Skip to main content
Log in

Miscibility gap in Fe-Ni-Al and Fe-Ni-Al-Co systems

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

The phase equilibria in Fe-Ni-Al and Fe-Ni-Al-Co systems have been investigated by the diffusion couple technique, and the miscibility gap that separates α1 (Fe-rich disordered bcc phase) from α2 (NiAl-rich ordered bcc phase) has been determined. It has been ascertained that the three-dimensional shape of the miscibility gap is not simple helmetlike, but has a peculiar ridge at the order-disorder transition temperature. The miscibility gap is narrowed and shifted to the Fe-rich corner by the addition of Co, and Co atoms are distributed to the α2 rather than the α1 Furthermore, by alloying Co, the fcc γ phase is stabilized and the miscibility gap between α1 and α2 is hidden to some extent by the phase regions concerned with the γ phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. Kiuchi:Rept. of Aeronautical Res. Inst., Tokyo Imp. Univ., 1937, vol. 12, p. 179; 1938, vol. 13, p. 555.

    Google Scholar 

  2. A. J. Bradley and A. Taylor:Nature, 1938, vol. 140, p. 1012.

    Google Scholar 

  3. A.J. Bradley and A. Taylor:Proc. Roy. Soc, A, 1938, vol. 166, p. 353.

    Article  Google Scholar 

  4. A.I. Bradley:J. Iron Steel Inst., 1949, vol. 163, p. 19; 1951, vol. 168, p. 233; 1952, vol. 171, p. 41.

    CAS  Google Scholar 

  5. G. Marcon, R. Peffen, and H. Lemaire:IEEE Trans. Mag., 1978, vol. 14, p. 685.

    Article  Google Scholar 

  6. I. L. Meijering:Philips Res. Rep., 1950, vol. 5, p. 333; 1951, vol. 6, p. 183.

    CAS  Google Scholar 

  7. H.K. Hardey:Acta Metall., 1953, vol. 1, p. 210.

    Article  Google Scholar 

  8. T. Nishizawa, M. Hasebe, and M. Ko:Acta Metall., 1979, vol. 27, p. 817.

    Article  CAS  Google Scholar 

  9. T. Nishizawa, S.M. Hao, M. Hasebe, and K. Ishida:Acta Metall., 1983, vol. 31, p. 1403.

    Article  CAS  Google Scholar 

  10. M. Hasebe and T. Nishizawa:Applications of Phase Diagrams in Metallurgy and Ceramics, G. C. Carter, ed., National Bureau of Standards, 1978, p. 911.

  11. M. Hasebe, H. Ohtani, and T. Nishizawa: to be published inMetall. Trans. A.

  12. T. O. Ziebold and R. E. Ogilvie:Anal. Chem., 1963, vol. 35, p. 621.

    Article  CAS  Google Scholar 

  13. L.A. Girifalco:Diffusion, ASM, Metals Park, OH, 1973, p. 185.

  14. O.S. Ivanov and M. A. Skryabina:Izv. Akad. Nauk SSSR, 1949, p. 242.

  15. D.I. Abson and I.A. Whiteman:Metall. Trans., 1972, vol. 3, p. 1157.

    Article  CAS  Google Scholar 

  16. G. V. Raynor and V. G. Rivlin:Int. Met. Rev., 1982, vol. 27, p. 169.

    CAS  Google Scholar 

  17. S. M. Hao, K. Ishida, and T. Nishizawa: to be published inMetall. Trans. A.

  18. Y. Shirakawa, D. Amamiya, and T. Abe:J. Jap. Inst. Met., 1964, vol. 28, p. 313; 1964, vol. 28, p. 689.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hao, S.M., Takayama, T., Ishida, K. et al. Miscibility gap in Fe-Ni-Al and Fe-Ni-Al-Co systems. Metall Trans A 15, 1819–1828 (1984). https://doi.org/10.1007/BF02664895

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02664895

Keywords

Navigation