Abstract
One of the most crucial issues of recent environmental sciences is the topic of background concentrations of elements and organic compounds in various abiotic and biotic systems. The relationship between natural and anthropogenically altered concentrations of chemical species is a question that involves many implications in the geosciences, environmental and biological sciences, toxicology, and other related disciplines. This is especially important when interpreting geochemical and biogeochemical anomalies of toxic elements and/or organic compounds in various media. To better understand the potential impact of hazardous substances in the environment, we must become more familiar with their spatial and temporal distribution and with their behavior under different physico-chemical and biotic conditions. This review presents an assessment of the geochemical background concept as used by various authors. Different assumptions and approaches to this topic are presented, including direct, statistical, and integrated methods. Based on the results derived from geochemical and biogeochemical studies performed in selected forest ecosystems of Poland, an integrated method is presented. As a consequence of data processing, a normal distribution of data points was obtained using an iterative 2σ-technique. This method of estimating geochemical background is feasible and can be used for setting environmental quality standards or for studying the impact of anthropogenic pollution sources on the environment.
Similar content being viewed by others
References
Agarwal AK (1975) Crippling cost of India’s big dam. New Sci 65:260–261
Anderson CWN, Brooks RR, Chiarucci A, Lacoste CJ, Leblanc M, Robinson BH, Simcock R, Steward RB (1999) Phytomining for thallium, nickel and gold. J Geochem Explor 67:407–415
Aston SR, Bruty D, Chester R, Padgham RC (1973) Mercury in lake sediments: a possible indicator of technological growth. Nature 246:450–451
Baize D, Sterckeman T (2001) Of the necessity of knowledge of the natural pedo-geochemical background content in the evaluation of the contamination of soils by trace elements. Sci Total Environ 264:127–139
Bates RL, Jackson JA (eds) (1984) Dictionary of geological terms. Anchor books. A Division of Random House Inc., New York
Baudo R, Giesy JP, Muntau H (eds) (1990) Sediments: chemistry and toxicity of in-place pollutants. Lewis Publishers Inc., Boston, MA
Boutron CF, Candelone JP, Hong S (1995) Greenland snow and ice cores; unique archives of large-scale pollution of the troposphere of the Northern Hemisphere by lead and other heavy metals. Sci Total Environ 160/161:233–241
Bowen HJM (1979) Environmental chemistry of elements. Academic Presss. London
Crock JG, Severson RC, Gough LP (1992) Determining baselines and variability of elements in plants and soils near the Kenai National Wildlife Refuge, Alaska. Water, Air, Soil Pollut 63:253–271
Crommentuijn T, Sijm D, de Bruijn J, van den Hoop M, van Leeuwen K, van de Plassche E (2000) Maximum permissible and negligible concentrations for metals and metalloids in the Netherlands, taking into account background concentrations. J Environ Manage 60:121–143
Darnley AG (1995) A global geochemical reference network: the foundation for geochemical baselines. J Geochem Explor 60:1–5
D’Itri FM (1990) The biomethylation and cycling of selected metals and metalloids in Aquatic sediments. In: Baudo R, Giesy JP, Muntau H (eds) Sediments: chemistry and toxicity of in-place pollutants. Lewis Publishers Inc., Boston, MA, pp 163–214
Dunn CE, Erdman JA, Hall G, Smith SC (1992) Biogeochemical exploration simplified. notes for a short course on methods of biogeochemical and geobotanical prospecting—with emphasis on arid terrains, Phoenix, AZ, February 22–23, 1992 (unpublished)
Fortescue JAC (1992) Landscape geochemistry—retrospect and prospect—1990. Appl Geochem 7:1–53
Gałuszka A (2005) The chemistry of soils, rocks and plant bioindicators in three ecosystems of the Holy Cross Mountains, Poland. Environ Monit Assess 110:55–70
Gałuszka A (2006) Methods of determining geochemical background in environmental studies. Problems of landscape ecology. Polish association of landscape ecology. Warsaw (in Polish with English summary) XVI/1:507–519
Gałuszka A, Migaszewski ZM (2004) Concentrations of polynuclear aromatic hydrocarbons in sediments of Lake Wigry and selected rivers near Suwałki, northeastern Poland. Prace Komisji Paleogeografii Czwartorzędu Polska Akademia Umiejętności 2:49–54 (in Polish with English summary)
Gough LP (1993) Understanding our fragile environment. Lessons from geochemical studies. US Geol Surv Circ 1105:1–34
Gough LP, Crock JG (1997) Distinguishing between natural geologic and anthropogenic trace element sources, Denali National Park and Preserve. US Geol Surv Prof Pap 1574:57–71
Gough LP, Jackson LL, Sacklin JA (1988a) Determining baseline element composition of lichens. II. Hypogymnia enteromorpha and Usnea spp. at Redwood National Park, CA. Water, Air, Soil Pollut 38:169–180
Gough LP, Severson RC, Jackson LL (1988b) Determining baseline element composition of lichens. I. Parmelia sulcata at Theodore Roosevelt National Park, ND. Water, Air, Soil Pollut 38:157–167
Gschwend PM, Hites RA (1981) Fluxes of polycyclic aromatic hydrocarbons to marine and lacustrine sediments in the northeastern US. Geochimica Cosmochimica Acta 45:2359–2367
Herring JR (1991) Selenium geochemistry—a conspectus. US Geol Surv Circ 1064:5–24
Hong S, Candelone JP, Patterson CC, Boutron CF (1994) Greenland ice evidence of hemispheric lead pollution 2–3 millennia ago by Greek and Roman civilizations. Science 265:1841–1843
Hong S, Candelone JP, Patterson CC, Boutron CF (1996) History of ancient copper smelting pollution during Roman and Medieval times recorded in Greenland ice. Science 272:246–249
Horckmans L, Swennen R, Deckers J, Maquil R (2005) Local background concentrations of trace elements in soils: a case study in the Grand Duchy of Luxemburg. Catena 59:279–304
Kabata-Pendias A, Pendias H (2001) Trace elements in soils and plants. CRC Press Inc., Roca Baton, Fl
Kelley KD, Taylor CD (1997) Environmental geochemistry of shale-hosted Ag-Pb-Zn massive sulfide deposits in northwest Alaska: natural background concentrations of metals in water from mineralized areas. Appl Geochem 12:397–409
Kentucky Guidance for Ambient Background Assessment (2004) Natural resources and environmental protection cabinet. http://rais.ornl.gov/homepage/AmbientBackgroundAssessment.pdf
Lee L, Helsel D (2005) Baseline models of trace elements in major aquifers of the US. Appl Geochem 20:1560–1570
Levinson AA (1980) Introduction to exploration geochemistry. Appled Publishing Ltd., Wilmette
Li Ch, Ma T, Junfa S (2003) Application of a fractal method relating concentrations and distances for separation of geochemical anomalies from background. J Geochem Explor 77:167–175
Mannion AM (2002) Natural environmental change. Routledge. London
Matschullat J, Ottenstein R, Reimann C (2000) Geochemical background—can we calculate it? Environ Geol 39:990–1000
Migaszewski ZM, Gałuszka A, Pasławski P (2002) Polynuclear aromatic hydrocarbons, phenols and trace metals in selected soil profiles and plant bioindicators in the Holy Cross Mountains, south-central Poland. Environ Int 28/4:303–313
Migaszewski ZM, Gałuszka A, Pasławski P (2004) Baseline element concentrations in soils and plant bioindicators of selected national parks of Poland. Geol Q 48(4):383–394
Migaszewski ZM, Gałuszka A, Pasławski P (2005) The use of barbell cluster ANOVA design for the assessment of environmental pollution: a case study, Wigierski National Park, NE Poland. Environ Pollut 133:213–223
Migaszewski ZM, Gough LP, Gałuszka A (2001) The role of biogeochemistry in environmental studies. Przegląd Geologiczny (Polish Geol Review) 49(10/2):960–965
Model Toxics Control Act—Cleanup (2001) Department of ecology. Washington Administrative Code. 173–340–200. http://www.apps.leg.wa.gov. Cited 22 Aug 2006
Nieto P, Custodio E, Manzano M (2005) Baseline groundwater quality: a European approach. Environ Sci Policy 8:399–409
Nordstrom DK, Alpers CN, Ptacek CJ, Blowes DW (2000) Negative pH and extremely acid mine waters from iron mountain superfund site, CA. Environ Sci Technol 34(2):254–258
Nriagu JO (1979) Global inventory of natural and anthropogenic emissions of trace metals to the atmosphere. Nature 279:409–411
Nriagu JO (1989) A global assessment of natural sources of atmospheric trace metals. Nature 338:47–49
Plumlee GS (1999) The environmental geology of mineral deposits. In: Plumlee GS, Logsdon JJ (eds) The environmental geochemistry of mineral deposits. Part A, Processes, Techniques, and Health Issues. Soc Econ Geol Rev Econ Geol 6A:71–116
Portier KM (2001) Statistical issues in assessing anthropogenic background for arsenic. Environ Forensics 2:155–160
Ramsey MH, Thompson M, Halle M (1992) Objective evaluation of precision requirements for geochemical analysis using robust analysis of variance. J Geochem Explorat 44:23–36
Reichenbach I (1994) Black shale as an environmental hazard; a review of black shales in Canada. Geol Surv Can Open-File 2697
Reimann C, Garret RG (2005) Geochemical background—concept and reality. Sci Total Environ 350:12–27
Richardson DHS (1992) Pollution monitoring with lichens. Richmond Publishing Co. Ltd. Slough, England
Rickwood PC (1983) Crustal abundance, distribution, and crystal chemistry of the elements. In: Govett GJS (ed) Handbook of exploration geochemistry, vol 3. Rock geochemistry in mineral exploration. Elsevier Scientific Publishing Co., Amsterdam, pp 347–387
Salminen R, Gregorauskiene V (2000) Considerations regarding the definition of a geochemical baseline of elements in the surficial materials in areas differing in basic geology. Appl Geochem 15:647–653
Salminen R, Tarvainen T (1997) The problem of defining geochemical baselines. A case study of selected elements and geological materials in Finland. J Geochem Explorat 60:91–98
Selinus OS, Esbensen K (1995) Separating anthropogenic from natural anomalies in environmental geochemistry. J Geochem Explorat 55:55–66
Smith KS, Huyck HOL (1999) An overview of the abundance, relative mobility, bioavailability, and human toxicity of metals. In: Plumlee GS, Logsdon JJ (eds) The Environmental geochemistry of mineral deposits, part A, processes, techniques, and health issues. Soc Econ Geol Rev Econ Geol 6A:29–69
Tidball RR, Erdman JA, Ebens RJ (1974) Geochemical baselines for sagebrush and soil. Powder River Basin. Montana-Wyoming. US Geol Surv Open-file Report 74–250, 6–13
Tobías FJ, Bech J, Algarra PS (1997) Establishment of the background levels of some trace elements in soils of NE Spain with probability plots. Sci Total Environ 206:255–265
Turekian KK, Wedepohl KH (1961) Distribution of the elements in some major units of the earth’s crust. Bull Geol Soc Am 72:175–192
Villeneuve JP, Holm E (1984) Atmospheric background of chlorinated hydrocarbons studied in Swedish lichens. Chemosphere 13:1133–1138
Acknowledgments
The author thanks Dr. Zdzislaw M. Migaszewski of the Pedagogical University in Kielce for encouraging me to write this paper, allowing me to use the archival data, and making comments on the subject discussed that certainly influenced the quality of my paper. I would also like to express my gratitude to Dr. Larry P. Gough of the US Geological Survey in Reston, Virginia for reading the final version of my paper and for the valuable remarks.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gałuszka, A. A review of geochemical background concepts and an example using data from Poland. Environ Geol 52, 861–870 (2007). https://doi.org/10.1007/s00254-006-0528-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00254-006-0528-2