Abstract
Singly and doubly doped ZnS phosphors have been synthesized using flux method. Laser-induced photoluminescence has been observed in ZnS-doped phosphors when these were excited by the pulsed UV N2 laser radiation. Due to down-conversion phenomenon, fast phosphorescence emission in the visible region is recorded in milliseconds time domain for ZnS:Mn while in the case of ZnS:Mn:killer (Fe, Co and Ni) the lifetime reduces to microseconds time domain. Experimentally observed luminescent emission parameters of excited states such as, lifetimes, trap-depth values and decay constants have been reported here at room temperature. The high efficiency and fast recombination times observed in doped ZnS phosphors make these materials very attractive for optoelectronic applications.
Similar content being viewed by others
References
A J Warren, C B Thomas and P R C Stevens,J. Phys. D16, 225 (1983)
W Lehmann,J. Lumin. 5, 87 (1972)
H S Bhatti,Indian J. Technol. 26, 595 (1988)
M Pham-Thi,J. Alloys Compounds 225, 547 (1995)
R N Bhargava,J. Lumin. 70, 85 (1996)
R E Imhof and F H Read,Rep. Prog. Phys. 40, 1 (1977)
F Wilkinson and C J Willsher,J. Lumin. 33, 187 (1985)
G A Slack and B M O’Meara,Phys. Rev. 163, 335 (1967)
C R Ronda,J. Lumin. 72–74, 49 (1997)
H S Bhatti, Rajesh Sharma, Sunil Kumar and N K Verma,Indian J. Eng. Mater. Sci. 11, 121 (2004)
Sunil Kumar, Rajesh Sharma, N K Verma and H S Bhatti,Atti-della Fond. G. Ronchi LVIII(2), 797 (2004)
D D Bhawalkar and S C Mehendale,Report on pulsed nitrogen laser (BARC, Bombay, India) BARC/I-434 1976
R H Bube,Phys. Rev. 80, 655 (1950)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bhatti, H.S., Sharma, R. & Verma, N.K. Laser-induced down-conversion parameters of singly and doubly doped ZnS phosphors. Pramana - J Phys 65, 541–546 (2005). https://doi.org/10.1007/BF02704213
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02704213