Skip to main content
Log in

Distribution of arsenic and other trace elements in the Holocene sediments of the Meghna River Delta, Bangladesh

  • Original Article
  • Published:
Environmental Geology

Abstract

Geochemical study of the Holocene sediments of the Meghna River Delta, Chandpur, Bangladesh was conducted to investigate the distribution of arsenic and related trace and major elements. The work carried out includes analyses of core sediments and provenance study by rare earth element (REE) analysis. Results showed that the cores pass downward from silty clays and clays into fine to medium sands. The uppermost 3 m of the core sediments are oxidized [average oxidation reduction potential (ORP) + 230 mV], and the ORP values gradually become negative with depths (−45 to −170 mV), indicating anoxic conditions prevail in the Meghna sediments. The REE patterns of all lithotypes in the study areas are similar and are comparable to the average upper continental crust. Arsenic and other trace elements (Pb, Zn, Cu, Ni, and Cr) have greater concentrations in the silts and clays compared to those in the sands. Positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed on Fe oxides in aquifer sediments.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Abraham J (1998) Spatial distribution of major and trace elements in shallow reservoir sediments: an example from Lake Waco, Texas. Environ Geol 36(3–4):349–363

    Article  Google Scholar 

  • Acharyya SK, Lahiri S, Raymahashay BC, Bhowmik A (2000) Arsenic toxicity of groundwater in parts of the Bengal basin in India and Bangladesh: the role of Quaternary stratigraphy and Holocene sea-level fluctuation. Environ Geol 39:1127–1137

    Article  Google Scholar 

  • Ahmed KM, Hoque M, Hasan MK, Ravenscroft P, Chowdhury LR (1998) Origin and occurrence of water well methane gas in Bangladesh aquifers. J Geol Soc India 51:697–708

    Google Scholar 

  • Ahmed KM, Bhattacharya P, Hasan MA, Akhter SH, Alam SMM, Bhuyian MAH, Imam MB, Khan AA, Sracek O (2004) Arsenic enrichment in groundwater of the alluvial aquifers in Bangladesh: an overview. Appl Geochem 19:181–200

    Article  Google Scholar 

  • Akai J, Izumi K, Fukuhara H, Masuda H, Nakano S, Yoshimura T, Ohfuji H, Anawar HM, Akai K (2004) Mineralogical and geomicrobiological investigations on groundwater arsenic enrichment in Bangladesh. Appl Geochem 19:215–230

    Article  Google Scholar 

  • Anawar HM, Komaki K, Akai J, Takada J, Ishizuka T, Takahashi T, Yoshioka T, Kato K (2002) Diagenetic control on arsenic partitioning in sediments of the Meghna River delta, Bangladesh. Environ Geol 41:816–825

    Article  Google Scholar 

  • Berg M, Tran HC, Nguyen TC, Pham HV, Schertenleib R, Giger W (2001) Arsenic contamination of groundwater and drinking water in Vietnam: a human health treat. Environ Sci Technol 35(13):2621–2626

    Article  Google Scholar 

  • BGS and DPHE (2001) Arsenic contamination of groundwater in Bangladesh, vol 2. Final report, BGS Technical report WC/00/19. 267 pp

  • Bibi MH, Ahmed F, Sattar MA, Ishiga H, Reza MM (2003) Heavy metals contamination at different soil depths at Chandpur, Bangladesh. Bangladesh J Environ Sci 9:169–175

    Google Scholar 

  • Brammer H (1996) The geography of the soils of Bangladesh. University Press Ltd, Dhaka, 287 pp

  • Condie KC (1993) Chemical composition and evolution of the upper continental crust: contrasting results from surface samples and shales. Chem Geol 104:1–37

    Article  Google Scholar 

  • Dhar RK, Biswas BK, Samanta G, Mandal BK, Chakraborty D, Roy S, Jafar A, Islam A, Ara G, Kabir S, Khan AW, Ahmed SA, Hadi SA (1997) Groundwater arsenic calamity in Bangladesh. Curr Sci 73(1):48–59

    Google Scholar 

  • Fabian D, Zhou Z, Wehrli B, Friedl G (2003) Diagenetic cycling of arsenic in the sediments of eutrophic Baldeggersee, Switzerland. Appl Geochem 18:1497–1506

    Article  Google Scholar 

  • Garcia-Sanchez A, Alvarez-Ayuso E (2003) Arsenic in soils and waters and its relation to geology and mining activities (Salamanca Province, Spain). J Geochem Explor 80:69–79

    Article  Google Scholar 

  • Guern CL, Baranger P, Crouzet C, Bodénan F, Conil P (2003) Arsenic trapping by iron oxyhydroxides and carbonates at hydrothermal spring outlets. Appl Geochem 18:1313–1323

    Article  Google Scholar 

  • Harvey CF, Swartz CH, Badruzzaman ABM, Keon-Blute N, Yu W, Ali MA, Jay J, Beckie R, Niedan V, Brabander D, Oates PM, Ashfaque KN, Islam S, Hemond HF, Ahmed MF (2002) Arsenic mobility and groundwater extraction in Bangladesh. Science 298:1602–1606

    Article  Google Scholar 

  • Ishiga H, Dozen K, Yamazaki C, Ahmed F, Islam MB, Rahman MH, Sattar MA, Yamamoto H, Itoh K (2000) Geological constraints on arsenic contamination of groundwater in Bangladesh. In: Proceedings of the 5th international forum on arsenic contamination of groundwater in Asia, Asia Arsenic Network, Yokohama, Japan, pp 53–62

  • Islam ABM (2003) Arsenic pollution and the probable bio-remediation. Ph.D. thesis, Kanazawa University, Japan, 130 pp

  • Markgraf V (1989) Palaeoclimates in central and South America since 18,000 BP based on pollen and lake level-records. Quatern Sci Rev 8(1):1–24

    Article  Google Scholar 

  • McArthur JM, Ravenscroft P, Safiullah S, Thirlwall MF (2001) Arsenic in groundwater: testing pollution mechanisms for sedimentary aquifers in Bangladesh. Water Resour Res 37:109–117

    Article  Google Scholar 

  • McArthur JM, Banerjee DM, Hudson-Edwards KA, Mishra R, Purohit R, Ravenscroft P, Cronin A, Howarth RJ, Chatterjee A, Talukder T, Lowry D, Houghton S, Chadha DK (2004) Natural organic matter in sedimentary basins and its relation to arsenic in anoxic groundwater: the example of West Bengal and its worldwide implications. Appl Geochem 19:1255–1293

    Article  Google Scholar 

  • McLennan SM, Hemming S, McDaniel DK, Hanson GN (1993) Geochemical approaches to sedimentation, provenance and tectonics. Geol Soc Am Spec Paper 284:21–40

    Google Scholar 

  • Mukherjee AB, Bhattacharya P (2001) Arsenic in groundwater in the Bengal Delta Plain: slow poisoning in Bangladesh. Environ Rev 9:189–220

    Article  Google Scholar 

  • Musashino M (1990) The Panthalassa- a cerium-rich Atlantic-type ocean: sedimentary environments of the Tamba Group, Southwest Japan. Tectonophysics 181:165–177

    Article  Google Scholar 

  • Nickson RT, McArthur JM, Ravenscroft P, Burgess WG, Ahmed KM (2000) Mechanism of arsenic release to groundwater, Bangladesh and West Bengal. Appl Geochem 15:403–413

    Article  Google Scholar 

  • Norman MD, De Deckker P (1990) Trace metals in lacustrine and marine sediments: a case study from the Gulf of Carpentaria, northern Australia. Chem Geol 82:299–318

    Article  Google Scholar 

  • Ogasawara M (1987) Trace element analysis of rock samples by X-ray fluorescence spectrometry, using Rh anode tube. Bull Geol Surv Jpn 38(2):57–68

    Google Scholar 

  • Padmalal D, Maya K, Seralathan P (1997) Geochemistry of Cu, Co, Ni, Zn, Cd and Cr in the surficial sediments of a tropical estuary, southwest coast of India: a granulometric approach. Environ Geol 31(1/2):85–93

    Article  Google Scholar 

  • Peltier EF, Webb SM, Gaillard JF (2003) Zinc and lead sequestration in an impacted wetland system. Adv Environ Res 8:103–112

    Article  Google Scholar 

  • Pierce ML, Moore CB (1982) Adsorption of arsenite and arsenate on amorphous iron hydroxides. Water Res 16:1247–1253

    Article  Google Scholar 

  • Preda M, Cox ME (2002) Trace metal occurrence and distribution in sediments and mangroves, Pumicestone region, southeast Queensland, Australia. Environ Int 28:433–449

    Article  Google Scholar 

  • Potts PJ, Tindle AG, Webb PC (1992) Geochemical reference material compositions. Whittles Publishing, Caithness, 313 pp

  • Rahman MH, Ishiga H (1999) Geochemical composition of sediments of boring core samples. Arsenic contamination of groundwater in Bangladesh. Asia Arsenic Network (AAN): interim report of the research at Samta Village, pp 49–56

  • Ravenscroft P, McArthur JM, Hoque BA (2001) Geochemical and palaeohydrological controls on pollution of groundwater by arsenic. In: Chappell WR, Abernathy CO, Calderon R (eds) Arsenic exposure and health effects IV. Elsevier, Oxford, pp 53–77

    Google Scholar 

  • Roser BP (2000) Whole-rock geochemical studies of clustic sedimentary suites. Mem Geol Soc Jpn 57:73–89

    Google Scholar 

  • Singh M, Sharma M, Tobschall HJ (2005) Weathering of the Ganga alluvial plain, northern India: implications from fluvial geochemistry of the Gomati River. Appl Geochem 20:1–21

    Article  Google Scholar 

  • Smedley PL, Kinniburgh DG (2002) A review of the source, behavior and distribution of arsenic in natural waters. Appl Geochem 17:517–568

    Article  Google Scholar 

  • Sullivan KA, Aller RC (1996) Diagenetic cycling of arsenic in Amazon shelf sediments. Geochim Cosmochim Acta 60(9):1465–1477

    Article  Google Scholar 

  • Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell, Oxford, 312 pp

  • Tessier A, Carignan R, Belzile N (1994) Processes occurring at the sediment-water interface: emphasis on trace elements. In: Buffle J, DeVitre RR (eds) Chemical and biological regulation of aquatic system. Lewis Publishers, Boca Raton, pp 137–173

    Google Scholar 

  • Tribovillard NP, Desprairies A, Verges EL, Bertrand P, Moureau N, Ramdani A, Ramanampisoa L (1994) Geochemical study of organic-matter rich cycles from the Kimmeridge Clay Formation of Yorkshire (UK): productivity versus anoxia. Palaeogeogr Palaeoclimatol Palaeoecol 108:165–181

    Article  Google Scholar 

  • Umitsu M (1993) Late Quaternary sedimentary environments and landforms in the Ganges delta. Sed Geol 83:177–186

    Article  Google Scholar 

  • Yamazaki C, Ishiga H, Dozen K, Higashi N, Ahmed F, Sampei Y, Rahman MH, Islam MB (2000) Geochemical composition of sediments of the Ganges delta of Bangladesh-arsenic release from the peat?. Earth Sci (Chikyu Kagaku) 54:81–93

    Google Scholar 

  • Yamazaki C, Ishiga H, Ahmed F, Itoh K, Suyama K, Yamamoto H (2003) Vertical distribution of arsenic in Ganges delta sediments in Deuli village, Bangladesh. Soil Sci Plant Nutr 49(4):567–574

    Google Scholar 

  • Yan X-P, Kerrich R, Hendry MJ (2000) Distribution of arsenic (III), arsenic (V) and total inorganic arsenic in porewaters from a thick till and clay-rich aquitard sequence, Saskatchewan, Canada. Geochim Cosmochim Acta 62(15):2637–2648

    Article  Google Scholar 

Download references

Acknowledgements

The authors thank Prof. Y. Sampei and Prof. Y. Sawada of Shimane University for access to the AAS and XRF facilities, respectively. Dr. Barry Roser of Shimane University is acknowledged for his constructive review and helpful comments on the manuscript. This study formed part of an M.S. program in Shimane University, and was financially supported by Monbukagakusho (The Japanese Ministry of Education, Culture, Sports, Science and Technology). The INAA was carried out under the Visiting Researchers Program of the Research Reactor Institute, Kyoto University, Japan.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Hawa Bibi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bibi, M.H., Ahmed, F. & Ishiga, H. Distribution of arsenic and other trace elements in the Holocene sediments of the Meghna River Delta, Bangladesh. Environ Geol 50, 1243–1253 (2006). https://doi.org/10.1007/s00254-006-0298-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00254-006-0298-x

Keywords

Navigation