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EPR techniques applied to the study of chemistry and catalysis on oxide surfaces

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Abstract

The use of electron paramagnetic resonance (EPR) spectroscopy to study the chemistry of oxide surfaces and catalysis is discussed. Emphasis is placed on those aspects of the techniques that are directly related to the specificity of heterogeneous systems, investigations of surfaces and catalytic reactions. The characteristic features of EPR spectra of high-surface oxide materials are analyzed, and the typical means employed to increase the amount of extractable information are presented. A brief survey of new potentialities of continuous-wave EPR and typical applications is also provided.

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Sojka, Z., Che, M. EPR techniques applied to the study of chemistry and catalysis on oxide surfaces. Appl. Magn. Reson. 20, 433–456 (2001). https://doi.org/10.1007/BF03162289

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