Abstract
Thermal conversion of cobalt(II) maleate, CoC4H2O42H2O, (1) at 340–370 °C was studied. The composition of the products of pyrolysis was determined. The major solid-phase product of decomposition consists of nano-sized particles of CoO (sizes vary within narrow limits) stabilized by the polymeric matrix. Thermal conversions of CoII maleate involve dehydration, polymerization of dehydrated monomers, and decarboxylation of the resulting polymer.
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For Part 47, see Ref. 1
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 265–270, February, 1998.
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Rosenberg, A.S., Aleksandrova, E.I., Ivleva, N.P. et al. Reactivity of metal-containing monomers. Russ Chem Bull 47, 259–264 (1998). https://doi.org/10.1007/BF02498945
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DOI: https://doi.org/10.1007/BF02498945