Skip to main content
Log in

Thermal stability of electrochemically prepared polythiophene and polypyrrole

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

The degradation behaviour of electrochemically prepared polythiophene and polypyrrole has been studied by thermal gravimetric analysis technique. Studies on both the polymers show that they are more stable than polyacetylene but still undergo degradation reactions which involve two steps, viz. loss of dopant and then degradation of polymer backbone. The general features of degradation mechanisms are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Cao Y, Wang P and Qian R 1985Macromol. Chem. 186 1093

    Article  CAS  Google Scholar 

  • Chien J C W 1986Proc. PDDG Meeting Univ. Manchester, UK

    Google Scholar 

  • Dall’olio A, Dascola Y, Varacca V and Bocchi V 1968Acad. Sci. Ser. C267 433

    Google Scholar 

  • Diaz A F 1981Chim. Scripta 17 145

    CAS  Google Scholar 

  • Diaz A F, Kanazawa K K and Gardini G P 1979J. Chem. Soc., Chem. Commun. 635

  • Erlandsson R, Inganas O, Lundstorm I and Salanek W R 1985Synth. Metals 10 303

    Article  CAS  Google Scholar 

  • Hahn S J, Gajda W J, Vogelhut P O and Zeller M V 1986Synth. Metals 14 89

    Article  CAS  Google Scholar 

  • Kaneto K, Kohno Y, Yoshino K and Inuishi Y 1983J. Chem. Soc., Chem. Commun. 382

  • Mohammad F 1988 D. Phil. thesis, University of Sussex, UK

    Google Scholar 

  • Mohammad F, Calvert P D and Billingham N C 1989Proc. 2nd CECRI’s Res Conf. on Electrocative Polymers, Karaikudi, India

  • Mohammad F, Calvert P D and Billingham N C 1990Bull. Electrochem. 6 194

    CAS  Google Scholar 

  • Mohammad F, Calvert P D and Billingham N C 1993Bull. Electrochem. 9 109

    CAS  Google Scholar 

  • Mohammad F, Calvert P D and Billingham N C 1994Synth. Metals 66 33

    Article  CAS  Google Scholar 

  • Shirakawa H and Ikeda S 1971Polymer J. 2 231

    Article  CAS  Google Scholar 

  • Shirakawa H, Louis E J, MacDiarmid A G, Chiang C K and Heeger A J 1977J. Chem. Soc., Chem. Commun. 578

  • Street G B, Clark T C, Croumbi M, Kanazawa K K, Lee V, Fluger P, Scott J and Weiser G 1982Mol. Cryst. Liq. Cryst. 83 253

    Article  Google Scholar 

  • Tourillon G and Garnier F 1982J. Electroanal. Chem. 135 173

    Article  CAS  Google Scholar 

  • Wynne K J and Street G B 1985Macromolecules 18 2361

    Article  CAS  Google Scholar 

  • Yang X Z and Chien J C W 1985J. Polym. Sci. Polym. Chem. Ed. 23 859

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mohammad, F., Calvert, P.D. & Billingham, N.C. Thermal stability of electrochemically prepared polythiophene and polypyrrole. Bull. Mater. Sci. 18, 255–261 (1995). https://doi.org/10.1007/BF02749663

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02749663

Keywords

Navigation