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Hydroxylapatite synthesis and characterization in dense polycrystalline form

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Abstract

A new process is described for preparing dense, polycrystalline hydroxylapatite. This material has close to theoretical density and is free of fine pores and second phases. The best material has an average compressive strength of 917 MN m−2 (133×103 psi), and polished samples have an average tensile strength of 196 MN m−2 (28.4×103 psi). The material is highly translucent, and the degree of translucence depends upon processing conditions. The relationship between processing variables and microstructure, strength, and translucence is described. This dense hydroxylapatite has good promise for bone implants and dental applications.

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References

  1. E. B. Nery, K. L. Lynch, W. M. Hirthe andK. H. Mueller,J. Periodontol. 46 (1975) 328.

    CAS  Google Scholar 

  2. M. Jarcho, K. I. Gumaer, J. F. Kay andR. H. Doremus, to be published.

  3. E. A. Monroe, W. Votava, D. B. Bass andJ. Mcmullers,J. Dent. Res. 50 (1971) 860.

    CAS  Google Scholar 

  4. W. R. Rao andR. F. Boehm,ibid 53 (1974) 1351.

    CAS  Google Scholar 

  5. W. Hubbard, Ph. D. thesis, Marquette University (1974).

  6. D. M. Roy andS. K. Linnehan,Nature 247 (1974) 221.

    Article  Google Scholar 

  7. M. Jarcho, U.S. and Foreign Patent Applications filed.

  8. M. D. Francis, J. A. Gray andW. J. Griebstein,Adc. Oral Biol. 3 (1968) 83.

    CAS  Google Scholar 

  9. J. E. Hilliard,Metal Prog. May (1964) 99.

  10. J. E. Hilliard andJ. W. Cahn, “Evalutation of Procedures in Quantitative Mettalography for Volume Fraction Analysis”,Trans. Met. Soc. AIME 221 (1961) 344.

    CAS  Google Scholar 

  11. M. B. Thomas andR. H. Doremus,J. Amer. Ceram. Soc. 56 (1976) 229.

    Article  Google Scholar 

  12. J. Bobick, M. S. Thesis, Rensselaer Polytechnic Institute, Troy, New York (1976).

    Google Scholar 

  13. J. Murphy andJ. Riley,Anal. Chem. Acta. 27 (1962) 31.

    Article  CAS  Google Scholar 

  14. E. Hayck andH. Newesely,Inorg. Synthesis 7 (1963) 63.

    Google Scholar 

  15. B. D. Cullity, “Elements of X-ray Diffraction” (Addison-Wesley, Reading, Mass, 1967) p. 388.

    Google Scholar 

  16. E. D. Eanes, J. H. Gillessen andA. L. Posner,Nature 208 (1965) 365.

    CAS  Google Scholar 

  17. T. R. N. Kutty,Ind. J. Chem. 11 (1973) 695.

    CAS  Google Scholar 

  18. P. Kubelka andF. Munk,Z. Tech. Physik. 12 1931) 593.

    Google Scholar 

  19. G. Kortum, “Reflectance Spectroscopy” (Springer-Verlag, New York, 1969) p. 103.

    Google Scholar 

  20. G. H. Nancollas andB. Tomazic,J. Phys. Chem. 78 (1974) 2218.

    Article  CAS  Google Scholar 

  21. A. S. Posner andF. Betts,Accounts Chem. Res. 8 (1975) 273.

    Article  CAS  Google Scholar 

  22. J. A. S. Bett, L. G. Chrisner andW. K. Hall,J. Amer. Chem. Soc. 89 (1967) 5535.

    Article  CAS  Google Scholar 

  23. E. D. Eanes,Calc. Tiss. Res. 5 (1970) 123.

    Article  Google Scholar 

  24. R. L. Coble,J. Appl. Phys. 32 (1961) 787.

    Article  CAS  Google Scholar 

  25. K. W. Lay, in “Materials Research”, Vol. 6 edited byG. C. Kuczynski (Plenum, New York, 1972) p. 65.

    Google Scholar 

  26. D. Kingery, “Introduction to Cermaics” (Wiley, New York, 1960) p. 232.

    Google Scholar 

  27. J. E. Burke, andJ. H. Rosolowski, General Electrical Technical Information Series, Report No. 73CRD268, 1973.

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Jarcho, M., Bolen, C.H., Thomas, M.B. et al. Hydroxylapatite synthesis and characterization in dense polycrystalline form. J Mater Sci 11, 2027–2035 (1976). https://doi.org/10.1007/BF02403350

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