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Contamination of the environmental ecosystems by trace elements from mining activities of Badao bone coal mine in China

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Environmental Geology

Abstract

Bone coal, as a main mining object, can be used by local inhabitants as daily fuel and by local industrial enterprises as industrial fuel in Pinglin County, Shaanxi Province, China. This study reports how the environmental ecosystems have been polluted around the Badao bone coal mine. Geochemical samples (e.g. rock, water, soil, edible plant and animal) were collected. Bone coal from the Badao mine contains Se up to 75 μg/g Se and 28 μg/g Se in ashes after its combustion, with higher contents of other trace elements. Bone coal and its ash seem to be the main geochemical source of trace elements in soils and plants, which may cause contamination of the local environmental ecosystems. Three ways by which soils have been contaminated by these trace elements derived from bone coal are proposed in this paper. Radishes and beans have the ability to accumulate Mo and Se from soils. There is no obvious difference in concentrations of Cu, Cr and F in each plant from the two areas.

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References

  • Ambers RKR, Hygelund BN (2001) Contamination of two Oregon reservoirs by cinnabar mining and mercury amalgamation. Environ Geol 40(6):699–707

    Article  CAS  Google Scholar 

  • Benvenuti M, Mascaro I, Corsini F, Lattanzi P, Parrini P, Tanelli G (1997) Mine waste dumps and heavy metal pollution in abandoned mining district of Boccheggiano (southern Tuscany, Italy). Environ Geol 30(3/4):238–243

    Google Scholar 

  • David CP (2002) Heavy metal concentrations in marine sediments impacted by a mine-tailings spill, Marinduque Island, Philippines. Environ Geol 42:955–965

    Article  CAS  Google Scholar 

  • Fang WX, Wu PW, Zuo JL, Li XF (1995) Environmental geochemical research and suggestion on the ecological agriculture in the Ankang area, Shaanxi Province (in Chinese with English abstract). Geol Explor Non-ferrous Metals 4(5):311–315

    Google Scholar 

  • Fang WX, Wu PW, Li XF (1996) Ecogeochemical research in Ankang Area, Shaanxi Province, China. 30th International Geological Congress, Abstracts, vol 3, 12-4-3, p 44

  • Fang WX, Hu RZ, Wu PW (2002) Influence of black shales in soils and edible plants in the Ankang area, Shaanxi Province, P. R. of China. Environ Geochem Health 24(1):35–46

    Article  CAS  Google Scholar 

  • Finkelman RB (1993) Trace and minor elements in coal. In: Engel MH, Macko SA (eds) Organic geochemistry. Plenum Press, New York, pp 593–605

  • Foos A (1997) Geochemical modeling of coal mine drainage, Summit County, Ohio. Environ Geol 31(3/4):205–210

    Google Scholar 

  • Goodarzi F, Sanei H, Garrett RG, Duncan WF (2003) Accumulation of trace elements on the surface soil around the Trail smelter, British Columbia, Canada. Environ Geol 43:29–38

    Article  Google Scholar 

  • Heikkinen P M, Korkka-Niemi K, Lahti M and Salonen V-P (2002) Groundwater and surface water contamination in the area of the Hitura nickel mine, western Finland. Environ Geol 42:313–329

    Article  CAS  Google Scholar 

  • Jablonska M, Rietmeijer FJM, Janeczek J (2001) Fine-grained barite in coal fly ash from the Upper Silesian industrial region. Environ Geol 40:941–948

    Article  CAS  Google Scholar 

  • Kim JJ, Kim SJ, Tazaki K (2002) Mineralogical characterization of microbial ferrihydrite and schwertmannite, and non-biogenic Al-sulfate precipitates from acid mine drainage in the Donghae mine area, Korea. Environ Geol 42:19–31

    Article  CAS  Google Scholar 

  • Lee JS, Chon HT, Kim JS, Kim KW and Moon HS (1998) Enrichment of potentially toxic elements in areas underlain by black shales and slates in Korea. Environ Geochem Health 20:135–147

    Article  CAS  Google Scholar 

  • Liorens JF, Fernandez-Turiel JL, Querol X (2001) The fate of trace elements in a large coal-fired power plant. Environ Geol 40(4–5):409–416

    Google Scholar 

  • Liu GJ (2000) Experiment of coal leaching and study of the separation of trace elements. Acta Geol Sin 74(2):386-390

    Google Scholar 

  • Loukola-Ruskeeniemi K, Uutela A, Tenhola M, Paukola T (1998) Environmental impact of metalliferous black shales at Talvivaara in Finland, with indication of lake acidification 9000 years ago. J Geochem Explor 64(1–3):395–407

    Google Scholar 

  • Milu V, Leroy JL, Peiffert C (2002) Water contamination downstream from a copper mine in the Apuseni Mountains, Romania. Environ Geol 42:773–782

    Article  CAS  Google Scholar 

  • Minkin JA, Finkelman RB, Thompson CL (1984) Microcharacterization of arsenic- and selenium-bearing pyrite in Upper Freeport coal, Indiana County, Pennsylvania. Scanning Electro Microsc 4:1515–1542

    Google Scholar 

  • Pluta I (2001) Barium and radium discharged from coal mines in the Upper Silesia, Poland. Environ Geol 40(3):345–348

    Article  CAS  Google Scholar 

  • Qi L, Hu J, Deng HL (1999) Determinations of disperse elements in black shale by inductively coupled plasma mass spectrometry. Chin Sci Bull 44(Suppl):173–174

    CAS  Google Scholar 

  • Sharmasarkar S, Vance GF, Cassel-Sharmasarker F (1998) Analysis and speciation of selenium ions in mine environments. Environ Geoly 34(1):31–38

    Article  CAS  Google Scholar 

  • Tang SR, Fang YH (2001) Copper accumulation by Polygonum microcephalum D. Don and Rumex hastatus D. Don from copper mining spoils in Yunnan Province, P.R. China. Environ Geol 40:902–907

    Article  CAS  Google Scholar 

  • Wang JY, Ren DY, Xu DW, Zhao F H (1999) Advances in the studies of selenium in coal (in Chinese with English abstract). Coal Geol Explor 2:16–18

    Google Scholar 

  • Wang Q, Shi JA, Chen GJ, Xue LH (2003) Environmental effects induced by human activities in arid Shiyang River basin, Gansu province, northwest China. Environ Geol 43:219–227

    Article  Google Scholar 

  • Wen HJ, Qiu YZ (1999) Geological setting of some classical selenium-bearing formations in China. Chin Sci Bull 44(Suppl):185–186

    CAS  Google Scholar 

  • Wright RJ, Codling EE, Stuczynski T, Siddaramappa R (1998) Influence of soil-applied coal combustion by-products on growth and elemental composition of annual ryegrass. Environ Geochem Health 20:11–18

    CAS  Google Scholar 

  • Xiao TF, Boyle D, Guha JYT, Hong YT, Zheng BS (1999) Hydrogeochemistry of toxic metals in Au-As-Hg-Tl mineralized area in southwest Guizhou Province, China. Chin Sci Bull 44(Suppl):171–172

    CAS  Google Scholar 

  • Yan CL, Hong YT, Wang SJ, Lin P, Yang XK, Fu SZ, Zhu KY, Wu SQ (1999) Effect of Pb, Hg and Cd in soil on scavenging system of activated oxygen in tobacco leaves. Chin Sci Bull 44(Suppl):93–93

    Google Scholar 

  • Zhang AY, Wu DM, Guo L, Wang YL (1987) The geochemistry of marine black shale formation and its metallogenic significance (in Chinese with English abstract). Sci Publ Hou, Beijing, pp 1–39

  • Zheng XL, Wang BC (2000) A new geochemical reaction model for groundwater systems. Acta Geologica Sinca (English ed.) 74(2): 339–343

    Google Scholar 

  • Zheng BS, Hong YT, Zhao W (1992) The Se-rich carbonaceous siliceous rock and endemic selenosis in southwest Hubei China. Chin Sci Bull 37(20): 725–1726

    Google Scholar 

  • Zhu JM, Zheng BS (1999) Distribution and affecting factors of selenium in soil in the high-Se environment of Yutangba mini-landscape. Chin Sci Bull 44(Suppl):46–47

    CAS  Google Scholar 

Download references

Acknowledgements

The authors wish to thank the local government of Pingli County, Shaanxi Province, China, for its assistance in fieldwork. The State Key Project on Fundamental Research Planning of China (grant no. 2001CB409805), the China National Non-ferrous Metal Industry Corporation (grant nos. CNNC95-D-25 and 93E01), and Visiting Scholar Fund of LODG of the Institute of Geochemistry, Chinese Academy of Sciences, provided joint financial support for this project. Special thanks are due to CNNC for giving the authors the opportunity to complete this research.

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Correspondence to W. X. Fang.

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Fang, W.X., Huang, Z.Y. & Wu, P.W. Contamination of the environmental ecosystems by trace elements from mining activities of Badao bone coal mine in China. Env Geol 44, 373–378 (2003). https://doi.org/10.1007/s00254-003-0768-3

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  • DOI: https://doi.org/10.1007/s00254-003-0768-3

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