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Synthesis and characterization of novel polyurethanes based on 4-{(4-hydroxyphenyl)iminomethyl}phenol

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Abstract

Four novel polyurethanes were prepared from 4-{(4-hydroxyphenyl)iminomethyl}phenol by reactions with two aromatic diisocyanates, 4,4′-diphenylmethane diisocyanate and toluene 2,4-diisocyanate, and two aliphatic diisocyanates, isophorone diisocyanate and hexamethylene diisocyanate. The polyurethanes formed were characterized by UV-vis, fluorescence, FT-IR,1H-NMR,13C-NMR, differential scanning calorimetry, thermogravimetry, and X-ray diffraction. The polymers were semi-crystalline and all polymers were soluble in polar aprotic solvents.

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Authors and Affiliations

  1. Department of Chemistry, University of Ulsan, 680-749, Ulsan, Korea

    A. V. Raghu, Han Mo Jeong, Jae Hoon Kim, Yu Rok Lee & Youn Bok Cho

  2. Center for Liquid Crystal Research, 560 013, Jalahalli, Bangalore, India

    Kiran Sirsalmath

Authors
  1. A. V. Raghu
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  2. Han Mo Jeong
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  3. Jae Hoon Kim
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  4. Yu Rok Lee
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  5. Youn Bok Cho
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  6. Kiran Sirsalmath
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Correspondence to A. V. Raghu or Han Mo Jeong.

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Raghu, A.V., Jeong, H.M., Kim, J.H. et al. Synthesis and characterization of novel polyurethanes based on 4-{(4-hydroxyphenyl)iminomethyl}phenol. Macromol. Res. 16, 194–199 (2008). https://doi.org/10.1007/BF03218852

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  • DOI: https://doi.org/10.1007/BF03218852

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