Abstract
Two alloys of high-nitrogen stainless steel have been heat treated to produce dual-phase microstruc-tures. The first alloy, N10CrNiMol7 1, a Ni-containing stainless steel, was processed conventionally. The second alloy, N20CrMol7, a Ni-free stainless steel, was processed to obtain a higher nitrogen content by pressurized electroslag remelting. The martensite in N10CrNiMol7 1 was homogeneously distributed in the ferrite and obtained a near-constant volume fraction as a function of intercritical annealing temperature. Microprobe analysis and microhardness measurements of the martensite con-stituent suggested that up to 0.4 pct N was dissolved in the austenite before quenching. Austenite formation, martensite transformation, undissolved nitrides, and retained austenite were evaluated by transmission electron microscopy (TEM). The Ni-containing alloy exhibited classic dual-phase tensile behavior in that continuous yielding was observed together with good combinations of ultimate tensile strength and total elongation. The martensite constituent in alloy N20CrMol7 was concen-trated within bands. Comparison of tensile properties of the two alloys at similar volume fractions and hardness levels of martensite and ferrite showed that the microstructure containing banded mar-tensite had inferior combinations of strength and ductility. The degradation of tensile ductility was accompanied by a fracture mode transition from microvoid coalescence to transgranular cleavage. The deformation and fracture behavior of both alloys were related to the microstructure.
Similar content being viewed by others
References
H. Berns:Steel Res., 1992, vol. 63 (8), pp. 343–47.
H. Berns:Z. Metallkd., 1995, vol. 86 (3), pp. 156–63.
J. Lueg: Ph.D. Thesis, Ruhr-Universitaet Bochum, VDI-Verlag, Duesseldorf, 1990, vol. 5 (188).
J.C. Rawers, J.S. Dunning, G. Asai, and R.P. Reed:Metall. Trans. A, 1992, vol. 23A, pp. 2061–68.
A.H. Satir-Kolorz: Ph.D. Thesis, ETH, Zuerich, Switzerland, 1989.
H. Schenk, M.G. Frohberg, and F. Reinders:Stahl Eisen, 1963, vol. 83 (2), pp. 93–99.
G. Stein, J. Menzel, and H. Doerr:High Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 32–38.
H. Berns and G. Wang:High Nitrogen Steels 90, Conf. Proc. HNS-90, Aachen, Germany, Oct. 10–12, 1990, G. Stein and H. Witulski, eds., Verlag Stahleisen, Duesseldorf, pp. 332–37.
D.K. Matlock, F. Zia-Ebrahimi, and G. Krauss:1982 ASM Material Science Seminar on Deformation, Processing, and Structure, Conf. Proc, St. Louis, MO, Oct. 23–24, 1982, ASM, Metals Park, OH, 1983, pp. 47–87.
R.D. Lawson, D.K. Matlock, and G. Krauss:AIME Symp. on Fundamentals of Dual-Phase Steels, Conf. Proc, Chicago, IL, Feb. 1981, R.A. Kot and D.L. Bramfitt, eds., AIME, New York, NY, pp. 347–81.
L.F. Ramos, D.K. Matlock, and G. Krauss:Metall. Trans. A, 1979, vol. 10A, pp. 259–61.
O. Maid, W. Dahl, C. Strassburger, and W. Mueschenborn:Stahl Eisen, 1988, vol. 108 (8), pp. 355–64.
O. Maid, W. Dahl, C. Strassburger, and W. Mueschenborn:Stahl Eisen, 1988, vol. 108 (8), pp. 365–70.
A.K. Panda, D.S. Sarma, and R.I. Ganguly:Steel Res., 1993, vol. 64 (10), pp. 513–16.
J. Becker, E. Hornbogen, and F. Wendl:Z. Metallkd., 1981, vol. 72, pp. 89–100.
N.K. Balliger and T. Gladman :Met. Sci., 1981, Mar., pp. 95–108.
N.J. Kim and G. Thomas:Metall. Trans. A, 1981, vol. 12A, pp. 483–89.
Y.L. Su and J. Gurland:Mater. Sci. Eng., 1987, vol. 95, pp. 151–65.
P. Uggowitzer and H.P. Stuewe:Mater. Sci. Eng., 1982, vol. 55, pp. 181–89.
G.R. Speich and R.L. Miller: inStructure and Properties of Dual-Phase-Steel, R.A. Kot and J.M. Morris, eds., TMS-AIME, Warrendale, PA, 1979, pp. 145–82.
A.M. Sarosiek and W.S. Owen:Mater. Sci. Eng., 1984, vol. 66, pp. 13–34.
T. Sakaki, K. Sugimoto, and T. Fukuzato:Acta Metall., 1983, vol. 31 (10), pp. 1737–46.
W.R. Cribb and J.M. Rigsbee: inStructure and Properties of Dual-Phase-Steel, R.A. Kot and J.M. Morris, eds., TMS-AIME, Warrendale, PA, 1979, pp. 91–117.
A.F. Szewczyk and J. Gurland:Metall. Trans. A, 1982, vol. 13A, pp. 1821–26.
G.R. Speich, V.A. Demarest, and R.L. Miller:Metall. Trans. A, 1981, vol. 12A, pp. 1419–28.
P. Uggowitzer and H.P. Stuewe:Mater. Sci. Eng., 1982, vol. 55, pp. 181–89.
X.L. Cai, A.J. Garrat-Reed, and W.S. Owen:Metall. Trans. A, 1985, vol. 16A, pp. 543–57.
C.L. Garcia and A.J. DeArdo:Metall. Trans. A, 1981, vol. 12A, pp. 521–30.
F.B. Pickering: inHigh Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 10–31.
G.P. Negoda, G.M. Grigorgenko, D.P. Novikova, and V.Yu. Orlovsky: inHigh Nitrogen Steels 90, Conf. Proc. HNS-90, Aachen, Germany, Oct. 10–12, 1990, G. Stein and H. Witulski, eds., Verlag Stahleisen, Duesseldorf, pp. 123–27.
H. Leda: inHigh Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 313–17.
F. Vandershaeve, R. Taillard and J. Foct:Steel Res., 1993, vol. 64 (4), pp. 221–27.
H. Berns, S.N. Bugajchuk, V.A. Duz, R. Ehrhardt, V.G. Gavriljuk, Y.N. Petrov, and I.A. Yakubzov:Steel Res., 1994, vol. 65 (10), pp. 444–50.
B.R. Anthamatten, P.J. Uggowitzer, M.L. Cui, M.O. Speidel, and G. Stein: inHigh Nitrogen Steel 88, Conf. Proc. HNS-88, Lille, France, May 18–20, 1988, H. Foct, ed., Institute of Metals, London, 1989, pp. 58–62.
D.Z. Yang, E.L. Brown, D.K. Matlock, and G. Krauss:Metall. Trans. A, 1985, vol. 16A, pp. 1385–92.
H. Berns, R. Ehrhardt, and S. Siebert:Mat.-wiss. u. Werkstofftech., 27 (1996) pp. 25–36.
Y. Sawada, P.P. Foley, S.W. Thompson, and G. Krauss: in35th MWSP, Conf. Proc, ISS-AIME, Warrendale, PA, 1994, vol. 31, pp. 263–86.
P.T. Purtscher, Y.W. Cheng, and R.P. Foley: in36th MWSP, Conf. Proc, ISS-AIME, Warrendale, PA, 1995, vol. 32, pp. 279–86.
H. Fischmeister and B. Karlsson:Z Metallkd., 1977, vol. 68 (5), pp. 311–27.
J. Lian, Z. Jiang, and J. Liu:Mater. Sci. Eng., 1991, vol. A147, pp. 55–65.
P. Uggowitzer and H.P. Stuewe:Z Metallkd., 1982, vol. 73 (5), pp. 277–85.
C.L. Magee and R.G. Davies: inAlloys for the Eighties, R.Q. Barr, ed., Climax Molybdenum Company, Greenwich, CT, 1981, pp. 25–35.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Berns, H., Kleff, J., Krauss, G. et al. Microstructure and tensile behavior of nitrogen-alloyed, dual-phase stainless steels. Metall Mater Trans A 27, 1845–1859 (1996). https://doi.org/10.1007/BF02651934
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02651934