Skip to main content
SpringerLink
Log in

Reactions of α-elimination of silanones as a path for formation and destruction of siloxane structures

  • Reviews
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Based on modern stereoelectronic concepts, our results, and published data, we explained the paths of formation and destruction of linear and cyclic oligo- and polysiloxanesvia intramolecular geminal decomposition of Si(OR)X groups, which results in the intermediate formation of short-lived silanones R2Si=0. The latter are subsequently oligomerized, polymerized, or inserted into the Si−X bonds (X=0, Cl,etc.) of the trapping agents.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. G. Voronkov, V. P. Mileshkevich, and Yu. A. Yuzhelevskii,The Siloxane Bond, Consultants Bureau, New York-London, 1978, 493 pp.

    Google Scholar 

  2. K. A. Andrianov,Khimiya Kremniiorganicheskikh soedinenii [Chemistry of Organosilicon Compounds], Goskhimizdat, Moscow, 1955, 520 pp. (in Russian).

    Google Scholar 

  3. N. N. Sokolov,Metody sinteza poliorganosiloksanov [Methods for Synthesis of Polyorganosiloxanes], Gosenergoizdat, Moscow-Leningrad, 1959, 197 pp. (in Russian).

    Google Scholar 

  4. T. C. Kendrick, B. Parbhoo, and J. W. White,The Chemistry of Organosilicon Compounds, Eds. S. Patai and Z. Rappoport, J. Wiley, Cambridge, 1989, 1289.

    Chapter  Google Scholar 

  5. M. G. Voronkov and N. G. Sviridova,Usp. Khim., 1971,40, 1761 [Russ. Chem. Rev., 1971,40 (Engl. Transl.)].

    CAS  Google Scholar 

  6. M. G. Voronkov, Yu. A. Turkin, R. G. Mirskov, E. E. Kuz'mina, and V. I. Rakhlin,Zh. Obshch. Khim., 1989,59, 611 [J. Gen. Chem. USSR, 1989,59 (Engl. Transl.)]; Yu. A. Turkin, P. V. Arbuzov, R. G. Mirskov, M. G. Voronkov, and V. I. Rakhlin,Tez dokl. IV Vsesoyuz. konf. “Stroenie i reaktsionnaya sposobnost' kremniiorganicheskikh soedinenii” [Proc. IV All-Union Conf. “Structure and Reactivity of Organosilicon Compounds”], Irkutsk, 1993, 64, 175 (in Russian).

    Google Scholar 

  7. M. G. Voronkov, S. V. Basenko, and M. V. Ustinov,Zh. Obshch. Khim., 1993,63, 2155 [Russ. J. Gen. Chem., 1993,63 (Engl. Transl.)];Dokl. Akad. Nauk, 1993,333, 180 [Dokl. Chem., 1993 (Engl. Transl.)]; S. V. Basenko and M. G. Voronkov,Dokl. Akad. Nauk, 1994,339, 204 [Dokl. Chem., 1993 (Engl. Transl.)].

    CAS  Google Scholar 

  8. S. V. Basenko and M. G. Voronkov,Dokl. Akad. Nauk, 1994,339, 486, [Dokl. Chem., 1994 (Engl. Transl.)].

    CAS  Google Scholar 

  9. Author's Certificate 2058318 RF;Byull. Izobret. [Inventor Bulletin], 1996, 170 (in Russian).

  10. M. G. Voronkov, S. V. Basenko, and M. V. Ustinov,Zh. Obshch. Khim., 1995,65, 1482 [Russ. J. Gen. Chem., 1995,65 (Engl. Transl.)].

    CAS  Google Scholar 

  11. M. G. Voronkov and S. V. Basenko,J. Organomet. Chem., 1995,500, 325.

    Article  CAS  Google Scholar 

  12. M. G. Voronkov, S. V. Basenko, and M. V. Ustinov,21th Sympos. Heteroat. Chemistry, Abstrs., Toyama, 1993, 117; M. G. Voronkov,28th Organosilicon Sympos., Gainsville (USA), 1995, A-21.

  13. M. G. Voronkov and S. V. Basenko,“Andrianovskie chteniya”, Tez. dokl. [Proc. “Andrianov Reading”], Moscow, 1995, 4 (in Russian).

  14. M. G. Voronkov and S. V. Basenko,Tez. dokl. V Vseros. simpoz. “Stroenie and reaktsionnaya sposobnost' kremniiorganicheskikh soedinenii” [Structure and Reactivity of Organosilicon Compounds], Irkutsk, 1996, 45, 78, 79 (in Russian).

  15. M. G. Voronkov, S. V. Basenko, I. A. Gebel, and R. G. Mirskov,XIth Intern. Sympos. on Organosilicon Chemistry, Abstrs., Montpellier (France), 1996, PA 32.

  16. E. I. Dubinskaya, I. P. Tsyrendorzhieva, and M. G. Voronkov,XIth Intern. Sympos. on Organosilicon Chemistry, Abstrs., Montpellier (France), 1996, PC 68, PC 69; E. I. Dubinskaya, I. P. Tsyrendorzhieva, and M. G. Voronkov,Tez. dokl. V Vseros. simpoz. “Stroenie i reaktsionnaya sposobnost'kremniiorganicheskikh soedinenii” [Proc. V All-Russian Sympos. “Structure and Reactivity of Organosilicon Compounds”], Irkutsk, 1996, 44, 47, 97 (in Russian); E. I. Dubinskaya, I. P. Tsyrendorzhieva, A. I. Albanov, and M. G. Voronkov,Xth Intern. Sympos. on Organosilion Chemistry, Abstrs., Montpellier (France), 1996, PC 67; E. I. Dubinskaya, I. P. Tsyrendorzhieva, A. I. Albanov, G. Yu. Tikhii, and M. G. Voronkov,Tez. dokl. V Vseros. simpoz. “Stroenie i reaktsionnaya sposobnost' kremniiorganicheskikh soedinenii” [Proc. V All-Russian Sympos. “Structure and Reactivity of Organosilicon Compounds”], Irkutsk, 1996, 43 (in Russian).

  17. A. V. Golovkin, N. A. Mudrova, T. L. Kracnova, L. V. Serebrenikov, V. S. Nikitin, and E. A. Chernyshev,Zh. Obshch. Khim., 1985,55, 2802 [J. Gen. Chem. USSR, 1985,55 (Engl. Transl.)]; E. A. Chernyshev, T. L. Krasnova, N. A. Mudrova, A. B. Petrunin, and G. N. Turkel'taub,Zh. Obshch. Khim., 1990,60, 1078 [J. Gen. Chem. USSR, 1990,60 (Engl. Transl.)]; E. A. Chernyshev, N. A. Mudrova, T. L. Krasnova, M. G. Kuznetsova, and G. N. Turkel'taub,Zh. Obshch. Khim., 1990,60, 1674 [J. Gen. Chem. USSR, 1990,60 (Engl. Transl.)]; E. A. Chernyshev, N. A. Mudrova, T. L. Krasnova, and A. B. Petrunin,Zh. Obshch. Khim., 1991,61, 916 [J. Gen. Chem. USSR, 1991,61 (Engl. Transl.)].

    CAS  Google Scholar 

  18. E. A. Chernyshev, T. L. Krasnova, N. A. Mudrova, A. V. Golovkin, and M. G. Kuznetsova,Zh. Obshch. Khim., 1987,57, 1725 [J. Gen. Chem. USSR, 1987,57 (Engl. Transl.)].

    CAS  Google Scholar 

  19. E. A. Chernyshev, N. A. Mudrova, T. L. Krasnova, Yu. M. Ushakov, A. B. Petrunin, and M. G. Kuznetsova,Zh. Obshch. Khim., 1992,62, 1308 [Russ. J. Gen. Chem., 1992,62 (Engl. Transl.)].

    CAS  Google Scholar 

  20. T. L. Krasnova, E. A. Chernyshev, and A. P. Sergeev,Izv. Akad. Nauk, Ser. Khim., 1996, 1299 [Russ. Chem. Bull., 1996,45, 1238 (Engl. Transl.)].

    Google Scholar 

  21. E. A. Chernyshev, T. L. Krasnova, A. P. Sergeev, and B. V. Molchanov,Izv. Akad. Nauk, Ser. Khim., 1996, 1577 [Russ. Chem. Bull., 1996,45, 1504 (Engl. Transl.)].

    Google Scholar 

  22. E. A. Chernyshev, T. L. Krasnova, and N. A. Mudrova,Tez. dokl. IV Vsesoyuz. konf. “Stroenie i reaktsionnaya sposobnost' kremniiorganicheskikh soedinenii” [Structure and Reactivity of Organosilicon Compounds], Irkutsk, 1989, 133 (in Russian); E. A. Chermyshev,Xth Intern. Sympos. on Organosilicon Chemistry, Abstrs., Poznan (Poland), 1993, 38; E. A. Chernyshev and T. L. Krasnova,Tez. dokl. I kremniiorganicheskogo mikrosimpoziuma [Proc. I Organosilicon Microsymposium], Moscow-Nizhnii Novgorod, 1994, 12, 13 (in Russian); E. A. Chernyshev and T. L. Krasnova,“Andrianovskie chteniya” Tez. dokl. [Proc. “Andrianov Reading”], Moscow, 1995, 15 (in Russian).

  23. K. A. Andrianov and N. N. Sokolov,Dolk. Akad. Nauk SSSR [Dokl. Chem. USSR], 1952,82, 909 (in Russian).

    CAS  Google Scholar 

  24. M. Kumada and H. Hattori,J. Inst. Polytech. Osaka City Univ., Ser. C,3, 77.

  25. US Pat 2 534 149;Chem. Abstrs., 1951,45, 4739.

    Google Scholar 

  26. A. M. Samsoniya,Uch. Zap. LGU [Scientific Notes of Leningrad State University], 1939,40, 51, (in Russian).

    Google Scholar 

  27. P. A. McCusker and T. Ostdick,J. Am. Chem. Soc., 1958,80, 1103.

    Article  CAS  Google Scholar 

  28. P. A. McCusker and T. Ostdick,J. Am. Chem. Soc., 1959,81, 5550.

    Article  CAS  Google Scholar 

  29. M. G. Voronkov, V. P. Davydova, and A. N. Lazarev,Zh. Obshch. Khim., 1958,28, 2128 [J. Gen. Chem. USSR, 1958,28 (Engl. Transl.)].

    CAS  Google Scholar 

  30. K. A. Andrianov, A. A. Zhdanov, and S. A. Pavlov,Dokl. Akad. Nauk SSSR [Dokl. Chem. USSR], 1955,102, 85 (in Russian).

    CAS  Google Scholar 

  31. M. G. Voronkov, N. G. Sviridova, I. B. Klemenko, N. G. Shchikunov, and V. A. Churmaeva,Zh. Obshch. Khim., 1969,39, 2502 [J. Gen. Chem. USSR, 1969,39 (Engl. Trans.)].

    CAS  Google Scholar 

  32. S. V. Basenko, P. A. Bormashev, R. G. Mirskov, and M. G. Voronkov,Dokl. Akad. Nauk SSSR, 1990,331, 177 [Dokl. Chem., 1990 (Engl. Transl.)].

    Google Scholar 

  33. Ping Lu, J. K. Paulasaari, and W. P. Weber,Organometallics, 1996,15, 4649.

    Article  CAS  Google Scholar 

  34. A. Stokes,Am. Chem. J., 1892,14, 438, 545.

    Google Scholar 

  35. S. N. Borisov, M. G. Voronkov, and E. Ya. Lukevits,Kremneelementoorganicheskie soedineniya [Organoelemental Silicon Compounds], Khimiya, Leningrad, 1966, 541 pp. (in Russian), S. N. Borisov, M. G. Voronkov, and E. Ya. Lukevitx,Organosilicon Heteropolymers and Heterocompounds, Plenum Press, New York, 1970, 632 pp.; M. G. Voronkov, E. A. Maletina, and V. K. Roman,Geterosiloksany [Heterosiloxanes], Nauka, Novosibirsk, 1984, 265 (in Russian); M. G. Voronkov, E.A. Maletina, and V. K. Roman,Heterosiloxanes, Derivatives of Non-Biogenic Elements, Harwood Acad., London, 1988,1, 469 pp.

    Google Scholar 

  36. A. Stock and C. Somieski,Ber., 1919,50, 1764; 1919,52, 1851.

    Google Scholar 

  37. L. R. Vyle and F. S. Kipping,J. Chem. Soc. (London), 1924,125, 2616.

    CAS  Google Scholar 

  38. T. Takiguchi, M. Sakurai, T. Kishi, J. Ichimura, and I. Jizuka,J. Org. Chem., 1960,25, 310.

    Article  CAS  Google Scholar 

  39. US Pat. 2 629 725;Chem. Abstrs., 1953,47, 5720e; US Pat. 2 629 726;Chem. Abstrs., 1953,47, 5720g.

    Google Scholar 

  40. Z. H. Aiube, J. Chojnouski, C. Eaborn, and W. A. Stanczyk,J. Chem. Soc., Chem. Commun., 1983, 493; C. Eaborn and W. A. Stanczyk,J. Chem. Soc., Perkin Trans. 2, 1984, 2099.

  41. M. G. Voronkov, S. V. Basenko, V. Yu. Vitkovskii, S. M. Nozdrya, and R. G. Mirskov,Metalloorg. Khim., 1989,2, 310 [Organomet. Chem. USSR, 1989,2 (Engl. Transl.)].

    CAS  Google Scholar 

  42. N. V. Komarov, Yu. V. Maroshin, A. D. Lebedeva, and L. N. Astaf'eva,Izv. Akad. Nauk SSSR, Otd. Khim. Nauk [Bull. Acad. Sci. USSR, Div. Chem. Sci.], 1963, 97 (in Russian); M. F. Shostakovskii, N. V. Komarov, and Yu. V. Maroshin,Zh. Obshch. Khim., 1965,35, 335 [J. Gen. Chem. USSR, 1965,35 (Engl. Transl.)]; M. F. Schostakovskij and N. V. Komarov,J. prakt. Chem., 1964,23, 208.

  43. L. E. Gusel'nikov, N. S. Nametkin, and V. M. Vdovin,Usp. Khim., 1974,43, 1317 [Russ. Chem. Rev., 1974,43, (Engl. Transl.)]; L. E. Gusel'nikov, N. S. Nametkin, and V. M. Vdovin,Acc. Chem. Res., 1975,8, 18; L. E. Gusel'nikov and N. S. Nametkin,Chem. Rev., 1979,79, 529.

    Google Scholar 

  44. G. Raabe and J. Michl,Chem. Rev., 1985,85, 419; G. Raabe and J. Michl, inThe Chemistry of Organic Silicon Compounds, Eds. S. Patai and Z. Rappoport, J. Wiley, Chichester-London, Ch. 17, 1989.

    Article  CAS  Google Scholar 

  45. V. N. Khabashesku, Z. A. Kerzina, A. K. Maltsev, and O. M. Nefedov,J. Organomet. Chem., 1989,364, 301; A. K. Maltsev, V. N. Khabashesku, O. M. Nefedov, inSilicon Chemistry, Eds. E. R. Corey, J. Y. Corey, and P. P. Gaspar, J. Wiley, New York, 1987, 211.

    Article  CAS  Google Scholar 

  46. H. N. Post and H. M. Norton,J. Org. Chem., 1942,7, 528.

    Article  CAS  Google Scholar 

  47. V. P. Feshin, L. S. Romanenko, and M. G. Voronkov,Usp. Khim., 1981,50, 461 [Russ. Chem. Rev., 1981,50 (Engl. Transl.)]

    Google Scholar 

  48. N. S. Zefirov and N. M. Shektman,Usp. Khim., 1971,40, 494 [Russ. Chem. Rev., 1971,40 (Engl. Transl.)]; P. Deslongchamps,Stereoelectronic Effects in Organic Chemistry, Pergamon Press, Oxford, 1983; J. Tvaroska and T. Beleha,Chem. Pap., 1985,39, 805; A. J. Kirby,The Anomeric Effect and Related Stereolectronic Effects at Oxygen, Springer-Verlag, Berlin, 1983.

    Google Scholar 

  49. Y. Apeloig and A. Stanger,J. Organomet. Chem., 1988,346, 305; Y. Apeloig, inThe Chemistry of Organic Silicon Compounds, Eds. S. Patai and Z. Rapport, J. Wiley, New York, 1989, 59.

    Article  CAS  Google Scholar 

  50. A. E. Reed and P. R. Schleyer,Inorg. Chem., 1988,27, 3969; R. P. Arshinova,Metalloorg. Khim., 1990,3, 1127 [Organomet. Chem. USSR, 1990,3 (Engl. Transl.)].

    Article  CAS  Google Scholar 

  51. I. P. Biryukov, M. G. Voronkov, E. Ya. Lukevits, and I. A. Safin,Teor. Eksp. Khim., [Sov. Theor. Exp. Chem.], 1970,6, 566 (in Russian), V. P. Feshin, M. G. Voronkov, G. Ya. Zueva, L. S. Romanenko, and G. V. Lipatova,Dokl. Akad. Nauk SSSR, 1977,232, 1370 [Dokl. Chem., 1977 (Engl. Transl.)]; A. N. Egorochkin, S. Ya. Khorshev, N. S. Vyazankin, T. I. Chernysheva, and O. V. Kuz'min,Izv. Akad. Nauk SSSR, Ser. Khim., 1971, 544 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971,20, 478 (Engl. Transl.)].

    CAS  Google Scholar 

  52. J. Goubau and H. Behz,Z. anorg. allgem. Chem., 1953,272, 2.

    Article  Google Scholar 

  53. J. R. Van Waser and K. Moedritzer,J. Inorg. Nucl. Chem., 1964,26, 737; K. Moedritzer,Organomet. Chem. Rev., 1966,1, 179.

    Article  Google Scholar 

  54. D. E. Peppard, W. U. Brown, and W. C. Jonson,J. Am. Chem. Soc., 1946,68, 76; W. Alrey and G. M. Sheldrick,J. Inorg. Nucl. Chem., 1970,32, 1827.

    Article  CAS  Google Scholar 

  55. V. G. Noskov, L. N. Kalinina, and M. A. Englin,Zh. Obshch. Khim., 1972,42, 2028 [J. Gen. Chem. USSR, 1972,42 (Engl. Transl.)].

    CAS  Google Scholar 

  56. P. Koehler, H. Weydig, and K. Licht,Z. Chem., 1977,3, 100.

    Google Scholar 

  57. A. Radecki and R. Piekoš,Rocžn. Chem., 1962,36, 177; 1329; A. Radecki,Rocžn. Chem., 1963,37, 727; A. Radecki and R. Piekoš,Rocžn. Chem., 1961,35, 869.

    CAS  Google Scholar 

  58. Yu. M. Varezhkin, D. Ya. Zhinkin, M. M. Morgunov, and V. P. Anosov,Zh. Obshch. Khim., 1977,47, 2089 [J. Gen. Chem. USSR, 1977,47 (Engl. Transl.)]; A. N. Mikhailova, M. M. Morgunova, D. Ya. Zhinkin, and G. L. Merkulova,Zh. Obshch. Khim., 1977,47, 2087 [J. Gen. Chem. USSR, 1977,47 (Engl. Transl.)].

    CAS  Google Scholar 

  59. H. J. Emeleus and H. G. Heal,J. Chem. Soc., 1949, 1696.

  60. C. Glidewell, A. G. Robiette, and G. M. Sheldrick,J. Chem. Soc., Chem. Commun., 1970, 931.

  61. M. G. Voronkov,Dokl. Akad. Nauk SSSR, 1961,138, 106 [Dokl. Chem., 1961 (Engl. Transl.)];Zh. Obshch. Khim., 1962,32, 2391 [J. Gen. Chem. USSR, 1962,32, (Engl. Transl.)].

    CAS  Google Scholar 

  62. A. N. Lazarev,Izv. Akad. Nauk SSSR, Ser. Khim., 1964, 235 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1964,13 (Engl. Transl.)]; A. N. Lazarev, G. F. Tenisheva, and V. P. Davydova,Dokl. Acad. Nauk SSSR, 1964,158, 648 [Dokl. Chem., 1964 (Engl. Transl.)]; A. N. Lazarev, K. Poiker, and G. F. Tenisheva,Dokl. Akad. Nauk SSSR, 1967,175, 1322 [Dokl. Chem., 1967 (Engl. Transl.)]; R. Poiker and A. N. Lazarev,Izv. Akad. Nauk SSSR, Neorgan. materialy [Bull. Acad. Sci. USSR, Inorganic Materials], 1968,4, 1716 (in Russian).

  63. H. Schmidbaur, J. A. Perez-Garsia, and H.S. Arnold,Z. anorg. allgem. Chem., 1964,328, 105.

    Article  CAS  Google Scholar 

  64. W. S. Taflock and E. G. Rochow,J. Org. Chem., 1952,17, 1555.

    Article  Google Scholar 

  65. M. G. Voronkov, G. V. Dolgushin, V. P. Feshin, L. P. Turchaninova, N. A. Korchevin, and E. N. Deryagina,Zh. Obshch. Khim., 1992,62, 1111 [Russ. J. Gen. Chem., 1992,62 (Engl. Transl.)]; M. G. Voronkov, G. V. Dolgushin, V. P. Feshin, L. P. Turchaninova, N. A. Korchevin, and E. N. Deryagina,Z. Naturforsch., 1992,47A, 147.

    CAS  Google Scholar 

  66. E. I. Brodskaya, G. V. Rotovskii, G. A. Yuzhikov, V. V. Belyaeva, and M. G. Voronkov,Zh. Obshch. Khim., 1997,67, 765 [Russ. J. Gen. Chem., 1997,67 (Engl. Transl.)].

    Google Scholar 

  67. D. C. Payne,J. Chem. Soc., 1954, 2143; B. J. Aylett, I. A. Ellis, and J. R. Richmond,J. Chem. Soc., Dalton Trans., 1973, 981; J. Goubeau and H. Grosse-Ruyken,Z. anorg. allgem. Chem., 1951, 230; M. Chaignear,Compt. Rend., 1968,266, 1053; K. G. Sharp and J. L. McGrave,J. Inorg. Nucl. Chem., 1971,33, 2813.

  68. H. S. Booth and R. S. Osten,J. Am. Chem. Soc., 1945,67, 1092.

    Article  CAS  Google Scholar 

  69. T. Margrave, K. G. Sharp, and P. W. Wilson,J. Am. Chem. Soc., 1970,92, 1530.

    Article  CAS  Google Scholar 

  70. Yu. L. Frolov, T. N. Aksamentova, G. A. Gavrilova, N. N. Chipanina, V. B. Modonov, L. I. Gubanova, V. M. D'yakov, and M. G. Voronkov,Dokl. Akad. Nauk SSSR, 1982,267, 646 [Dokl. Chem., 1982 (Engl. Transl.)].

    CAS  Google Scholar 

  71. T. Kh. Islamov, Ph. D. (Chem.) Thesis, INKhS, Moscow, 1970 (in Russian); L. E. Gusel'nikov, T. Kh. Islamov, V. M. Vdovin, and N. S. Nametkin,Tez. dokl. soveshch. “Vliyanie vysshikh atomnykh orbitalei na fizicheskie i khimicheskie svoistva perekhodnykh elementov” [Proc. Meeting “Influence of Highest Atomic Orbitals on Physical and Chemical Properties of Non-Transition Elements”], Riga, Zinatne, 1971, 74 (in Russian); L. E. Gusel'nikov, N. S. Nametkin, T. Kh. Islamov, A. A. Sobtsov, and V. M. Vdovin,Izv. Akad. Nauk SSSR, Ser. Khim., 1971, 84; 90 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971,20, 71; 76 (Engl. Transl.)].

  72. I. M. T. Davidson and J. Thompson,J. Chem. Soc., Chem. Commun., 1971, 251.

  73. M. V. Sobolevskii, I. I. Skorokhodov, V. E. Ditsent, L. V. Sobolevskaya, and G. M. Moiseeva,Vysokomol. Soedin., A, 1970,12, 2714; 1974,16, 729 [Polym. Sci USSR, Ser. A, 1970,12; 1974,16, (Engl. Transl.)].

    CAS  Google Scholar 

  74. M. G. Voronkov,Zh. Obshch. Khim., 1996,66, 167 [Russ. J. Gen. Chem., 1996,66 (Engl. Transl.)]; M. G. Voronkov, V. A. Klyuchnikov, and L. I. Marenkova,Dokl. Akad. Nauk, 1995,344, 489. [Dokl. Chem., 1995 (Engl. Transl.)]; M. G. Voronkov, V. A., Klyuchnikov, E. V. Mironenko, G. N. Shvets, T. F. Danilova, and Yu. I. Khudobin,J. Organomet. Chem., 1991,406, 91; M. G. Voronkov, V. A. Klyuchnikov, and L. I. Marenkova,J. Organomet. Chem., 1996,510, 263.

    CAS  Google Scholar 

  75. M. R. Alexander, R. D. Short, and F. R. Jones,XIth Intern. Sympos. on Organosilicon Chemistry, Abstrs., Montpellier (France), 1996, OC 19.

  76. T. H. Thomas and T. C. Kendrick,J. Polym. Sci., Part A-2, 1969,7, 537.

    Article  CAS  Google Scholar 

  77. M. V. Sobolevskii, I. I. Skorokhodov, V. E. Ditsent, and L. V. Sobolevskaya,Vysokomol. Soedin., A, 1973,15, 507 [Polym. Sci. USSR, Ser. A, 1973,15 (Engl. Transl.)]; Yu. A. Alekandrova, T. S. Nikitina, and A. N. Pravednikov,Vysokomol. Soedin., A, 1968,10, 1078 [Polym. Sci. USSR, Ser., A, 1968,10 (Engl. Transl.)].

    CAS  Google Scholar 

  78. M. A. Verkhotin, V. V. Rode, and S. R. Rafikov,Vysokomol. Soedin., A, 1967,9, 847 [Polym. Sci. USSR, Ser. A, 1967,9 (Engl. Transl.)].

    CAS  Google Scholar 

  79. A. Ballistreri, S. Toti, P. Maravigna, G. Montaudo, and E. Scamporrino,J. Polym. Chem. Ed., 1980,18, 1923; 1981,19, 1679; 1982,20, 1685.

    Article  CAS  Google Scholar 

  80. A. Ballistreri, D. Garozzo, and G. Montaudo,Macromolecules, 1984,17, 1312.

    Article  CAS  Google Scholar 

  81. A. A. Berlin and A. M. Dubinskaya,Vysokomol. Soedin., 1959,1, 1678.

    CAS  Google Scholar 

  82. A. N. Novikov, G. S. Gol'din, and L. S. Baturina,Perkhlorsiloksany. Poluchenie i svoistva [Perchlorosiloxanes. Preparation and Properties], NIITEKhIM, Moscow, 1985, 20 (in Russian).

    Google Scholar 

  83. C. Somiesky,Ber., 1923,56, 132; M. I. Rogovik, Z. L. Novitskii, and P. D. Romanenko, Dep. ONIITEKhIM, Cherkassy, 1979, No. 2802/79 (in Russian).

    Google Scholar 

  84. G. D. Cooper and A. R. Gilbert,J. Am. Chem. Soc., 1960,82, 5042.

    Article  CAS  Google Scholar 

  85. G. S. Gol'din, L. S. Baturina, S. G. Fedorov, A. N. Novikova, and T. N. Pushakova,Zh. Obshch. Khim., 1980,50, 2627, [J. Gen. Chem. USSR, 1980,50 (Engl. Transl.)].

    Google Scholar 

  86. H. Reiboldt and W. Wisfeld,J. Am. Chem. Soc., 1935,57, 197.

    Google Scholar 

  87. W. C. Schumb and C. H. Klein,J. Am. Chem. Soc., 1937,59, 261; W. C. Schumb and C. M. Saffer,J. Am. Chem. Soc., 1937,61, 363; W. C. Schumb,Chem. Rev., 1942,31, 587.

    Article  CAS  Google Scholar 

  88. M. G. Voronkov and Yu. I. Khudobin,Zh. Obshch. Khim., 1956,26, 2584.

    Google Scholar 

  89. M. G. Voronkov, S. F. Pavlov, and E. I. Dubinskaya,Izv. Akad. Nauk SSSR, Ser. Khim., 1975, 657 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1975,24 (Engl. Transl.)];Dokl. Akad. Nauk SSSR, 1976,227, 607 [Dokl. Chem., 1976 (Engl. Transl.)].

  90. M. G. Voronkov, B. N. Dolgov, and N. A. Dmitrieva,Dokl. Akad. Nauk SSSR [Docl. Chem. USSSR], 1952,84, 959 (in Russian) Author's Certificate 451172/344 USSR;Byull. Izobret. [Inventor Bulletin], 1955, 13 (in Russian).

    CAS  Google Scholar 

  91. M. G. Voronkov and Yu. I. Khudobin,Izv. Akad. Nauk SSSR, Otd. Khim. Nauk [Bull. Acad. Sci. USSR, Div. Chem. Sci.], 1956, 713; 805 (in Russian).

  92. B. N. Dolgov, S. N. Borisov, and M. G. Voronkov,Zh. Obshch. Khim. [Sov. J. Gen. Chem.], 1957,27, 716; 2692 (in Russian).

    CAS  Google Scholar 

  93. M. G. Voronkov, V. E. Puzanova, S. F. Pavlov, and E. I. Dubinskaya,Izv. Akad. Nauk SSSR, Ser. Khim., 1975, 448 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1975,24 (Engl. Transl.)]; M. G. Voronkov, E. I. Dubinskaya, and S. F. Pavlov,7th Intern. Conf. on Organometallic Chemistry, Abstrs., Venice, 1975, 155; M. G. Voronkov, E. I. Dubinskaya, S. F. Pavlov, and V. G. Gorokhova,Izv. Akad. Nauk SSSR, Ser. Khim., 1976, 2355 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1976,25, (Engl. Transl.)].

  94. M. G. Voronkov, E. I. Dubinskaya, V. G. Komarov, and S. F. Pavlov,Zh. Obshch. Khim., 1976,46, 1908 [J. Gen. Chem. USSR, 1976,46, (Engl. Transl.)]; M. G. Voronkov, V. G. Komarov, A. I. Albanov, I. M. Korotaeva, and E. I. Dubinskaya,Izv. Akad. Nauk SSSR, Ser. Khim., 1978, 1415 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1978,27, 1233 (Engl. Transl.)]; M. G. Voronkov, V. G. Komarov, A. I. Albanov, E. I. Kositsyna, and E. I. Dubinskaya,Izv. Akad. Nauk SSSR, Ser. Khim., 1978, 1692 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1978,27, (Engl. Transl.)]; M. G. Voronkov, E. I. Dubinskaya, and V. G. Komarov,Zh. Obshch. Khim., 1990,60, 1355 [J. Gen. Chem. USSR, 1990,60 (Engl. Transl.)]; G. M. Telysheva, R. E. Pankova, A. V. Novikov, E. I. Dubinskaya, and M. G. Voronkov,VIII Intern. Sympos. on Fundamental Research of Wood, Reports, Warsaw, 1990, 90; M. G. Voronkov and E. I. Dubinskaya,J. Organomet. Chem., 1991,410, 13.

    CAS  Google Scholar 

  95. V. A. Pestunovich, L. P. Petukhov, V. I. Rakhlin, B. Z. Shterenberg, R. G. Mirskov, and M. G. Voronkov,Dokl. Akad. Nauk SSSR, 1982,263, 904 [Dokl. Chem., 1982 (Engl. Transl.)].

    CAS  Google Scholar 

  96. R. Piekos and A. Radecki,Rocžn. Chem., 1962,36, 1303.

    CAS  Google Scholar 

  97. H. H. Anderson, D. L. Seaton, and R. P. T. Radnicki,J. Am. Chem. Soc., 1951,73, 2144.

    Article  CAS  Google Scholar 

  98. B. Sternbach and A. C. McDiarmid,J. Am. Chem. Soc., 1961,83, 3384.

    Article  CAS  Google Scholar 

  99. W. Ando and M. Ikeno,Chem. Lett. 1980, 1255.

  100. D. Grafslein,J. Am. Chem. Soc., 1955,77, 6650.

    Article  Google Scholar 

  101. W. Ando and M. Ikeno,Tetrahedron Lett., 1979,51, 4941.

    Article  Google Scholar 

  102. H. H. Anderson,J. Am. Chem. Soc., 1959,81, 4786.

    Google Scholar 

  103. H. J. Emeleus, A. G. MacDiarmid, and A. G. Maddoc,J. Inorg. Nucl. Chem., 1955,1, 194.

    Article  CAS  Google Scholar 

  104. H. J. Emeleus, M. Onyszchuk, and W. Z. Kuchen,Z. anorg. allgem. Chem., 1956,283, 74.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation

    M. G. Voronkov

Authors
  1. M. G. Voronkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 824–835, May, 1998.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Voronkov, M.G. Reactions of α-elimination of silanones as a path for formation and destruction of siloxane structures. Russ Chem Bull 47, 795–806 (1998). https://doi.org/10.1007/BF02498145

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02498145

Key words

Search

Navigation