Abstract
Zircon U-Pb dating is the most commonly used method for isotopic geochronology. However, it has been a difficult issue when relating zircon U-Pb ages to metamorphic conditions in complex metamorphic rocks. Much progress has been made in the past decade with respect to the genesis of zircon and its constraints on interpretation of U-Pb age. Three methods have been proposed to link zircon U-Pb age to metamorphic conditions: (i) internal structure; (ii) trace element feature; (iii) mineral inclusion composition. Magmatic zircon shows typical oscillatory zoning and/or sector zoning, whereas metamorphic zircon has internal structures such as no zoned, weakly zoned, cloudy zoned, sector zoned, planar zoned, and patched zoned ones. Zircons formed in different geological environments generally have characteristic internal structures. Magmatic zircons from different rock types have variable trace element abundances, with a general trend of increasing trace element abundances in zircons from ultramafic through mafic to granitic rocks. Zircons formed under different metamorphic conditions have different trace element characteristics that can be used to relate their formation to metamorphic conditions. It is an effective way to relate zircon growth to certain P-T conditions by studying the trace element partitioning between coexisting metamorphic zircon and garnet in high-grade metamorphic rocks containing both zircon and garnet. Primary mineral inclusions in zircon can also provide unambiguous constraints on its formation conditions. Therefore, interpretation of zircon U-Pb ages can be constrained by its internal structure, trace element composition, mineral inclusion and so on.
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Lee, J., Williams, I., Ellis, D., Pb, U. and Th diffusion in nature zircon, Nature, 1997, 390(13): 159–162
Cherniak, D. J., Watson, E. B., Pb diffusion in zircon, Chemical Geology, 2000, 172: 5–24.
Compston, W., Williams, I. S., Kirschvink, J. L. et al., Zircon U-Pb ages for the Early Cambrian time-scale, J. of Geological Society, London, 1992, 149: 171–184.
Ireland, T. R., Williams, I. S., Considerations in zircon geochronology by SIMS, Zircon Reviews in Mineralogy and Geochemistry, 2003, 53: 215–238.
Williams, I. S., U-Th-Pb geochronology by ion microprobe, in Applications of Microanalytical Techniques to Understanding Mineralizing Processes (eds. McKibben, M. A., Shanks, W. C., Ridley, W. I.), Review of Economical Geology, 1998, 7: 1–35.
Liang, X., Li, X., Liu, Y., Simultaneous determination of U-Pb ages and trace elements in single zircon by using LAM-ICP-MS, Rock and Mineral Analysis (in Chinese with English abstract), 1999, 18(4): 253–258.
Yuan Honglin, Wu Fuyuan, Gao Shan et al., LA-ICPMS zircon U-Pb dating and REE analysis from Cenozoic intrusions in northeast region, China, Chinese Sci. Bull., 2003, 48(22): 2411–2421.
Feng, R., Machado, N., Ludden, J., Lead geochronology of zircon by laser-inductively coupled plasma mass spectrometry (ICP-MS), Geochim. Cosmochim. Acta, 1993, 57: 3479–3486.
Fryer, D., Jackson, S., Longerich, H., The application of laser ablation micro-probe-inductively couple plasma mass spectormetry (LAM-ICP-MS) toin situ (U)-Pb geochronology, Chemical Geology, 1993, 109: 1–8.
Horn, I., Rudnick, R. L., Mcdonough, W. F., Precise element and isotope ratio measurement by simultaneous solution nebulisation and laser ablation-ICP-MS: Application to U-Pb geochronology, Chem. Geol., 2000, 164: 281–301.
Kosler, J., Sylvester, P. J., Present trends and the future of zircon in geochronology: Laser ablation ICPMS, Zircon. Reviews in Mineralogy and Geochemistry, 2003, 53: 243–271.
Hanchar, J. M., Hoskin, P. W. O., Zircon, Reviews in Mineralogy and Geochemistry, 2003, 53: V-VII.
Müller, W., Strengthening the link between geochronology, textures and petrology, Earth and Planetary Science Letters, 2003, 206: 237–251.
Gebauer, D., Schertl, H. P., Brix, M. et al., 35 Ma old ultrahighpressure metamorphism and evidence for very rapid exhumation in the Dora Maira Massif, Wester Alps. Lithos., 1997, 41: 5–24.
Hacker, B. R., Ratshbacher, L., Webb, L. et al., U/Pb zircon ages constrain the architecture of the ultrahigh-pressure Qinling-Dabie Orogen, China. Earth Planet Sci. Lett., 1998, 161: 215–230.
Hermann, J., Rubatto, D., Korsakov, A., Multiple zircon growth during fast exhumation of diamondiferous, deeply subducted continental crust (Kokchetav Massif, Kazakhstan), Contrib. Mineral Petrol., 2001, 141: 66–82.
Katayama, I., Maruyama, S., Parkinson, C. D., Ion micro-probe U-Pb zircon geochronology of peak and retrograde stages of ultrahigh-pressure metamorphic rocks from the Kokchetav massif, northern Kazakhstan, Earth and Planetary Science Letters, 2001, 188: 185–198.
Mojzsis, S. J., Harrison, T. M., Pidgeon, R. T., Oxygen isotope evidence from ancient zircons for liquid water at the earth’s surface 4300 Myr ago, Nature, 2001, 409: 178–181.
Rubatto, D., Gebauer, D., Fanning, M., Jurassic formation and Eocene subductions for the geodynamic evolution of the Central and Western Alps, Contrib. Mineral. Petrol., 1998, 132: 269–287.
Rubatto, D., Gebauer, G., Compagnoni, R., Dating of eclogitefacies zircons: the age of Alpine metamorphism in the Sesia-Lanzo Zone (Western Alps), Earth and Planetary Science Letters, 1999, 167: 141–158.
Rubatto, D., Williams, I. S., Imaging, trace element geochemistry and mineral inclusions: linking U-Pb ages with metamorphic conditions, EOS, 2000, 21: 25.
Rubatto, D., Zircon trace element geochemistry: partitioning with garnet and the link between U-Pb ages and metamorphism, Chemical Geology, 2002, 184: 123–138.
Rubatto, D., Hermann, J., Zircon formation during fluid circulation in eclogites (Monviso, Western Alps): Implications for Zr and Hf budget in subduction zones, Geochimica et Cosmochimica Acta, 2003, 67(12): 2173–2187.
Schaltegger, U., Fanning, C. M., Gunther, D. et al., Growth, annealing and recrystallization of zircon and preservation of monazite in high-grade metamorphism: conventional andin-situ U-Pb isotope, cathodoluminescence and microchemical evidence, Contrib. Mineral Petrol., 1999, 134: 186–201.
Vavra, G., Gebauer, D., Schmid, R., Multiple zircon growth and recrystallization during polyphase Late Carboniferous to Triassic metamorphism in granulites of the Ivrea Zone (Southern Alps): an ion microprobe (SHRIMP) study, Contrib. Mineral Petrol., 1996, 122: 337–358.
Vavra, G., Schmid, R., Gebauer, D., Internal morphology, habit and U-Th-Pb microanalysis of amphibole to granulite facies zircon: geochronology of the Ivren Zone(Southern Alps), Contrib. Mineral Petrol., 1999, 134: 380–404.
Whitehouse, M. J., Kamber, B. S., On the overabundance of light rare earth elements in terrestrial zircons and its implication for Earth’s earliest magmatic differentiation, Earth and Planetary Science Letters, 2002, 204: 333–346.
Whitehouse, M. J., Platt, J. P., Dating high-grade metamorphismconstraints from rare-earth elements in zircons and garnet, Contrib. Mineral Petrol., 2003, 145: 61–74.
Wilde, S. A., Valley, J. W., Peck, W. H. et al., Evidence from detrital zircons for the existence of continental crust and oceans on the Earth 4.4 Gyr ago, Nature, 2001, 409: 175–178.
Pidgeon, R. T., Nemchin, A. A., Hitchen, G. J., Internal structures of zircons from Archaean granites from the Darling Range batholith: implications for zircon stability and the interpretation of zircon U-Pb ages, Contrib. Mineral Petrol., 1998, 132: 288–299.
Nasdala, L., Wenzel, M., Vavra, G. et al., Metamictization of natural zircon: accumulation versus thermal annealing of radioactivity-induced damage, Contrib. to Mineral. and Petrol., 2001, 141: 125–144.
Hanchar, J. M., Miller, C. F., Zircon zonation patterns as revealed by cathodoluminescence and backscattered electron images: Implications for interpretation of complex crustal histories, Chemical Geology, 1993, 110: 1–13.
Hanchar, J. M., Rudnick, R. L., Revealing hidden structures: the application of cathodoluminescence and back-scatter electrical imaging to dating zircons from lower crustal xenoliths, Lithos., 1995, 36: 289–303.
Crofu, F., Hanchar, J. M., Hoskin, P. W. O. et al., Atlas of zircon textures, Reviews in Mineralogy and Geochemistry, 2003, 53: 469–495.
Rubatto, D., Gebauer, D., Use of Cathodoluminescence for U-Pb Zircon Dating by IOM Microprobe: Some Examples from the Western Alps, Cathodoluminescence in Geoscience, Berlin, Heidelberg: Springer-Verlag, 2000, 373–400.
Zhao, Zifu, Zheng Yongfei, Wei Chunsheng ET AL., Zircon U-Pb age, element and isotope geochemistry of mesozoic mafic-ultramafic rocks at Shacun and Jiaoziyan in North Dabie, Geological Journal of China Universities (in Chinese with English abstract), 2003, 9(2): 139–162.
Hoskin, P. W. O., Schaltegger, U., The composition of zircon and igneous and metamorphic petrogenesis, Zircon. Reviews in Mineralogy and Geochemistry, 2003, 53: 27–55.
Belusova, E., Griffin, W., Pearson, N. J., Trace element composition and cathodoluminescence properties of southern African kimberlitic zircons, Mineral Mag., 1998, 62: 355–366.
Konzett, J., Armstrong, R. A., Sweeny, R. J. et al., The timing of MARID metasomatism in the Kaapvaal mantle: an ion probe study of zircons from MARID xenoliths, Earth Planet Sci. Lett., 1998, 160: 133–145.
Guo, J., O’Reilly, S. Y., Griffin, W. L., Zircon inclusions in corundum megacrystals, 1. Trace element geochemistry and clues to the origin of corundum megacrysts in alkali basalts, Geochem CosmochimActa, 1996, 60: 237–269.
Upton, B. G. J., Hinton, R. W., Aspen, P. et al., Megacrysts and associated xenoliths: evidence for migration of geochemically enriched melts in the upper mantle beneath Scotland, J. Petrol., 1999, 40: 935–956.
Keay, S., Lister, G., Buick, I., The timing of partial melting, Barrovian metamorphism and granite intrusion in the Naxos metamorphic core complex, Cyclades, Aegean Sea, Greece, Tectonophysics, 2001, 342: 275–312.
Roberts, M., Finger, F., Do U-Pb zircon ages from granulites reflect peak metamorphic conditions? Geology, 1997, 25(4): 319–322.
Bingen, B., Austrheim, H., Whitehouse, M., Ilmenite as a source for zirconium during high-grade metamorphism? Textural evidence from the Caledonides of Western Norway and implications for zircon geochronology, J. Petrol., 2001, 42(2): 355–375.
Fraser, G., Ellis, D., Eggins, S., Zirconium abundance in granulite-facies minerals, with implications for zircon geochronology in high-grade rocks, Geology, 1997, 25(7): 607–610.
Dubinskaa, E., Bylinab, P., Kozlowskia, A. et al., U-Pb dating of serpentinization: hydrothermal zircon from a metasomatic rodingite shell (Sudetic ophiolite, S W Poland), Chemical Geology, 2004, 203: 183–203.
Liati, A., Gebauer, D., Constraining the pregrade and regrade P-T-t path of Eocene HP rocks by SHRIMP dating difference zircon domain: inferred rated of heating-burial, cooling and exhumation for central Rhodope, northern Greece, Contrib. Minern. Petrol., 1999, 135: 340–354.
Geisler, T., Ulonska, M., Schleicher, H. et al., Leaching and differential recrystallization of metamict zircon under experimental hydrothermal conditions, Chemical Geology, 2001, 141: 53–65.
Hoskin, P. W. O., Black, L. P., Metamorphic zircon formation by solid-state recrystallization of protolith igneous zircon, J. Metamorphic Geol., 2000, 18: 423–439.
Pidgeon, R. T., Recrystallization of oscillatory-zoned zircon: some geochronological and petrological implications, Contrib. Mineral Petrol., 1992, 110: 463–472.
Rizvanova, N. G., Lenchenkov, O. A., Belous, A. E. et al., Zircon reaction and stability of the U-Pb isotope system during the interaction with carbonate fluid: experimental hydrothermal study, Contrib. Mineral Petrol., 2000, 139: 101–134.
Tomaschek, F., Kennedy, A. K., Villa, I. M. et al., Zircons from Syros, Cyclades, Greece-recrystallization and mobilization of zircon during high-pressure metamorphism, Jour. of Petrology, 2003, 44(11): 1977–2002.
Liati, A., Gebauer, D., Wysoczanski, R., U-Pb SHRIMP-dating of zircon domains from UHP garnet-rich mafic rocks and late pegmatoids in the Rhodope zone (N Greece): evidence for Early Cretaceous crystallization and Late Cretaceous metamorphism, Chem. Geology, 2002, 184: 281–299.
Möller, A., O’Brien, P. J., Kennedy, A. et al., Linking growth episodes of zircon and metamorphic textures to zircon chemistry: an example from the ultrahigh-temperature granulites of Rogaland (SW Norway), EMU Notes in Mineralogy, 2003, 5: 65–82.
Mezger, K., Krogstad, E. J., Interpretation of discordant U-Pb zircon ages: An evaluation, J. Metamorphic Geol., 1997, 15: 127–140.
Rowley, D. B., Xue, F., Tucker, R. D., Ages of ultrahigh pressure metamorphism and protolith orthogneisses from the eastern Dabie Shan: U/Ph zircon geochronology, Earth and Planet Science Letters, 1997, 151: 191–203.
Mojzsis, S. J., Harrison, T. M., Establishment of a 3.83-Ga magmatic age for the Akilia tonalite (southern West Greenland), Earth and Planetary Science Letters, 2002, 202: 563–576.
Wu Yuanbao, Chen Daogong, Xia Qunke et al.,In-situ trace element analyses of zircons from Dabieshan Huangzhen eclogite— Trace element characteristics of eclogite-facies metamorphic zircon, Chin. Sci. Bull., 2002, 47(16): 1398–1401.
Gebauer, D. A., P-T-t path for an (ultra-?) high-pressure ultramafic-mafic rockassociation and its felsic country-rocks based on SHRIMP—Dating of magmatic and metamorphic zircon domains, example: Alpe Arami (Central Swiss Alps), in Earth Processes Reading the Isotopic Code, Geophysical Monograph, 1996, 95: 307–329.
Hidaka, H., Shimizu, H., Adachi, M., U-Pb geochronology and REE geochemistry of zircons from Palaeoproterozoic paragneiss clasts in the Mesozoic Kamiaso conglomerate, central Japan: evidence for an Archean provenance, Chem. Geol., 2002, 187: 278–293.
Belousova, E., Griffin, W., Suzanne, Y., Igneous zircon: trace element composition as an indicator of source rock type, Contrib. Mineral Petrol., 2002, 143: 602–622.
Hermann, J., Allanite: thorium and light rare earth element carrier insubducted crust, Chemical Geology, 2002, 192: 289–306.
Nozhkin, A. D., Turkina, O. M., Radiogeochemistry of the charnokite-granulite complex, Sharyzhalgay Window, Siberian Platform, Geochem. Int., 1995, 32: 62–78.
Rollinson, H. R., Windley, B. F., Selective elemental depletion during metamorphism of Archean granulites, Contrib. Mineral. Petrol., 1980, 72: 257–263.
Hoskin, P. W. O., Ireland, T., Rare earth element chemistry of zircon and its use as a provenance indicator, Geology, 2000, 28(7): 627–630.
Peck, W. H., Valley, J., Wilde, S., Oxygen isotope ratios and rare earth elements in 3.3 to 4.4 Ga zircons: Ion microprobe evidence for highδ18O continental crust and oceans in the Early Archean, Geochimica et Cosmochimica Acta, 2001, 65(22): 4215–4229.
Valley, J. W., Peck, W. H., King, E. M., A cool early Earth, Geology, 2002, 30: 351–354.
Wu Yuanbao, Chen Daogong, Xia Qunke et al.,In-situ trace element analyses and Pb-Pb dating of zircons by LAM-ICP-MS in granulite from Huangtuling, Dabieshan, Science in China, Series D, 2003, 46(11): 1161–1170.
Rubatto, D., Liati, A., Gebauer, D., Dating UHP metamorphism, EMU Notes in Mineralogy, 2003, 5: 341–363.
Rudnick, R., Barth, M., Horn, I., Rutile-bearing refractory eclogites: Missing link between continents and depleted mantle, Science, 2000, 287: 278–281.
Whitehuse, M., Combingin situ zircon REE and U-Th-Pb geochronology: A petrogenetic dating tool, Journal of Conference Abstracts, 2000, 5(2): 1086.
Pidgeon, R. T., O’neil, J. R., Silver, R. T., The interdependence of U-Pb stability, crystallinity and external conditions in natural zircons—an early experimental study, Leon T Silver 70th Birthday Symposium and Celebration, extend abstract, 1995,225–231.
Watson, B., Cherniak, D. J., Hanchar, J. M. et al., The incorporation of Pb into zircon, Chem. Geol., 1997, 141: 19–33.
Liu, F., Xu, Z., Katayama, I., Mineral inclusions in zircons of para- and orthogneiss from pre-pilot drillhole CCSD-PP1,Chinese Continental Scientific Drilling Project, Lithos, 2001a, 59: 199–215.
Liu, J., Ye, K., Maruyama, S., Mineral inclusions in zircon from gneisses in the Ultrahigh-pressure zone of the Dabie Mountains, China, Journal of Geology, 2001b, 109: 523–535.
Tabata, H., Yamauchi, K., Maruyama, S., Tracing the extent of a UHP metamorphic terrane: mineral-inclusion study of zircons in gneisses from the Dabie Shan, in When Continents Collide: Geodynamics and Geochemistry of Ultra-High-Pressure Rocks (eds. Hacker, B., Liou, J.), Dordrecht: Kluwer, 1998, 261–274.
Ye, K., Yao, Y., Katayama, I., Large areal extent of ultrahigh-pressure metamorphism in the Sulu ultrahigh-pressure terrane of East China: new implications from coesite and omphacite inclusions in zircon of granitic geiss, Lithos, 2000, 52: 157–164.
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Wu, Y., Zheng, Y. Genesis of zircon and its constraints on interpretation of U-Pb age. Chin.Sci.Bull. 49, 1554–1569 (2004). https://doi.org/10.1007/BF03184122
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DOI: https://doi.org/10.1007/BF03184122