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Comparison of SO2 and H2SO4 impregnation of softwood prior to steam pretreatment on ethanol production

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Abstract

The pretreatment of softwood with sulfuric acid impregnation in the production of ethanol, based on enzymatic hydrolysis, has been investigated. The parameters investigated were: H2SO4 concentration (0.5 – 4.4% w/w liquid), temperature (180 – 240°C), and residence time (1-20 minutes). The combined severity (log Ro-pH) was used to combine the parameters into a single reaction ordinate. The highest yields of fermentable sugars, i.e., glucose and mannose, were obtained at a combined severity of 3. At this severity, however, the fermentability declined and the ethanol yield decreased. In a comparison with previous results, SO2 impregnation was found to be preferable, since it resulted in approximately the same sugar yields, but better fermentability.

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References

  1. Torget, R., Werdene, P., Himmel, M., and Grohmann, K. (1990),Appl. Biochem. Biotechnol. 24/25, 115–126.

    Google Scholar 

  2. Martinez, J., Negro, M. J., Saez, F., Manero, J., Saez, R., and Martin, C. (1990),Appl. Biochem. Biotechnol. 24/25, 127–134.

    Google Scholar 

  3. Ropars, M., Marchal, R., Pourquié, J., and Vandecasteele, J. P. (1992)Bioresource. Technol. 42, 197–204.

    Article  CAS  Google Scholar 

  4. Grethlein, H. E. and Converse, A. O. (1991),Bioresource Technol. 36, 77–82.

    Article  CAS  Google Scholar 

  5. Ramos, L. P., Breuil, C, and Saddler, J. N. (1992),Appl. Biochem. Biotechnol. 34/35, 37–48.

    Google Scholar 

  6. Gregg, D. J. and Saddler, J. N. (1996),Biotechnol. Bioeng. 51, 375–383.

    Article  CAS  Google Scholar 

  7. Mackie, K. L., Brownell, H. H., West, K. L., and Saddler, J. N. (1985),J. Wood Chem. Technol. 5, 405–425.

    Article  CAS  Google Scholar 

  8. Schwald, W., Breuil, C., Brownell, H. H., Chan M., and Saddler, J. N. (1989),Appl. Biochem. Biotechnol. 20/21, 29–44.

    Article  Google Scholar 

  9. Schwald, W., Smaridge, T., Chan, M., Breuil, C, and Saddler, J. N. (1989), inEnzyme Systems for Lignocellulose Degradation, Coughlan, M. P., ed., Elsevier, New York, pp. 231–242.

    Google Scholar 

  10. Mamers, H. and Menz, D. N. J. (1984),Appita 37, 644–649.

    CAS  Google Scholar 

  11. Clark, T. A., Mackie, K. L., Dare, P. H., and McDonald, A. G. (1989),J. Wood Chem. Technol. 9 135–166.

    Article  CAS  Google Scholar 

  12. Clark, T. A. and Mackie, K. L. (1987),J. Wood Chem. Technol. 7, 373–403.

    Article  CAS  Google Scholar 

  13. Stenberg, K., Tengborg, C., Galbe, M., and Zacchi, G. (1997)J. Chem. Tech. Biotechnol, accepted.

  14. von Sivers, M. and Zacchi, G. (1996),Bioresource. Technol. 56, 131–140.

    Article  Google Scholar 

  15. Overend, R. P. and Chornet, E. (1987),Phil. Trans. R. Soc. London, Series A,321, 523–536.

    Article  CAS  Google Scholar 

  16. Chum, H. L., Johnson, D. K., Black, S. K., and Overend, R. P. (1990),Appl. Biochem. Biotechnol. 24/25, 1–14.

    Google Scholar 

  17. Chum, H. L., Johnson, D. K., and Black, S. K. (1990),Ind. Eng. Chem. Res. 29, 156–162.

    Article  CAS  Google Scholar 

  18. van Walsum, G. P., Allen, S. G., Spencer, M. J., Laser, M. S., Antal, M. J., and Lynd, L. R. (1996),Appl. Biochem. Biotechnol. 57/58, 157–170.

    Google Scholar 

  19. Mandels, M., Andreotti, R., and Roche, C. (1976),Biotechnol. Bioeng. Symp. 6, 21–33.

    CAS  Google Scholar 

  20. Berghem, L. E. R. and Petterson, L. G. (1974), Eur. J. Biochem.46, 295–305.

    Article  CAS  Google Scholar 

  21. Eklund, R., Galbe, M., and Zacchi G. (1995),Bioresource. Eng. 52, 225–229.

    Article  CAS  Google Scholar 

  22. Stenberg, K., Tengborg, C, Galbe, M., Zacchi, G., Palmqvist, E., and Hahn-Hagerdal, B., (1997),Appl. Biochem. Biotechnol., accepted.

  23. Nilvebrant, N.-O., Reimann, A., de Sousa, F., Kleen, M., and Palmqvist, E. (1997) Proc. 9th International Symposium on Wood and Pulping Chemistry, Poster no. 79, Montréal, Canada, June 9 – 12.

  24. Baugh, K. D. and McCarty, P. L. (1988),Biotechnol Bioeng. 31, 50–61.

    Article  CAS  Google Scholar 

  25. Clark, T. A. and Clark, T. A. (1984),J. Chem. Tech. Biotechnol. 34B, 101–110.

    CAS  Google Scholar 

  26. Russel, N. J. and Gould, G. W. (1991),Food Preservatives, Blackie and Son, Glasgow and London.

  27. Taherzadeh, M. J., Niklasson, C., and Lidén, G. (1997),Chem. Eng. Sci. 52, 2653–2659.

    Article  CAS  Google Scholar 

  28. Torget, R., Hatzis, C., Hayward, T. K., Hsu, T.-A., and Philippidis, G. P. (1996),Appl. Biochem. Biotechnol. 57/58, 85–101.

    Google Scholar 

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Tengborg, C., Stenberg, K., Galbe, M. et al. Comparison of SO2 and H2SO4 impregnation of softwood prior to steam pretreatment on ethanol production. Appl Biochem Biotechnol 70, 3–15 (1998). https://doi.org/10.1007/BF02920119

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