Summary
The refining of blister copper prior to casting into anodes consists of oxidizing the copper melt to remove sulfur and then reducing its oxygen content. The age-old “wood poling” technique for deoxidation is gradually being replaced by the injection of reducing gases through one or two tuyeres.
Thermodynamic and mass transfer analysis as well as laboratory tests have shown that the operating efficiency of gas injection can be improved considerably by enhancing mixing and gas-liquid mass transfer conditions within the copper bath. The injection of inert gas through porous plugs offers a viable industrial means for effecting such an improvement.
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References
G. Agricola, De Re Metallica, Dover Publication, New York (1950).
L. Klein, “Gaseous Reduction of Oxygen-Containing Copper,” J. Metl. 13(8) (1961), pp. 545–547.
C. R. Kuzell, M. G. Fowler, D. L. Klein, and J. H. David, “Gaseous Reduction of Oxygen-Containing Copper,” U.S. Patent No. 2,989,397, June 20, 1961.
J. B. Huttl, “Poling Becomes Ancient History at Phelps Dodge Smelters,” Engineering and Mining Journal, 162(7) (1961), pp. 82–85.
F. E. Brantley, and C. H. Schack, “Deoxidation of Blister Copper by Gaseous Reduction,” U.S. Bureau of Mines Report of Investigations 6113 (1962).
G. A. Komlev, O. V. Levkovskii, and A. V. Shirokov, “Reduction of Liquid Oxidized Copper with Natural Gas,” Tsvetnye Metally, 5(9) (1964), pp. 15–16.
R. Henych, F. Kadlec, and V. Sedlacek, “Copper Refining by Gaseous Ammonia,” J. Met., 17(4) (1965), pp. 386–388.
T. Ito, “Pyrometallurgical Refining Process for Copper,” Canadian Patent No. 722,592, November 30, 1965.
M. P. Makhov, I. M. Piskunov, A. I. Stezhenskii, Ya. G. Prazhennik, O. G. Miller, and I. G. Bannikov, “Natural Gas Conversion Methods and Ways to Use Them When Producing Heavy Non-Ferrous Metals,” Tsvetnye Metally, 8 (1967), pp. 78–81.
T. A. Web, “Can Copper Producers Get Rid of That Clumsy Poling Step,” Engineering and Mining Journal, 169(9) (1968), p. 143.
L. E. Mulholland, “Reduction of Copper Through the Use of Propane,” Paper presented at the AIME Annual Meeting, Washington, D.C., February 1969.
N. J. Themelis and P. R. Schmidt, “Process for Gaseous Deoxidation of Copper,” U.S. Patent No, 3,604,698, September 14, 1971.
A. Yazawa and T. Azakami, “Thermodynamics of Removing Impurities During Copper Smelting,” Canadian Metallurgical Quarterly, 8(3) (1969), p. 257.
K. Sano, and H. Sakao, “Thermodynamical Considerations For the Experimental Results of the Equilibrium Between Liquid Cu and CO-CO2-SO2 Gas Mixtures,” J. Japan Institute of Metals, 19 (1955), pp. 655–659.
J. P. Coughlin, U.S. Bur. Mines, Bull. No. 542 (1954).
O. Kubaschewski, and C. B. Alcock, Metallurgical Thermochemistry, 5th edition, Pergamon, Oxford, (1979).
G. K. Sigworth, and J. F. Elliott, “The Thermodynamics of Dilute Liquid Copper Alloys,” Canadian Metallurgical Quarterly, 13,(3) (1976).
R. B. Mullen, and P. Stubbs, “Argon Stirring at Dofasco,” Iron and Steelmaker, November 1979, p. 21.
N. J. Themelis, and P. Goyal, “Gas Injection in Steelmaking,” Canadian Metallurgical Quarterly, (in press).
G. Denier, J. C. Grosjean, M. LeMaire, F. Schleimer, R. Henrion, and F. Goedert, “Industrial Development of Bottom Gas Injection in Top Blown Converters,” Iron and Steelmaker, August 1980, p. 6.
A. Berthet, G. Denier, and H. Gaye, “Improvement of BOF With Bottom Inert Gas Injections,” 3rd International Iron and Steel Congress, Chicago, April 1979.
C. F. Baes, Jr., and H. H. Kellogg, “Effect of Dissolved Sulfur on the Surface Tension of Liquid Copper,” Trans. AIME, 197 (1953), p. 643.
N. J. Themelis, and P. R. Schmidt, “Deoxidation of Liquid Copper by a Submerged Gas Jet,” Trans. AIME, 239, (1967), p. 1313.
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Goyal, P., Themelis, N.J. & Zanchuk, W.A. Gaseous Refining of Anode Copper. JOM 34, 22–28 (1982). https://doi.org/10.1007/BF03338157
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DOI: https://doi.org/10.1007/BF03338157