Skip to main content
Log in

Structure-property relationships in bainitic steels

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

Bainitic microstructures can be produced in a variety of steels either as a result of a deliberate attempt to achieve a particular combination of strength and toughness or in response to welding during fabrication. In addition, such microstructures can offer advantages in terms of their resistance to creep or fatigue deformation or susceptibility to hydrogen embrittlement. The relationships among chemical composition, processing, microstructure, and the mechanical properties will be reviewed. Particular emphasis will be placed on recent advances in alloy design. These developments rely on an improved understanding of the mechanisms of bainitic transformation, and the relevance of recent research in this area to the design of new alloy systems will be discussed. Bainitic structures which arise during welding can have a significant and sometimes detrimental effect on the fracture toughness of the welded joint. The fracture toughness of bainitic microstructures in so-called “local brittle zones” in the heat-affected zone and in weld metals and the importance of controlling the bainitic morphology will be considered and the transformation mechanisms discussed. In summary, the aim of this review will be to indicate the prospects for improved microstructural control of structure-property relationships in steels containing a significant proportion of bainite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H.I. Aaronson:The Mechanisms of Phase Transformations in Crystalline Solids, Monograph 33, Institute of Metals, London, 1969, pp. 207–81.

    Google Scholar 

  2. R.F. Hehemann, K.R. Kinsman, and H.I. Aaronson:Metall. Trans., 1972, vol. 3, pp. 1077–94.

    Article  CAS  Google Scholar 

  3. R.F. Hehemann:Phase Transformations, ASM, Metals Park, OH, 1970, pp. 397–432.

    Google Scholar 

  4. J.W. Christian and D.V. Edmonds: inPhase Transformations in Ferrous Alloys, A.R. Marder and J.I. Goldstein, eds., AIME, New York, NY, 1984, pp. 293–325.

    Google Scholar 

  5. G.B. Olson:Scripta Metall., 1987, vol. 21, pp. 1023–28.

    Article  Google Scholar 

  6. D.P. Fairchild: American Welding Society Autumn Meeting, 1986.

  7. R.E. Dolby: Welding Institute Research Rep. No. 14, Welding Institute, Abington, Cambridge, 1976.

  8. D.J. Abson and R.E. Dolby:Welding Institute Research Bull., Welding Institute, Abington, Cambridge, 1978, vol. 19.

    Google Scholar 

  9. G.S. Barritte and D.V. Edmonds:Advances in the Physical Metallurgy & Applications of Steels, Metals Society, London, 1981, pp. 126–35.

    Google Scholar 

  10. H.I. Aaronson and H.J. Lee:Scripta Metall., 1987, vol. 21, pp. 1011–16.

    Article  CAS  Google Scholar 

  11. G. Thomas and M. Sarikaya: inSolid-Solid Phase Transformations, H.I. Aaronson, eds., AIME, New York, NY, 1983, pp. 999–1003.

    Google Scholar 

  12. J.M. Oblak and R.F. Hehemann:Transformation and Hardenability in Steels, Climax Molybdenum Co., Ann Arbor, MI, 1964, pp. 15–30.

    Google Scholar 

  13. D.N. Shackleton and P.M. Kelly:Acta Metall., 1967, vol. 15, pp. 979–92; G.R. Srinivason and C.M. Wayman: Acta Metall., 1968, vol. 16, pp. 609–20 and 621–36.

    Article  CAS  Google Scholar 

  14. H.K.D.H. Bhadeshia and D.V. Edmonds:Metall. Trans. A, 1979, vol. 10A, pp. 895–907.

    CAS  Google Scholar 

  15. Y. Ohmori, H. Ohtani, and T. Kunitake:Trans. Iron Steel Inst. Jpn., 1971, vol. 11, pp. 250–59.

    CAS  Google Scholar 

  16. Y. Ohmori, H. Ohtani, and T. Kunitake:Trans. Iron Steel Inst. Jpn., 1972, vol. 12, pp. 146–54.

    CAS  Google Scholar 

  17. L.J. Habraken and M. Economopoulos:Transformation and Hardenability in Steels, Climax Molybdenum Co., Ann Arbor, MI, 1967, pp. 69–107.

    Google Scholar 

  18. D.V. Edmonds:Metals Handbook, 9th ed., ASM, Metals Park, OH, 1985, vol. 9, pp. 662–67.

    Google Scholar 

  19. H.N. Lander, Y.E. Smith, and J.L. Michelich:Trans. Iron Steel Inst. Jpn., 1974, vol. 14, pp. 419–24.

    CAS  Google Scholar 

  20. J.V. Bee and D.V. Edmonds:Metallography, 1979, vol. 12, pp. 3–21.

    Article  CAS  Google Scholar 

  21. D.V. Edmonds and R.W.K. Honeycombe:J. Iron Steel Inst., 1973, vol. 24, pp. 209–16.

    Google Scholar 

  22. Microalloying '75, Proc. Int. Symp., Washington, DC, 1975, Union Carbide Corp., New York, NY, 1977.

  23. Y.E. Smith and C.A. Seibert:Metall. Trans., 1971, vol. 2, pp. 1711–25.

    CAS  Google Scholar 

  24. M. Civallero, C. Parrini, and A. Pizzimenti:Aust. Weld. Res. Assoc, 1973, Preprint 3.

  25. G.S. Barritte: Ph.D. Dissertation, University of Cambridge, Cambridge, 1982.

  26. J.R. Yang and H.K.D.H. Bhadeshia: inAdvances in Welding Science & Technology, S.A. David, ed., ASM, Metals Park, OH, 1986, pp. 187–91.

    Google Scholar 

  27. K.J. Irvine and F.B. Pickering:J. Iron Steel Inst., 1958, vol. 188, p. 101; The Physical Properties of Martensite and Bainite, Iron and Steel Institute, London, Spec. Rep. No. 93, 1965, pp. 110–25.

    CAS  Google Scholar 

  28. F.B. Pickering:Microalloying '75, Proc. Int. Symp., Washington, DC, 1975, Union Carbide Corp., New York, NY, 1977, pp. 9–31.

    Google Scholar 

  29. F.B. Pickering:Transformation and Hardenability in Steels, Climax Molybdenum Co., Ann Arbor, MI, 1967, pp. 109–29; Discussion, p. 130.

    Google Scholar 

  30. R.W.K. Honeycombe and F.B. Pickering:Metall. Trans., 1972, vol. 3, pp. 1099–1112.

    Article  CAS  Google Scholar 

  31. T. Gladman, B. Holmes, and I.D. Mclvor:The Effects of Second Phase Particles on the Mechanical Properties of Steels, Iron and Steel Institute, London, 1971, pp. 68–78.

    Google Scholar 

  32. T. Gladman, D. Dulieu, and I.D. Mclvor:Microalloying '75, Proc. Int. Symp., Washington, DC, 1975, Union Carbide Corp., New York, NY, 1977, pp. 32–55.

    Google Scholar 

  33. T. Gladman and F.B. Pickering: inYield, Flow and Fracture of Polycrystals, T.N. Baker, ed., Applied Science Publishers, Essex, United Kingdom, 1983, pp. 141–98.

    Google Scholar 

  34. J.A. Whiteman:Low Carbon Structural Steels for the Eighties, Institution of Metallurgists, London, 1977, pp. 11–17.

    Google Scholar 

  35. P. Brozzo, G. Buzzichelli, A. Mascanzoni, and M. Mirabile:Met. Sci., 1977, vol. 11, pp. 123–29.

    Article  CAS  Google Scholar 

  36. T. Kunitake:Trans. Iron Steel Inst. Jpn., 1967, vol. 7, pp. 254–62.

    CAS  Google Scholar 

  37. M.J. Roberts:Metall. Trans., 1970, vol. 1, pp. 3287–94.

    CAS  Google Scholar 

  38. J.E. Roberts:Rosenhain Centenary Conf., Royal Society, London, 1975, pp. 22–24.

    Google Scholar 

  39. R.R. Preston and P.S. Mitchell:Controlled Processing of HSLA Steels, British Steel Product Technology Conf., York, 1976, Paper 11.

    Google Scholar 

  40. L.A. Norstrom:Scand J. Metall., 1976, vol. 5, pp. 159–65.

    CAS  Google Scholar 

  41. D. Lonsdale and P.E.J. Flewitt:Metall. Trans. A, 1978, vol. 9A, pp. 1619–23.

    CAS  Google Scholar 

  42. J.P. Naylor and R. Blondeau:Metall. Trans. A, 1976, vol. 7A, pp. 891–94.

    CAS  Google Scholar 

  43. J.P. Naylor:Grain Boundaries, Institution of Metallurgists, London,1976, pp. F13–17;Metall. Trans. A, 1979, vol. 10A, pp. 861–73.

    Google Scholar 

  44. R.A. Grange:Trans. ASM, 1966, vol. 59, pp. 26–48.

    CAS  Google Scholar 

  45. J.S. Irani: British Iron and Steel Research Association Rep. No. MG/A/60/67, BISRA, London, 1967.

  46. R.H. Edwards and N.F. Kennon:Metall. Trans. A, 1978, vol. 9A, pp. 1801–09.

    CAS  Google Scholar 

  47. J.R. Yang: Ph.D. Dissertation, University of Cambridge, Cambridge, 1987.

  48. G. Langford and M. Cohen:Trans. ASM, 1969, vol. 62, pp. 623–38.

    CAS  Google Scholar 

  49. K.R. Kinsman and H.I. Aaronson: (discussion to Ref. 12)Transformation and Hardenability in Steels, Climax Molybdenum Co., Ann Arbor, MI, 1964, pp. 33–38.

    Google Scholar 

  50. P. Vasudevan, L.W. Graham, and H.J. Axon:J. Iron Steel Inst., 1958, vol. 190, pp. 386–91.

    CAS  Google Scholar 

  51. H.K.D.H. Bhadeshia and A.R. Waugh:Acta Metall., 1982, vol. 30, pp. 775–84.

    Article  CAS  Google Scholar 

  52. I. Stark: D.Phil. Dissertation, University of Oxford, Oxford, 1988.

  53. C.E. Lacy and M. Gensamer:Trans. ASM, 1944, vol. 32, p. 88.

    Google Scholar 

  54. R.W.K. Honeycombe:Structure and Strength of Alloy Steels, Climax Molybdenum Co., Ann Arbor, MI, 1974.

    Google Scholar 

  55. I.D. Mclvor: British Steel Research Rep. No. PROD/PM/ 6498/-/72/A, British Steel, London, 1972.

  56. Y. Tomita and K. Okabayashi:Metall. Trans. A, 1985, vol. 16A, pp. 73–82.

    CAS  Google Scholar 

  57. Y. Tomita and K. Okabayashi:Metall. Trans. A, 1985, vol. 16A, pp. 83–91.

    CAS  Google Scholar 

  58. Y. Tomita and K. Okabayashi:Metall. Trans. A, 1986, vol. 17A, pp. 1203–08.

    CAS  Google Scholar 

  59. H. Ohtani, F. Terasaki, and T. Kunitake:Trans. Iron Steel Inst. Jpn., 1972, vol. 12, p. 118.

    Google Scholar 

  60. S. Matsuda, T. Inoue, H. Mimura, and Y. Okamura:Trans. Iron Steel Inst. Jpn., 1972, vol. 12, pp. 325–33.

    CAS  Google Scholar 

  61. Y. Ohmori, H. Ohtani, and T. Kunitake:Met. Sci., 1974, vol. 8, p. 357.

    Article  CAS  Google Scholar 

  62. S. Tanaka, S. Tani, and C. Ouchi:Trans. Iron Steel Inst. Jpn., 1975, vol. 15, pp. 19–26.

    CAS  Google Scholar 

  63. J.P. Naylor and P.R. Krahe:Metall. Trans., 1974, vol. 5, pp. 1699–1701.

    Article  CAS  Google Scholar 

  64. P. Bowen: Ph.D. Dissertation, University of Cambridge, Cambridge, 1984.

  65. J. Heslop and N.J. Petch:Phil. Mag., 1958, vol. 3, pp. 1128–36.

    Article  Google Scholar 

  66. F.B. Pickering and K.W. Burns:J. Iron Steel Inst., 1964, vol. 202, p. 899.

    Google Scholar 

  67. A.J. McEvily, R.G. Davies, C.L. Magee, and T.L. Johnston:Transformation and Hardenability in Steel, Climax Molybdenum Co., Ann Arbor, MI, 1967, pp. 179–91.

    Google Scholar 

  68. H. Martensson:Scand. J. Metall., 1972, vol. 1, pp. 319–26.

    CAS  Google Scholar 

  69. T. Terazawa:Towards Improved Ductility and Toughness, Climax Molybdenum Co., Ann Arbor, MI, and Japan Institute of Metals, 1971, p. 101.

    Google Scholar 

  70. H. Nakawugi, H. Matsuda, and H. Tamehiro:Alloys for the 80's, Climax Molybdenum Co., Ann Arbor, MI, 1979, p. 213.

    Google Scholar 

  71. H.K.D.H. Bhadeshia and D.V. Edmonds:Met. Sci., 1983, vol. 17, pp. 411–19.

    Article  CAS  Google Scholar 

  72. H.K.D.H. Bhadeshia and D.V. Edmonds:Met. Sci., 1983, vol. 17, pp. 420–25.

    Article  CAS  Google Scholar 

  73. V.T.T. Miihkinen and D.V. Edmonds:Mater. Sci. Technol., 1987, vol. 3, pp. 441–49.

    CAS  Google Scholar 

  74. V. Biss and R.L. Cryderman:Metall. Trans., 1971, vol. 2, pp. 2267–76.

    CAS  Google Scholar 

  75. G.T. Eldis, A.P. Coldren, and F.B. Fletcher:Alloys for the 80's, Climax Molybdenum Co., Ann Arbor, MI, 1979, p. 35.

    Google Scholar 

  76. Y.E. Smith, A.P. Coldren, and R.L. Cryderman:Towards Improved Ductility and Toughness, Climax Molybdenum Co., Ann Arbor, MI, 1971.

    Google Scholar 

  77. C. Shiga:Steels for Linepipe and Pipeline Fittings, Institute of Metals/Vanitec, London, 1981.

    Google Scholar 

  78. Y. Ito and M. Naganishi:Sumitomo Search, 1976, No. 15.

  79. M. Strang Wood and H.K.D.H. Bhadeshia: inAdvances in Welding Science and Technology, S.A. David, ed., ASM, Metals Park, OH, 1986, pp. 209–13.

    Google Scholar 

  80. G. Thewlis:Welding and Performance of Pipelines, The Welding Institute, Nov. 1986, Paper 9.

  81. J.G. Garland and P.R. Kirkwood:Met. Constr., 1975, vol. 7, pp. 275–83 and 320–30.

    CAS  Google Scholar 

  82. P. Bowen, S.G. Druce, and J.F. Knott:Acta Metall., 1986, vol. 34, pp. 1121–31.

    Article  CAS  Google Scholar 

  83. H.G.A. Bates and K.A. Ridal:Creep, Inst. Mech. Eng., London, 1963, p. 99.

    Google Scholar 

  84. M.C. Mwphy and G.D. Branch:J. Iron Steel Inst., 1969, vol. 207, p. 1347.

    Google Scholar 

  85. J. Barford and G. Willoughby:Met. Sci. J., 1971, vol. 5, p. 32.

    Article  CAS  Google Scholar 

  86. C.J. Middleton: Central Electricity Research Laboratories, Leatherhead, United Kingdom, private communication, 1988.

  87. D.A. Canonico:Towards Improved Ductility and Toughness, Climax Molybdenum Co., Ann Arbor, MI, 1971, pp. 131–47.

    Google Scholar 

  88. V.F. Zackay and E.R. Parker:Low Alloy Steels for Thick Wall Pressure Vessels, CONF 791014, Gaithersburg, MD, 1979, U.S. Department of Energy.

    Google Scholar 

  89. G.E. Kerns, M.T. Wang, and R.W. Staehle: inStress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys, NACE-5, R.W. Staehle, ed., NACE, Houston, TX, 1977, pp. 700–35.

    Google Scholar 

  90. T. Fujita and Y. Yamada: inStress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys, NACE-5, R.W. Staehle, ed., NACE, Houston, TX, 1977, pp. 736–46.

    Google Scholar 

  91. I.M. Bernstein and A.W. Thompson: inAdvances in Corrosion Science and Technology, M.G. Fontana and R.W. Staehle, eds., Plenum, New York, NY, 1980, vol. 7, pp. 53–175.

    Google Scholar 

  92. I.M. Bernstein and A.W. Thompson:Int. Met. Rev., 1976, pp. 269–87.

  93. H.K. Yalci: Oxford University, Oxford, unpublished research, 1989.

  94. K.J. Sawley, R. Preston, and R. Pendleton:Bainite, Institute of Metals, London, Discussion Meeting, 1985.

    Google Scholar 

  95. R. Brook and W.R. Callender:Bainite, Institute of Metals, London, Discussion Meeting, 1985.

    Google Scholar 

  96. G.E. Hollox, R.A. Hobbs, and J.M. Hampshire:Wear, 1981, vol. 68, pp. 229–40.

    Article  CAS  Google Scholar 

  97. F.C. Akbasoglu: D.Phil. Dissertation, Oxford University, Oxford, 1988.

  98. F.C. Akbasoglu and D.V. Edmonds:Metall. Trans. A, 1990, vol. 21A, pp. 889–93.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

This paper is based on a presentation made in the symposium “International Conference on Bainite” presented at the 1988 World Materials Congress in Chicago, IL, on September 26 and 27, 1988, under the auspices of the ASM INTERNATIONAL Phase Transformations Committee and the TMS Ferrous Metallurgy Committee.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Edmonds, D.V., Cochrane, R.C. Structure-property relationships in bainitic steels. Metall Trans A 21, 1527–1540 (1990). https://doi.org/10.1007/BF02672567

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02672567

Keywords

Navigation