Abstract
Adsorption of disperse dyes from aqueous solutions onto calcined alunite has been investigated to assess the possibility of using alunite for removing disperse dyes from aqueous solutions. The effects of particle size, adsorbent mass, initial pH and temperature of the dye solution on the adsorption capacities have been evaluated. Acidic pH was favorable for the adsorption of all dyes: Disperse Blue 56 (DB56), Disperse Red 74 (DR74) and Disperse Yellow 119 (DY119). The experimental data were correlated reasonably well by the Langmuir isotherm and the isotherm parameters (KL and aL) have been calculated. The adsorption capacities were found to be 498, 525 and 500 mg of dye per g of calcined alunite for DB56, DR74 and DY119, respectively. The single-stage batch adsorber design of the adsorption of disperse dyes onto alunite has been studied based on the Langmuir isotherm equation.
Similar content being viewed by others
References
Al-Qodah Z (2000) Adsorption of dyes using shale oil ash. Water Res 34:4295–4303
Annadurai G, Juang R-S, Lee D-J (2002) Use of cellulose based wastes for adsorption of dyes from aqueous solutions. J Hazard Mater 92:263–274
Bajpai AK, Rajpoot M (2000) Static and kinetic studies on the adsorption behavior of sulfadiazene. Adsorption 6:349–357
Bouhamed H, Boufi S, Magnin A (2003) Alumina interaction AMPS-MPEG random copolymer I. Adsorption and electrokinetic behavior. J Col Interface Sci 261:264–272
Chiou M-S, Li H-Y (2002) Equilibrium and kinetic modelling of adsorption of reactive dyes on cross-linked chitosan beads. J Hazard Mater 93:233–248
Chu HC, Chen KM (2002a) Reuse of activated sludge biomass: II. The rate processes for the adsorption of basic dyes on biomass. Process Biochemistry 37:1129–1134
Chu HC, Chen KM (2002b) Reuse of activated sludge biomass: I. Removal of basic dyes from wastewater by biomass. Process Biochemistry 37:595–600
Demirbaş Ö, Alkan M, Doğan M (2002) The removal of victoria blue from aqueous solution by adsorption on a low-cost material. Adsorption 8:341–349
Doğan M, Alkan M, Onguner Y (2000) Adsorption of methylene blue on perlite from agueous solutions. Water, Air, And Soil Pollut 120:229–248
Golob V, Tušek L (1999) Vis absorption spectrophotometry of disperse dyes. Dyes and Pigments 40:211–217
Gupta GS, Prasad G, Singh VN (1990) Removal of chrome dye from aqueous solutions by mixed adsorbents: Fly ash and coal. Water Res 24:45–50
Gupta VK, Srivastava SK, Mohan D (1997) Equilibrium uptake, sorption dynamics, process optimization, and column operations for the removal and recovery of malachite green from wastewater using activated carbon and activated slag. Ind Eng Chem Res 36:2207–2218
Ho YS, McKay G (1998) A two-stage batch sorption optimized design for dye removal to minimize contact time. Trans IChemE 76B: 313–318
Ho YS, McKay G (2000) Batch sorber design using equilibrium and contact time data for the removal of lead. Water, Air, and Soil Pollut 124:141–153
Ho YS, Chiang CC (2001) Sorption studies of acid dye by mixed sorbents. Adsorption 37:139–147
Inouye K, Koyama T, Kaneko K, Ozeki S (1985) The high-order structure and dye adsorption of a porous alunite. Nippon Kagaku Kaishi 2:156–162
Lin SH (1993) Adsorption of disperse dye by powdered activated carbon. J Chem Tech Biotechnol 57:387–391
Lin S-H, Juang R-S (2002) Heavy metal removal from water by sorption using surfactant-modified montmorillonite. J Hazard Mater 92:315–326
McKay G, Otterburn MS, Aga JA (1985) Fuller’s earth and fired clay as adsorbents for dyestuffs equilibrium and rate studies. Water, Air, and Soil Pollut 24:307–322
McKay G, El-Geundi M, Nassar MM (1988) External mass transport process during the adsorption of dyes onto bagasse pith. Water Res 22:1527–1533
McKay G, El-Geundi, M, Nassar MM (1997) Equilibrium studies for the adsorption of dyes on bagasse pith. Adsorp Sci Technol 15:251–270
Nassar MM, Magdy YH (1997) Removal of different basic dyes from aqueous solutions by adsorption on palm-fruit bunch particles. Chem Eng J 66:223–226
Nigam P, Armour G, Banat IM, Singh B, Marchanat R (2000) Physical removal of textile dyes from effluents and solid-state fermentation of dye adsorbed agricultural residues. Bioresource Technol 72:219–226
Özacar M (1995) Calcination and leaching kinetics of alunite ore in alkaline media. M.Sc. Thesis, Sakarya University, Sakarya, Turkey, 63 pp
Özacar M (2003a) Adsorption of phosphate from aqueous solution onto alunite. Chemosphere 51:321–327
Özacar M (2003b) Equilibrium and kinetic modelling of adsorption of phosphorus on calcined alunite. Adsorption 9:125–132
Özacar M (2003c) Phosphate adsorption characteristics of alunite to be used as a cement additive. Cem Concr Res 33:1583–1587
Özacar M, Şengil İA (1999) Optimum conditions for leaching calcined alunite ore in strong NaOH. Can Metal Quarterly 38: 249–255
Özacar M, Şengil İA (2002) Adsorption of acid dyes from aqueous solutions by calcined alunite and granular activated carbon. Adsorption 8:301–308
Özacar M, Şengil İA (2003) Adsorption of reactive dyes on calcined alunite from aqueous solutions. J Hazard Mater B98:211–224
Özacar M, Şengil İA, Teker M (2000) The use of alunite-ZnO mixtures as adsorbent for sulfur dioxide gas. In: Doruk M (Ed) 10th Proc. of the International Metallurgy and Materials Congress, İstanbul, Turkey, Chamber of Metallurgical Engineers, Ankara, Vol. 1, pp 439–446
Ramakrishna KR, Viraraghavan T (1997a) Use of slag for dye removal. Waste Manag 17:483–488
Ramakrishna KR, Viraraghavan T (1997b) Dye removal using low cost adsorbents. Water Sci Tech 36:189–196
Şengil İA (1995) The utilization of alunite ore as a coagulant aid. Water Res 29:1988–1992
Şengil İA, Teker M, Özacar M (1995) The investigation of adsorbent specifications of alunite-ZnO mixtures, In: Berkem AR, Baysal BM, Berkem ML (Eds) 35th Iupac Congress, İstanbul, Turkey, Chemical Society of Turkey, İstanbul, p 1387
Szpyrkowicz L, Juzzolino C, Kaul SN (2001) A comparative study on oxidation of disperse dyes by electrochemical process, ozone, hypochlorite and Fenton regent. Water Res 35:2129–2136
Thomass WJ, Crittenden B (1998) Adsorption technology and design. Butterwort-Heinemann, Woburn
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Özacar, M., Şengil, İ.A. Equilibrium data and process design for adsorption of disperse dyes onto Alunite. Env Geol 45, 762–768 (2004). https://doi.org/10.1007/s00254-003-0936-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00254-003-0936-5