Abstract
The effect of carbon ordering on the crystal structure and resistivity of cubic TiCy was studied. The ordering of TiCy below 1020 K was found to yield cubic or trigonal Ti2C or orthorhombic Ti3C2, depending on composition. Temperature-dependent resistivity data for compositions from TiC0.522 to TiC0.62 indicate that the temperature of the reversible equilibrium order-disorder transition ranges from 980 to 1000 K.
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Lipatnikov, V.N., Kottar, A., Zueva, L.V. et al. Ordering effects in nonstoichiometric titanium carbide. Inorg Mater 36, 155–161 (2000). https://doi.org/10.1007/BF02758018
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DOI: https://doi.org/10.1007/BF02758018