Investigations on transient directional solidification under microgravity on sounding rocket missions

Abstract

Transient growth conditions are common to a variety of technical solidification processes and lead to modified materials properties. In directional solidification the microstructure at the solid-liquid interface of an alloy is a result of the interaction of diffusive and convective heat and mass transport in the bulk and of interface and thermophysical properties. We have carried out experiments under diffusive conditions without convection in microgravity during the sounding rocket missions TEXUS-36 and 40. The used transparent alloy succinonitrile-acetone freezes like metals and the solidification process was observed in-situ. Within a gradient furnace the solid-liquid interface is forced to move accelerated and to transform from planar into cellular and dendritic structures. The dynamics of the planar interface and of the spacing and the amplitude of diffusive grown cells and dendrites were observed directly with cameras and analyzed. A comparison of the TEXUS-40 results to predictions taken from a macroscopic thermal model, a coupled heat-mass transfer model and a phase-field model was carried out. A good agreement is found for the planar interface dynamics for the coupled heat-mass transfer model and the phase-field model, when using additional information from the thermal modelling. In the cellular and dendritic growth regime typical microstructure features can be reproduced by the phase-field model. The experimental results thus serve as important bench-marks for the validation of numerical models describing time-dependent solidification processes.