Skip to main content
Log in

Nutrient chemistry of groundwater in an intensively irrigated region of southern India

  • Original Article
  • Published:
Environmental Geology

Abstract

The concentration of nutrients in groundwater acts as an indicator to identify the influence of agricultural activities on the shallow subsurface environment. Hence, the present study was carried out to assess nutrient concentration (nitrate, phosphate and potassium) and understand its spatial and seasonal variations in the groundwater of Palar and Cheyyar River basin, Tamil Nadu, India. The groundwater samples collected from 43 wells were analyzed for nutrients once a month from January 1998 to June 1999. Results of the study suggested that agricultural activities, including application of fertilizers, soil mineralization processes and irrigation return flow, are major processes regulating the nutrients chemistry in the groundwater of this region. Groundwater in the sedimentary formation has comparatively higher concentration of nutrients than the groundwater in hard rock formations, which seems to be due to the adsorption of nutrients by the weathered rock materials. The seasonal water level fluctuation shows that rising water level increases nutrients concentration in groundwater due to the agriculture related activities. The results also indicate that nitrate and potassium concentrations are within the recommended drinking water limits, whereas phosphate concentration exceeds its drinking water limit and 35% of the samples are unsuitable for drinking purposes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  • APHA (American Public Health Association, American Water Works Association, and Water Pollution Control Federation) (1989) Standard methods for the examination of water and wastewater, 17th edn. APHA, Washington

  • Boyer DG, Pasquarell GC (1995) Nitrate concentrations in karst springs in an extensively grazes area. Water Resour Bull 31:729–736

    Google Scholar 

  • Bureau of Indian Standards (BIS) (1991) Drinking water specification. IS:10500:1991. New Delhi, India

  • Canadian Department of National Health and Welfare (1969) Canadian drinking water standards and objectives, 1968. Canada

  • Chandu SN, Subbarao NV, Raviprakash S (1995) Suitability of groundwater for domestic and irrigational purposes in some parts of Jhansi District, UP. Bhu-jal News 10:12–18

    Google Scholar 

  • Degens ET, Chillingar GV (1967) Diagenesis of subsurface waters. In: Larson G, Chillingar GV (eds) Diagenesis in sediments. Developments in sedimentalogy. Elsevier, Amsterdam

    Google Scholar 

  • Driescher E, Gelbrecht J (1993) Assessing the diffuse phosphorus input from subsurface to surface water in the catchment area of the lower river spree (Germany). Water Sci Technol 28:337–347

    Google Scholar 

  • Exner ME, Spalding RF (1979) Evolution of contaminated groundwater in Halt country, Nebraska. Water Resour Res 15:139–147

    Google Scholar 

  • Flipse WJ, Bonner FT (1985) Nitrogen-isotope ratios of nitrate in groundwater under fertilized fields, Long Island, New York. Groundwater 23:59–67

    Google Scholar 

  • Freeze RA, Cherry JA (1979) Groundwater. Prentice Hall, New Jersey

    Google Scholar 

  • Guimera J (1998) Anomalously high nitrate concentrations in groundwater. Groundwater 36:275–282

    Google Scholar 

  • Hamilton PA, Helsel DR (1995) Effects of agriculture on groundwater quality in five regions of the United States. Groundwater 33:217–226

    Google Scholar 

  • Hantzsche NN, Finnemore EJ (1992) Predicting groundwater nitrate-nitrogen impacts. Groundwater 30:490–499

    Google Scholar 

  • Hem JD (1985) Study and interpretation of the chemical characteristics of natural waters, US Geological Survey Water-Supply paper 2254:263

  • Hudak PF (2000) Regional trends in nitrate content of Texas groundwater. J Hydrol 228:37–47

    Google Scholar 

  • Jacks G, Sharma VP (1983) Nitrogen circulation and nitrate in groundwater in an agricultural catchment in southern India. Environ Geol 5: 61–64

    Google Scholar 

  • Kacaroglu F, Gunay G (1997) Impacts of human activities on groundwater quality of an alluvial aquifer: a case study of the Eskesehir plain, Turkey. Hydrogeol J 5:60–69

    Google Scholar 

  • Klimas A, Paukstys B (1993) Nitrate contamination of groundwater in the Republic of Lithuania. NGU Bull 424:75–85

    Google Scholar 

  • Kraft GS, Stites W, Mechenich DJ (1999) Impacts of irrigated vegetable agriculture on a Humid north–Central US Sand plain aquifer. Groundwater 37:572–580

    Google Scholar 

  • Matthess G (1982) The properties of groundwater. Wiley, New York

    Google Scholar 

  • Mohan R, Singh AK, Tripathi JK, Chowdhary GC (2000) Hydrochemistry and quality assessment of groundwater in Naini industrial area, Allahabad district, Uttar Pradesh. J Geol Soc India 55:77–89

    Google Scholar 

  • Mukherjee S, Pandey DS (1994) Nitrate pollution in groundwater at Jaunpur and its environs, Uttar Pradesh. Bhu-jal News 9:22–25

    Google Scholar 

  • Nolan BT (2001) Relating nitrogen sources and aquifer susceptibility to nitrate in shallow groundwaters of the United States. Groundwater 39:290–299

    Google Scholar 

  • Oren O, Yechieli Y, Böhlke JK, Dody A (2004) Contamination of groundwater under cultivated fields in an arid environment, central Arava Valley, Israel. J Hydol 290:312–328

    Google Scholar 

  • Pacheco J, Marìn L, Cabrera A, Steinich B, Escolero O (2001) Nitrate temporal and spatial patterns in 12 water-supply wells, Yucatan, Mexico. Envion Geol 40:708–715

    Google Scholar 

  • Petrovic AM (1990) The fate of nitrogenous fertilizers applied to turfgrass. J Environ Qual 19:1–14

    Google Scholar 

  • Piskin R (1973) Evaluation of nitrate content of groundwater in Hall Cpounty, Nebraska. Groundwater 11:4–13

    Google Scholar 

  • Prasad R (1998) Fertilizer urea, food security, health and the environments. Curr Sci 75:667–683

    Google Scholar 

  • Public Work Department (PWD) (2000) Groundwater perspectives: a profile of Kancheepuram district, TamilNadu. 220 pp

    Google Scholar 

  • Rajmohan N (2001) Hydrogeochemical studies in a part of Palar and Cheyyar river basin, Tamil Nadu, India. PhD Thesis, Anna University, Chennai

  • Rajmohan N, Elango L (2001) Modelling the movement of chloride and nitrogen in the unsaturated zone. In: Elango L, Jayakumar R (eds) Modelling in hydrogeology.UNESCO-IHP, Allied Publishers, New Dehli, pp 209–223

    Google Scholar 

  • Rajmohan N, Elango L (2004) Identification and evolution of hydrogeochemical processes in the groundwater environment in a part of Palar and Cheyyar River Basins, southern India. Environ Geol 46:47–61

    Google Scholar 

  • Rajmohan N, Elango L, Elampooranam T (1997) Seasonal and spatial variation in magnesium and chloride concentration in groundwater of Nagai Quaid E Milleth District in Tamil Nadu. Indian J Environ Prot 17(6):448–453

    Google Scholar 

  • Rajmohan N, Elango L, Ramachandran S, Natarajan M (2000) Major ion correlation in groundwater of Kancheepuram region, South India. Indian J Environ Prot 20(3):188–193

    Google Scholar 

  • Rao NS (1998) Impact of clayey soils on nitrate pollution in the groundwater of the lower Vamsadhara river basin, India. Hydrol Sci J 43:701–714

    Google Scholar 

  • Rao NS, Prasad PR (1997) Phosphate pollution in the groundwater of lower Vamsadhara river basin, India. Envion Geol 31:117–122

    Google Scholar 

  • Ritter WF (1988) Reducing impacts of non point source pollution from agriculture: a review. J Environ Sci Health 7:645–667

    Google Scholar 

  • Ritter WF, Chirnside AEM (1984) Impact of land use on groundwater quality in southern Delaware. Groundwater 22:38–47

    Google Scholar 

  • Scheytt T (1997) Seasonal variations in groundwater chemistry near Lake Belau, Schleswig-holstein, Northern Germany. Hydrogeol J 5:86–95

    Google Scholar 

  • Smeats J, Amavis P (1981) European Community directives relating to the quality of water intended for human consumption. Water Air Soil Pollut 15(4):483–502

    Google Scholar 

  • Stigter TY, Ooijen SPJV, Post VEA, Appello CAJ, Dill AMMC (1998) A hydrogeological and hydrochemical explanation of the groundwater composition under irrigated land in a mediterranean environment, Algarve, Portugal. J Hydrol 208:262–279

    Article  CAS  Google Scholar 

  • Stuart MA, Rich FJ, Bishop GA (1995) Survey of nitrate contamination in shallow domestic drinking water wells of the inner coastal plain of Georgia. Groundwater 33:284–290

    Google Scholar 

  • Stumm W, Morgan JJ (1996) Aquatic Chemistry. Wiley-Interscience, New York

    Google Scholar 

  • Tamta SR, Kapoor SL, Goverdhanan T (1991) Manurial NO3 pollution of groundwater in the decan trap formation of godavari Basin–Karnataka: a preliminary case study. Bhu-jal News 6:29–33

    Google Scholar 

  • Walter MF, Bubenzer GD, Converse JC (1975) Predicting vertical movement of manurial nitrogen in soil. Trans Am Soc Agric Eng 18:100–105

    Google Scholar 

  • Williams AE, Johnson JA, Lund LJ, Kabala ZJ (1998) Spatial and temporal variations in nitrate contamination of a rural aquifer, California. J Environ Qual 27:1147–1157

    Google Scholar 

  • World Health Organization (WHO) (1993) Guidelines for drinking water quality, vol 1, 2nd ed. Recommendations, Geneva

Download references

Acknowledgements

The authors wish to acknowledge the research grant provided by the University Grants Commission, New Delhi to carry out this research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to L. Elango.

Electronic Supplementary Material

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rajmohan, N., Elango, L. Nutrient chemistry of groundwater in an intensively irrigated region of southern India. Environ Geol 47, 820–830 (2005). https://doi.org/10.1007/s00254-004-1212-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00254-004-1212-z

Keywords

Navigation