G. Ernst, G. Maurer, and E. Wiederuh,J. Chem. Thermodyn. 21:53 (1989).
W. Lemming, personal communication to R. Span (Ruhr-UniversitÄt, Bochum, 1989).
K. M. Pamidimukkala, D. Rogers, and G. B. Skinner,J. Phys. Chem. Ref. Data 11:83 (1982).
G. B. Kistiakowsky and W. W. Rice,J. Chem. Phys. 8:610 (1940).
B. P. Daily and W. A. Felsing,J. Am. Chem. Soc. 65:42 (1943).
G. Ernst and U. E. Hochberg,J. Chem. Thermodyn. 21:407 (1989).
G. B. Kistiakowsky, J. R. Lacher, and W. W. Ransom,J. Chem. Phys. 8:970 (1940).
G. B. Kistiakowsky and W. W. Rice,J. Chem. Phys. 8:610 (1940).
G. Ernst and J. Büsser,J. Chem. Thermodyn. 2:787 (1970).
M. B. Ewing, A. R. H. Goodwin, M. L. McGlashan, and J. P. M. Trusler,J. Chem. Thermodyn. 21:867 (1989).
S. O. Colgate, C. F. Sona, K. Reed, and A. Sivaraman,J. Chem. Eng. Data 4:859 (1990).
P. F. Wacker, R. K. Cheney, and R. B. Scott,J. Res. NBS 38:651 (1947).
D. W. Scott,J. Chem. Phys. 60:3144 (1974).
M. B. Ewing, A. R. H. Goodwin, and J. P. M. Trusler,J. Chem. Thermodyn. 21:867 (1989).
H. Zeise,Thermodynamic, Vol. II, Part 1, Tables (Thermodynamik, Bd. III/1, Tabellen) (Hirzel, Leipzig, 1954).
P. Schley,Development of Correlations for the Isobaric Heat Capacity in the State of the Ideal-Gas (Entwicklung von Korrelationsgleichungen für die isobare WÄrmekapazitÄt im Zustand des idealen Gases) (Diplomarbeit, Ruhr-UniversitÄt, Bochum, 1994).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Jaeschke, M., Schley, P. Ideal-gas thermodynamic properties for natural-gas applications. Int J Thermophys 16, 1381–1392 (1995). https://doi.org/10.1007/BF02083547
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02083547