Abstract
Cadmium doped lead-borate glasses were prepared from the melts in appropriate proportions of PbO2, H3BO3 and (15–40 mol%) CdO mixture in the temperature range 700–950°C. The infrared spectra of the glasses in the range 400–4000 cm-1 show their structures. No boroxol ring formation was observed in the structure of these glasses. Furthermore, doped cadmium atoms were not seen in tetrahedral coordination. But the conversion of three-fold to four-fold coordination of boron atoms in the structure of glasses was observed.
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Alemi, A.A., Sedghi, H., Mirmohseni, A.R. et al. Synthesis and characterization of cadmium doped lead-borate glasses. Bull Mater Sci 29, 55–58 (2006). https://doi.org/10.1007/BF02709356
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DOI: https://doi.org/10.1007/BF02709356