Abstract
The geochemical investigation of sediments deposited in the Renuka Lake basin and its adjoining wetland has shown variation in the distribution and concentration of major, trace and REEs. The major elements are depleted in the lake in relation to wetland and that of Post Archaean Australian, Shale (PAAS), except for CaO which is strikingly in excess and has a dilution effect on SiO2 and other oxides and trace elements. The Wetland sediments, on the other hand, are enriched in Al2O3, Fe2O3, K2O and TiO2 and the latter three show a positive correlation with Al2O3 in both wetland and lake sediments suggesting their association with phyllosilicates and similar source rocks. The enrichment of Y, Zr, Ni, Th, U and Nb in wetland compared to lake and their similarity with PAAS in the former, suggests more clay fractions in the wetland. A high Zr/Hf ratio in wetland and lake sediments and a positive correlation of Zr with Y and HREE indicate Zr control on HREEs. However, higher Zr/Yb and Zr/Th ratios in wetland compared to lake indicate mineral sorting during the process of lighter particles (clays) being trapped in wetland soil. This is also reflected from negative correlation of GdN/YbN with Al2O3 and a strong positive correlation with SiO2 in wetland sediments. The wetland in this context has a control on lake sediment chemistry. The chondrite normalized REE patterns are essentially the same for lake as well as wetland sediments but abundance decreases in the former. The similarity of pattern with that of PAAS and negative Eu anomaly indicates a cratonic source of sediments. In a plot of the individual samples, wetland samples cluster while lake samples are separated indicating fractionation of lake sediments. A strong positive correlation of LaN/YbN with Al2O3 and a positive correlation of Zr-∑LREE and Zr-LaN/YbN suggest that LREEs are controlled by both phyllosilicates and zircon. The chemical index of alteration (CIA) indices in lake sediments and in wetland are higher than PAAS indicating moderate chemical weathering in the source area. The petrography, lack of felsic magmatic rock fragments, and negative correlation between Zr-(Gd/Yb)C indicate sedimentary source rocks for the detritus. This is in conformity with the Lesser Himalayan sedimentary sequence belonging to neo-Proterozoic–Proterozoic age and constituting lake catchment of Renuka. The tectonic delineation and discriminant function plots of lake and wetland sediments indicate their cratonic and/or quartzose sedimentary orogenic terrain source that has been deposited in a passive margin setting.
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References
Auden JB (1934) The geology of the Krol Belt. Rec Geol Surv India 67(4):357–454
Balasov YA, Ronov AV, Migdisov AA, Turanskaya NV (1964) The effect of climate and Facies environment in the fractionation of the rare earths during sedimentation. Geochem Int 10:951–969
Bauluz B, Mayayo MJ, Fernandez-Nieto C, Lopez JMG (2000) Geochemistry, of Precambrian and Paleozoic siliciclastic rocks from the Iberian Range (NE Spain): implications for source-area weathering, sorting, provenance, and tectonic setting. Chem Geol 168:135–150
Berggren B, Oden S (1972) Analyseresultat rorande Fungmettaller och Klorerade Kolvaten i Rotslam fra Svenska Renningsverk 1968–1971. Inst.f. Markventeskap Lantbrukshogskolan, Uppsala
Berrow ML, Webber J (1972) Trace elements in sewage sludges. J Sci Food Agric 23:93–100
Bhatia MR (1983) Plate tectonics and geochemical composition of sandstones. J Geol 91:611–627
Bhatia MR (1985a) Rare-Earth Elements geochemistry of Australian Paleozoic Graywackes and Mud Rocks: provenance and tectonic control. Sediment Geol 45:97–113
Bhatia MR (1985b) Composition and classification of Paleozoic flysch mudrocks of Eastern Australia: Implications in provenance and tectonic setting interpretation. Sediment Geol 41:249–268
Bhatia MR, Crook KAW (1986) Trace -element characteristics of graywacks and tectonic setting discrimination of sedimentary basins. Contrib Miner Petrol 92:181–193
Bhatia MR, Taylor SR (1981) Trace-element geochemistry and sedimentary provinces: a study from the Tasman Geosyncline, Australia. Chem Geol 33:115–125
Burrard SG, Hayden HH (1908) A sketch of the geography and geology of the Himalayan mountains and Tibet part IV-the geology of the Himalaya
Cantrell KJ, Byrne RH (1987) Rare-earth element complexation by carbonate and oxalate ions. Geochim Cosmochim Acta 51:597–605
Condie KC (1991) Another look at rare-earth elements in shales. Geochim Cosmochim Acta 55:2527–2531
Crook KAW (1974) Lithogenesis and geotectonics, the significance of compositional variation in flysch arenites (graywackes). In: Dott RH, Shaver RH (eds) Modern and ancient geosynclinal sedimentation. Soc Econ Pa1eont Miner Sp1 Pub, vol 19, pp 304–310
Cullers RL, Stone J (1991) Chemical and mineralogical composition of the Pennsylvanian mountain, Colorado, USA (an uplifted continental blocks) to sedimentary rocks from other tectonics environments. Lithos 27:115–131
Cullers RL, Chaudhuri C, Kilbane N, Koch R (1979) REE in size fractions and sedimentary rocks of Pennsylvanian–Permian age from the mid-continent of the USA Geochim. Cosmochim Acta 43:1285–1301
Cullers RL, Barrett T, Carlson R, Robinson B (1987) REE and mineralogic changes in Holocene soil and stream sediments. Chem Geol 63:275–297
Cullers RL, Basu A, Suttner LJ (1988) Geochemical signature of provenance in sand size material in soils and stream sediment near the Tobacco Root Batholith Montana, USA. Chem Geol 70:335–348
Das BK, Haake BG (2003) Geochemistry of Rewalsar Lake sediment, Lesser Himalaya, India: implications for source-area weathering, provenance and tectonic setting. Geosciences J 7(4):299–312
Das BK, AI-Mikhlafi AS, Kaur P (2006) Geochemistry of Mansar Lake sediments, Jammu, India: implication for source-area weathering, provenance, and tectonic setting. J Asia Earth Sci 26(6):649–668
Dickinson WR, Suczek CA (1979) Plate tectonics and sandstone compositions. Am Assoc Petrol Geol Bull 63:2164–2182
Fedo CM, Eriksson KA, Krogstad EJ (1996) Geochemistry of shales from the Archean (∼3.0 Ga) Buhwa Greenstone Belt, Zimbanwe: implications for provenance and source-area weathering. Geochim Cosmochim Acta 60(10):1751–1763
Floyd PA, Leveridge BE (1987) Tectonic environment of the Devonian Gramscatho basin, Cornwall: frame work mode and geochemical evidence from turbiditic sandstones. J Geol Soc Lond 144:531–542
Forstner U, Wittmann GTW (1979) Metal pollution in the aquatic environment. Springer, Berlin, pp 1–486
Franzinelli E, Potter PE (1983) Petrology, chemistry, and texture of modern river sands, Amazon River System. J Geol 91:23–39
Graver JI, Scott TJ (1995) Trace elements in shale as indicators of crustal provenance and terrain accretion in south Canadian Cordillera. Geol Soc Am Bull 107:440–453
Griffin GM (1971) Interpretation of X-ray diffraction data. In: Carve RE (ed) Procedures in sedimentary petrology. Wiley, New York, pp 541–569
Gromet LP, Dymek RF, Haskin LA, Korotev RL (1984) The North American shale composite: its compilation and major and trace element characteristics. Geochim Cosmochim Acta 48:2469–2482
Herron MM (1988) Geochemical classification of terrigenous sands and shales from core or log data. J Sediment Petrol 58:820–829
Joshi KL (1984) Geography of Himachal Pradesh. National Book Trust, Delhi
Mclennan SM (1989) Rare-earth elements in sedimentary rocks: influence of provenance and sedimentary processes. Rev Miner 21:170–199
McLennan SM, Taylor JR (1991) Sedimentary rocks and crustal evolution: tectonic setting and secular trends. J Geol 99:1–21
McLennan SM, Nance WB, Taylor WB (1980) Rare-Earth-thorium correlations in sedimentary rocks, and the composition of the continental crust. Geochim Cosmochim Acta 44:1833–1839
McLennan SM, Hemming S., McDaniel DK, Hanson GN (1993) Geochemical approaches to sedimentation, provenance and tectonics. In: Johnsson MJ, Basu A (eds) Processes controlling the composition of clastic sediments. Geol Soc Am Spl Pap, vol 284, pp 21–40
Murali AV, Parthasarathy R, Mahadevan TM, Sankar Das M (1983) Trace element characteristics, REE patterns partition coefficients of zircons from different geological environments-A case study on Indian zircons. Geochim Cosmochim Acta 47:2047–2052
Nesbitt HW (1979) Mobility and fractionation of rare-earth elements during weathering of a granodiorite. Nature 279:206–210
Nesbitt HW, Young GM (1982) Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature 299:715–717
Pettijohn FJ, Potter PR, Siever R (1972) Sand and sandstones. Springer, New York
Piper DZ (1974) Rare-earth elements in the sedimentary cycle: a summary. Chem Geol 14:285–304
Potter PE (1978) Petrology and chemistry of big river sands. J Geol 86:423–449
Ronov AB, Balashov YA, Migdisov AA (1967) Geochemistry of the rare-earths in sedimentary cycle. Geochemistry Int 4(1):1–17
Roser BP (1983) Comparative studies of copper and manganese mineralization in the Torlesse, Waipapa, and Haast Schist terranes, New Zealand: Unpublished Ph.D thesis. Victoria University of Wellington, p 329
Roser BP, Korsch RJ (1986) Determination of tectonic setting of sandstone–mudstone suites using SiO2 content and K2O/Na2O ratio. J Geol 94:635–650
Roser BP, Korsch RJ (1988) Provenance signatures and sandstone-mudstone suites determined using discriminant function analysis of major-element data. Chem Geol 67:119–139
Rowe GH (1980) Applied geology of Wellington rocks for aggregate and concrete: Unpublished Ph.D thesis, Victoria University of Wellington, Wellington
Schwab FL (1975) Frame work mineralogy and chemical composition of continental margin-type sandstones. Geology 3:487–490
Siever R (1979) Plate-tectonic controls on diagenesis. J Geol 87:125–155
Srikantia SV, Bhargava ON (1998) Geology of Himacahal Pradesh. Geol Soc India Spl Publ 124–137
Takahashi Y, Simizu H, Kagi H, Yoshida H, Usui A, Nomura M (2000) A new method for the determination of CeIIl/CeIV ratios in geological materials; implication for weathering, sedimentary and diagenetic processes. Earth Planet Sci Lett 182(3–4):201–207
Taylor SR, McLennan SM (1985) The continental crust; its composition and evolution. Blackwell, Oxford
Vital H, Stattegger K (2000) Major and trace elements of stream sediments from the lower most Amazon River. Chem Geol 168:151–168
Acknowledgments
The financial support received from University grants commission, Government of India under the project [No. F5–2/98 (SR-I)] sanctioned to BKD and the German Research Council Grant GA 755/3 to GB are thankfully acknowledged. We thank Dieter Garbe-Schoenberg (Institute for Geosciences, Christian-Albrechts-University of Kiel, Germany) for carrying out rare earth elements analysis.
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Das, B.K., Birgit-Gaye & Kaur, P. Geochemistry of Renuka Lake and wetland sediments, Lesser Himalaya (India): implications for source-area weathering, provenance, and tectonic setting. Environ Geol 54, 147–163 (2008). https://doi.org/10.1007/s00254-007-0801-z
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DOI: https://doi.org/10.1007/s00254-007-0801-z