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Microstructure and tensile behavior of nitrogen-alloyed, dual-phase stainless steels

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Abstract

Two alloys of high-nitrogen stainless steel have been heat treated to produce dual-phase microstruc-tures. The first alloy, N10CrNiMol7 1, a Ni-containing stainless steel, was processed conventionally. The second alloy, N20CrMol7, a Ni-free stainless steel, was processed to obtain a higher nitrogen content by pressurized electroslag remelting. The martensite in N10CrNiMol7 1 was homogeneously distributed in the ferrite and obtained a near-constant volume fraction as a function of intercritical annealing temperature. Microprobe analysis and microhardness measurements of the martensite con-stituent suggested that up to 0.4 pct N was dissolved in the austenite before quenching. Austenite formation, martensite transformation, undissolved nitrides, and retained austenite were evaluated by transmission electron microscopy (TEM). The Ni-containing alloy exhibited classic dual-phase tensile behavior in that continuous yielding was observed together with good combinations of ultimate tensile strength and total elongation. The martensite constituent in alloy N20CrMol7 was concen-trated within bands. Comparison of tensile properties of the two alloys at similar volume fractions and hardness levels of martensite and ferrite showed that the microstructure containing banded mar-tensite had inferior combinations of strength and ductility. The degradation of tensile ductility was accompanied by a fracture mode transition from microvoid coalescence to transgranular cleavage. The deformation and fracture behavior of both alloys were related to the microstructure.

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References

  1. H. Berns:Steel Res., 1992, vol. 63 (8), pp. 343–47.

    CAS  Google Scholar 

  2. H. Berns:Z. Metallkd., 1995, vol. 86 (3), pp. 156–63.

    CAS  Google Scholar 

  3. J. Lueg: Ph.D. Thesis, Ruhr-Universitaet Bochum, VDI-Verlag, Duesseldorf, 1990, vol. 5 (188).

    Google Scholar 

  4. J.C. Rawers, J.S. Dunning, G. Asai, and R.P. Reed:Metall. Trans. A, 1992, vol. 23A, pp. 2061–68.

    CAS  Google Scholar 

  5. A.H. Satir-Kolorz: Ph.D. Thesis, ETH, Zuerich, Switzerland, 1989.

    Google Scholar 

  6. H. Schenk, M.G. Frohberg, and F. Reinders:Stahl Eisen, 1963, vol. 83 (2), pp. 93–99.

    Google Scholar 

  7. G. Stein, J. Menzel, and H. Doerr:High Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 32–38.

    Google Scholar 

  8. H. Berns and G. Wang:High Nitrogen Steels 90, Conf. Proc. HNS-90, Aachen, Germany, Oct. 10–12, 1990, G. Stein and H. Witulski, eds., Verlag Stahleisen, Duesseldorf, pp. 332–37.

    Google Scholar 

  9. D.K. Matlock, F. Zia-Ebrahimi, and G. Krauss:1982 ASM Material Science Seminar on Deformation, Processing, and Structure, Conf. Proc, St. Louis, MO, Oct. 23–24, 1982, ASM, Metals Park, OH, 1983, pp. 47–87.

    Google Scholar 

  10. R.D. Lawson, D.K. Matlock, and G. Krauss:AIME Symp. on Fundamentals of Dual-Phase Steels, Conf. Proc, Chicago, IL, Feb. 1981, R.A. Kot and D.L. Bramfitt, eds., AIME, New York, NY, pp. 347–81.

    Google Scholar 

  11. L.F. Ramos, D.K. Matlock, and G. Krauss:Metall. Trans. A, 1979, vol. 10A, pp. 259–61.

    CAS  Google Scholar 

  12. O. Maid, W. Dahl, C. Strassburger, and W. Mueschenborn:Stahl Eisen, 1988, vol. 108 (8), pp. 355–64.

    Google Scholar 

  13. O. Maid, W. Dahl, C. Strassburger, and W. Mueschenborn:Stahl Eisen, 1988, vol. 108 (8), pp. 365–70.

    Google Scholar 

  14. A.K. Panda, D.S. Sarma, and R.I. Ganguly:Steel Res., 1993, vol. 64 (10), pp. 513–16.

    CAS  Google Scholar 

  15. J. Becker, E. Hornbogen, and F. Wendl:Z. Metallkd., 1981, vol. 72, pp. 89–100.

    CAS  Google Scholar 

  16. N.K. Balliger and T. Gladman :Met. Sci., 1981, Mar., pp. 95–108.

  17. N.J. Kim and G. Thomas:Metall. Trans. A, 1981, vol. 12A, pp. 483–89.

    Google Scholar 

  18. Y.L. Su and J. Gurland:Mater. Sci. Eng., 1987, vol. 95, pp. 151–65.

    Article  CAS  Google Scholar 

  19. P. Uggowitzer and H.P. Stuewe:Mater. Sci. Eng., 1982, vol. 55, pp. 181–89.

    Article  Google Scholar 

  20. G.R. Speich and R.L. Miller: inStructure and Properties of Dual-Phase-Steel, R.A. Kot and J.M. Morris, eds., TMS-AIME, Warrendale, PA, 1979, pp. 145–82.

    Google Scholar 

  21. A.M. Sarosiek and W.S. Owen:Mater. Sci. Eng., 1984, vol. 66, pp. 13–34.

    Article  CAS  Google Scholar 

  22. T. Sakaki, K. Sugimoto, and T. Fukuzato:Acta Metall., 1983, vol. 31 (10), pp. 1737–46.

    Article  CAS  Google Scholar 

  23. W.R. Cribb and J.M. Rigsbee: inStructure and Properties of Dual-Phase-Steel, R.A. Kot and J.M. Morris, eds., TMS-AIME, Warrendale, PA, 1979, pp. 91–117.

    Google Scholar 

  24. A.F. Szewczyk and J. Gurland:Metall. Trans. A, 1982, vol. 13A, pp. 1821–26.

    Google Scholar 

  25. G.R. Speich, V.A. Demarest, and R.L. Miller:Metall. Trans. A, 1981, vol. 12A, pp. 1419–28.

    Google Scholar 

  26. P. Uggowitzer and H.P. Stuewe:Mater. Sci. Eng., 1982, vol. 55, pp. 181–89.

    Article  Google Scholar 

  27. X.L. Cai, A.J. Garrat-Reed, and W.S. Owen:Metall. Trans. A, 1985, vol. 16A, pp. 543–57.

    CAS  Google Scholar 

  28. C.L. Garcia and A.J. DeArdo:Metall. Trans. A, 1981, vol. 12A, pp. 521–30.

    Google Scholar 

  29. F.B. Pickering: inHigh Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 10–31.

    Google Scholar 

  30. G.P. Negoda, G.M. Grigorgenko, D.P. Novikova, and V.Yu. Orlovsky: inHigh Nitrogen Steels 90, Conf. Proc. HNS-90, Aachen, Germany, Oct. 10–12, 1990, G. Stein and H. Witulski, eds., Verlag Stahleisen, Duesseldorf, pp. 123–27.

    Google Scholar 

  31. H. Leda: inHigh Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 313–17.

    Google Scholar 

  32. F. Vandershaeve, R. Taillard and J. Foct:Steel Res., 1993, vol. 64 (4), pp. 221–27.

    Google Scholar 

  33. H. Berns, S.N. Bugajchuk, V.A. Duz, R. Ehrhardt, V.G. Gavriljuk, Y.N. Petrov, and I.A. Yakubzov:Steel Res., 1994, vol. 65 (10), pp. 444–50.

    CAS  Google Scholar 

  34. B.R. Anthamatten, P.J. Uggowitzer, M.L. Cui, M.O. Speidel, and G. Stein: inHigh Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 58–62.

    Google Scholar 

  35. D.Z. Yang, E.L. Brown, D.K. Matlock, and G. Krauss:Metall. Trans. A, 1985, vol. 16A, pp. 1385–92.

    CAS  Google Scholar 

  36. H. Berns, R. Ehrhardt, and S. Siebert:Mat.-wiss. u. Werkstofftech., 27 (1996) pp. 25–36.

    Article  CAS  Google Scholar 

  37. Y. Sawada, P.P. Foley, S.W. Thompson, and G. Krauss: in35th MWSP, Conf. Proc, ISS-AIME, Warrendale, PA, 1994, vol. 31, pp. 263–86.

    Google Scholar 

  38. P.T. Purtscher, Y.W. Cheng, and R.P. Foley: in36th MWSP, Conf. Proc, ISS-AIME, Warrendale, PA, 1995, vol. 32, pp. 279–86.

    Google Scholar 

  39. H. Fischmeister and B. Karlsson:Z Metallkd., 1977, vol. 68 (5), pp. 311–27.

    CAS  Google Scholar 

  40. J. Lian, Z. Jiang, and J. Liu:Mater. Sci. Eng., 1991, vol. A147, pp. 55–65.

    CAS  Google Scholar 

  41. P. Uggowitzer and H.P. Stuewe:Z Metallkd., 1982, vol. 73 (5), pp. 277–85.

    CAS  Google Scholar 

  42. C.L. Magee and R.G. Davies: inAlloys for the Eighties, R.Q. Barr, ed., Climax Molybdenum Company, Greenwich, CT, 1981, pp. 25–35.

    Google Scholar 

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Berns, H., Kleff, J., Krauss, G. et al. Microstructure and tensile behavior of nitrogen-alloyed, dual-phase stainless steels. Metall Mater Trans A 27, 1845–1859 (1996). https://doi.org/10.1007/BF02651934

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