Residues of Bagasse (Saccharum officinarum L.), canola (Brassica napus L.) and hemp (Cannabissativa L.) as well as industrial wood chips in various proportions from 0–100% were used as raw materials for the main component of the middle layer in urea formaldehyde bonded particle boards.
The results reveal that most of the investigated mechanical-technological properties of the boards achieved the requirements of EN 312-2 (2003). Only increasing the percentage of canola chips usage in the middle layer to more than 30% negatively affect the internal bond (IB) properties. Comparing the water absorption (WA) and thickness swelling (TS) values, the boards containing up to 50% bagasse and hemp reach similar values to the ones of the reference boards, while increasing the amount of canola leads to more and more disadvantageous WA and TS.
In summary, the results reveal that agri-fibers can be used for making composite panels conforming to the standards (EN 312-2 2003). One possible application for these panels could be the production of furniture.
Hinweise
This article is dedicated to Gerd Wegener on the occasion of his retirement as professor at the Technische Universität München.
1 Introduction
In recent years the importance of wood and waste wood as a source of energy has increased due to soaring energy prices on the one hand. On the other hand, this situation has caused a sharp increase in the price of manufactured materials (EPF 2006).
Agricultural residues are an excellent alternative to using virgin wood chips for many reasons. At present some agricultural residues such as wheat and rice straws, sorghum stalks and some annual plants such as hemp and jute are used as raw materials for pulp and paper production (Rousu and Anttila 2002; Ashori 2006; Schöpper et al. 2009). Moreover numerous studies have been performed to introduce new lignocellulosic resources for paper and wood industries.
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One of the most abundant natural resources is the by-product of the sugar industry, the bagasse (Chen and Negulescu 2002). Bagasse (Saccharum officinarum L.)—a fibrous material—is one of the main by-products of sugarcane manufacturing plants which is obtained after the glucose syrup is leached out of the sugarcane. One developing application for bagasse fibers is in the manufacturing of material products, such as automobile interior trim parts (Mueller et al. 2001; Chen et al. 2003; Rowell and Keany 1991).
Another raw material of interest for the wood industry is canola. Canola (Brassica napus L.) is widely cultivated throughout the world and used as a major oilseed for vegetable oils and biodiesel production. In addition to oil production from the canola seed, the leaves of canola can be used as an animal feed (Banuelos et al. 2002). Thus, it can be concluded that at least 34 million tons of canola stalks are available annually which could be used in various products, including particle boards.
Actually the wood costs are generally rising with demand surpassing supply (Kharazipour 2005). In fact, the international wood-supply balance is now beginning to shift in favor of alternative non-wooden materials, including industrial hemp. Hemp is a plant called Cannabis sativa L. which is the most durable plant that has been used since pre-history for various applications. The hemp plant consists of long, strong fibers. The long fiber is hemp’s best feature, even when ground up it is still two to three times stronger than comparative annual plants fibers (Osburn 1994). Another component of hemp is the sheaves. The sheaves amount to up to 60% of each hemp plant. In the past this material was only used as litter in animal stables. Especially in these studies the sheaves are used to produce particle boards (Karus 2005; Ohlhauser 2005; Cescutti and Müssig 2005; Schöpper et al. 2009). Today the goal of hemp farming is to use it for the production of wood composites (Karus 2005; Ohlhauser 2005).
In light of these changes, hemp sheaves may become increasingly competitive in price relative to wood, particularly since fast-growing tree species such as aspen, poplar and grand fir are the only alternatives to conventional wood sources in northern latitudes such as Europe (Lloyd 1996; Voß and Kharazipour 2010).
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Combining wood with other materials from renewable resources creates new functional properties for wood composites (COST Action E20 2003).
This study is mainly focused on the research of properties with regard to wood chips with different percentages of hemp sheaves, bagasse and canola chips.
2 Materials and methods
2.1 Board manufacturing
Three-layer particle boards with a different percentage of wood chips and annual plant materials were manufactured in the pilot plant of Buesgen-Institute, Department of Molecular Wood-Biotechnology and Technical Mycology, Georg August University of Goettingen. The boards were made in different series from one year old bagasse material, agriculture residues canola chips and hemp sheaves. The chips and sheaves had been stored prior to the particle board manufacturing. They were hammer-milled to reach a size of ca. 6-mm, and were dried in a dry-oven to about 3–4% moisture content (MC). The materials were finally mixed with different combinations of bagasse, canola and hemp and wood chips in the middle layer. The surface layer was of 100% wood chips. Both layers were glued with Urea Formaldehyde (UF) resin from BASF, Germany, formed into mats, and pressed into particle boards at 200 °C (70 cm × 46.5 cm × 2 cm) with target conditions listed in Table 1. For each annual plant material (bagasse, canola and hemp) 15 particle boards were made.
Table 1
Technical information for the manufacture of particle boards with bagasse, canola and hemp material in the middle layer (ML) and 100% wood chips in the surface layer (SL)
Tab. 1
Herstellungsparameter der Spanplatten aus Bagasse, Raps und Hanf in der Mittelschicht und 100 % Holzspänen in der Deckschicht
Material
UF-resin content (%)
Target thickness (mm)
Target density (g/cm3)
Press time (s/mm)
Press temperature (°C)
Percentage of annual plant in combination with wood (middle layer) (%)
ML
SL
1. industrial wood chips
8
10
20
0.7
15
200
90, 80, 70, 50, 0
2. bagasse
8
10
20
0.7
15
200
10, 20, 30, 50, 100
3. canola chips
8
10
20
0.7
15
200
10, 20, 30, 50, 100
4. hemp sheaves
8
10
20
0.7
15
200
10, 20, 30, 50, 100
2.2 Preparation of materials
The materials were industrial wood chips, ordered from Pfleiderer AG, Guetersloh, Germany. The annual plants bagasse (Saccharum officinarum) were received from Iran, hemp (Cannabissativa) from Germany (Nordhanf GmbH) and canola [Brassica Rapa (syn. Brassica campestris)] from an agriculture company from southwest Germany..
Three samples of each series of particle boards were produced. The fibers of the surface layer, in all series, consisted totally of industrial wood. The middle layers were a combination of 10, 20, 30, 50 and 100 percent of bagasse, canola or hemp with industrial wood chips (see Table 1).
2.3 Sample preparation and testing mechanical-technical properties of the particle boards
The samples for various tests were prepared from the experimental boards according to the specifications shown in Table 2.
Table 2
Test criteria, size and number of samples of the produced particle boards
Tab. 2
Testkriterien, Maße und Anzahl der Spanplattenproben
Test
Sample size [mm]
Number of samples for each series
Bending MOE/MOR
50×360×20
9 / 9
Internal Bond (IB) Strength
50×50×20
24
Thickness Swelling (TS)
50×50×20
24
Water absorbance
50×50×20
24
Bending MOE/MOR and internal bond (IB) strengths were tested with a Universal Testing Machine (ZWICK/ ROELL) according to EN-310 and EN-319 standards respectively.
Thickness swelling (TS) tests were done by means of the 24-hour water soaking procedure according to the EN 317 standard. Conditioned samples, square shape, having side lengths of 50 mm ±1 mm for the evaluation of thickness swelling (TS) were prepared according to EN 317 standard.
The measured properties were compared with the corresponding specifications listed in EN 312-2 (2003) for particle boards (category: particle boards for interior fitments including furniture EN 312-2 2003).
3 Results and discussion
3.1 Bending MOE and MOR
MOE and MOR as a function of sample strengths were measured. According to EN 312-2 (2003) the minimum requirement of modulus of rupture (known as bending strength) is 13 N/mm2 (>13 to 20 mm thickness of particle boards). Figure 1 shows the bending properties of the bagasse, hemp, and canola particle boards. Various percentages of bagasse and hemp in the boards obtained higher values than those of boards containing canola. Based on these results, all bagasse, hemp and canola boards fulfill the minimum requirement of the EN standard. Figure 2 shows the modulus of elasticity of the particle boards. Boards containing hemp gained considerably better bending strength than the two other series (canola, bagasse). Based on the results, with a density of 700 kg/m3, the values of boards are higher than those values which are required in EN 312-2 (2003).
Fig. 1
Comparison of the bending strengths of particleboards, containing bagasse, hemp and canola, each in mixture with wood in the middle layer
Abb. 1
Vergleich der Biegefestigkeiten der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holz in der Mittelschicht
Fig. 2
Comparison of bending modulus of particle boards, containing bagasse, hemp and canola, each in mixture with wood in the middle layer
Abb. 2
Vergleich des Elastizitätsmoduls der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holz in der Mittelschicht
×
×
3.2 Internal bond strength (IB)
The bar chart of the IB strength as a function of mechanical strengths is shown in Fig. 3. Similar to the MOE and MOR data, bagasse and hemp’s IB strengths fulfilled the minimum requirement of European standards. In all combinations of bagasse with wood chips in the middle layer the requirements of EN 312-2 (2003) could be highly fulfilled.
Fig. 3
Comparison of Internal Bond Strength of particle boards, containing bagasse, hemp and canola, each in mixture with wood in the middle layer
Abb. 3
Vergleich der Querzugfestigkeiten der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holz in der Mittelschicht
×
The results of the hemp particle boards show the best IBs. They are nearly two times higher than the standard value. The case of this strong difference can be mentioned by the usage of hemp sheaves in the middle layer of the boards. In contrast to hemp sheaves, the use of more than 50% of canola material could not meet the standard value. The achieved value in canola 30% was 0.35 N/mm2, which is the minimum value requirement in EN 312-2.
3.3 Thickness Swelling
The TS and water absorption (WA) data for all series are summarized in Figs. 4 and 5. The values for thickness swelling after immersion in water are shown in Fig. 4. In comparison to the reference, all values from 10% to 30% for the series of hemp and bagasse are very similar (Fig. 4). Increasing usage of canola in the boards’ middle layer shows more and more negative effects.
Fig. 4
Comparison of thickness swelling of particle boards, containing bagasse, hemp and canola, each in mixture with wood after 24 hour soaking
Abb. 4
Vergleich der Dickenquellung der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holz in der Mittelschicht
Fig. 5
Comparison of water absorption of particle boards, containing bagasse, hemp and canola, each in mixture with wood and references after 24 hour soaking
Abb. 5
Vergleich der Wasseraufnahme der Spanplatten jeweils mit Bagasse, Hanf und Raps in Mischung mit Holzspänen und Referenzen nach 24-stündiger Quellung
×
×
The mean WA for hemp series, except in the mixture of 100%, was less than reference value. The WA average for bagasse from 10% to 30% in mixture was lower than the value of the reference. The particle boards with a middle layer mixture of 50% and 100% bagasse were higher than the reference value. All mixtures of canola show higher WA in comparison to all other boards (Fig. 5).
4 Conclusion
These studies show that particle boards with a middle layer of annual plants such as bagasse, hemp and canola in different mixtures with wood chips indicate good mechanical-technological properties. The particle boards made with hemp and bagasse in mixtures of up to 50% fulfill the requirements of EN 312-2 (2003). In the case of hemp sheaves, even the use of 100% is possible. The mechanical-technological properties of particle boards produced with canola chips in mixtures with wood chips did not meet all specifications of EN 312-2 (2003).
The additional measured water absorption and thickness swelling reveal that using hemp and bagasse of up to 50% leads to similar results in comparison to the references. In the presence of canola the TS and WA are poor.
The achieved results of particle boards containing canola show that further investigations for better mechanical-technological properties are necessary. In the same case also the usage of bagasse in higher amounts for the production of particle boards has to be improved.
The main reason for these disadvantages could be the inhomogeneous structure of the milled and sized bagasse and canola chips. Therefore, for future works the use of residues of annual plants should be adapted to the process of producing particle boards.
Open Access
This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
Open AccessThis is an open access article distributed under the terms of the Creative Commons Attribution Noncommercial License (https://creativecommons.org/licenses/by-nc/2.0), which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
