Abstract
Grain size parameters, trace metals (Co, Cu, Ni, Pb, Cr, Zn, Ba, Zr and Sr) and total organic matter (TOM) of 38 surficial sediments and a sediment core of west-four Pearl River Estuary region were analyzed. The spacial distribution and the transportation procession of the chemical element in surficial sediments were studied mainly. Multivariate statistics are used to analyses the interrelationship of metal elements, TOM and the grain size parameters. The results demonstrated that terrigenous sediment taken by the rivers are main sources of the trace metal elements and TOM, and the lithology of parent material is a dominating factor controlling the trace metal composition in the surficial sediment. In addition, the hydrodynamic condition and landform are the dominating factors controlling the large-scale distribution, while the anthropogenic input in the coastal area alters the regional distribution of heavy metal elements Co, Cu, Ni, Pb, Cr and Zn. The enrichment factor (EF) analysis was used for the differentiation of the metal source between anthropogenic and naturally occurring, and for the assessment of the anthropogenic influence, the deeper layer content of heavy metals were calculated as the background values and Zr was chosen as the reference element for Co, Cu, Ni, Pb, Cr and Zn. The result indicate prevalent enrichment of Co, Cu, Ni, Pb and Cr, and the contamination of Pb is most obvious, further more, the peculiar high EF value sites of Zn and Pb probably suggest point source input.
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Adamo P, Arienzo M, Imperato M, Naimo D, Nardi G, Stanzione D (2005) Distribution and partition of heavy metals in surface and sub-surface sediments of Naples city port. Chemosphere 61(6):800–809
Barcellos C, de Lacerda LD, Ceradini S (1997) Sediment origin and budget in Sepetiba Bay (Brazil)—an approach based on multi-elemental analysis. Environ Geol 32(3):203–209
Blaser P, Zimmermann S, Luster J, Shotyk W (2000) Critical examination of trace element enrichments and depletions in soils: As, Cr, Cu, Ni, Pb and Zn in Swiss forest soils. Sci Total Environ 249:257–280
Chen YT (1995) Sedimentation divisions of Pearl River Mouth. Acta Scientiarum naturalium universitatis sunyatseni 34(3):109–114
Chen XH (2000) Allocation and variation of sediment for branching channels main river in the pearl delta—a case study of the west and north river delta. Tropic Geogr 20(1):22–26
Chen YT, Luo ZR (1991) Modern sedimentary velocity and their reflected sedimentary characteristics in the Pearl River Mouth. Tropic oceanol 10(2):57–64
Chen CW, Kao CM, Chen CF, Dong CD (2007) Distribution and accumulation of heavy metals in the sediments of Kaohsiung Harbor. Taiwan. Chemosphere 66:1431–1440
Cobelo-García A, Prego R (2003) Heavy metal sedimentary record in a Galician Ria (NW Spain): background values and recent contamination. Mar Pollut Bull 46:1253–1262
DeMora S, Sheikholeslami MR, Wyse E, Azemard S, Cassi R (2004) An assessment of metal contamination in coastal sediments of the Caspian Sea. Mar Pollut Bull 48:61–77
Einax JW, Soldt U (1999) Geostatistical and multivariate statistical methods for the assessment of polluted soils—merits and limitations. Chemomet Intell Lab Syst 46:79–91
Grabemann I, Uncles RJ, Krause G, Stephens JA (1997) Behaviour of turbidity maxima in the tamar (U.K.) and Weser (F.R.G) estuaries. Estuar Coast Shelf Sci 45:235–246
Graham E, Richard J Howarth, Nombela MA (2003) Metals in the sediments of Ensenada de San Simón (inner Ría de Vigo), Galicia, NW Spain. Appl Geochem 18:973–996
Guerra-García José M, García-Gomez JC (2005). Assessing pollution levels in sediments of a harbour with two opposing entrances. Environmental implications. J Environ Manage 77(1):1–11
Hills P, Zhang L, Liu JH (1998) Transboundary pollution between Guangdong Province and Hong Kong: threats to water quality in the Pearl River Estuary and their implications for environmental policy planning. J Environ Plann Manage 41:375–396
Howarth RJ, Nombela MA (2003) Metals in the sediments of Ensenada de San Simon (inner Ria de Vigo), Galicia, NW Spain. Appl Geochem 18:973–996
Lau MM, Rootham RC, Bradley GC (1993) A strategy for the management of contaminated dredged sediment in Hong Kong. J Environ Manage 38:99–114
Lee CSL, Li XD, Zhang G, Li J, Ding AJ, Wang T (2007) Heavy metals and Pb isotopic composition of aerosols in urban and suburban areas of Hong Kong and Guangzhou, South China-Evidence of the long-range transport of air contaminants. Atmos Environ 41(2):432–447
Li XD, Wai OWH, Li YS, Coles B, Eamsy MH, Thornton I (2000) Heavy metal contaminants in sediment profiles of the Pearl River Estuary. Appl Geochem 15:567–581
Liang J (2005) Characteristics of the sediment and sedimentary environment in the Modaomen estuary. Trop Geogr 25(2):117–122
Lin ZH, Liang SH (1995) Modern sedimentary environment and heavy metal content distribution in bottom load in Pearl Estuary. Mar Sci Bull 14(4):43–49
Lin S, Hsieh IJ, Huang KM, Wang CH (2002) Influence of the Yangtze River and grain size on the spatial variations of heavy metals and organic carbon in the East China Sea continental shelf sediments. Chem Geol 182:377–394
Liu WX, Li XD, Shen ZG, Wang DC, Wai OWH, Li YS (2003) Multivariate statistical study of heavy metal enrichment in sediments of the Pearl River Estuary. Environ Pollut 121:377–388
McCready S, Gavin F. Birch, Edward R. Long (2006) Metallic and organic contaminants in sediments of Sydney Harbour, Australia and vicinity—a chemical dataset for evaluating sediment quality guidelines. Environ Int 32:455–465
Mitchell SB, West JR, Arundale AMW, Guymer I, Couperthwaite JS (1998). Dynamics of the turbidity maxima in the upper Humber estuary system, UK. Mar Pollut Bull 37:190–205
Morillo J, Usero J, Gracia I (2004) Heavy metal distribution in marine sediments from the southwestcoast of Spain. Chemosphere 55:432–442
Muniz P, Danulat E, Yannicelli B, Garcia-Alonso J, Medina G, Bicego MC (2004) Assessment of contamination by heavy metals and petroleum hydrocarbons in sediments of Montevideo Harbour (Uruguay). Environ Int 29:1019–1028
Ou XJ, Zhao HT, Song CJ (1983) Hydrological and sedimentary characteristics of the Modaomen distributary mouth, Xijiang (west river). Tropic oceanol 2(4):278–288
Peng XT, Zhou HY, Ye Y, Chen G Q (2004) Characteristics of sediment grain size and their implications for bottom hydrodynamic environment in the Pearl River estuary. Acta Sedimentologica Sinica 22(3):487–493
Roussiez V, Ludwig W, Monaco A, Probst JL, Bouloubassi I, Buscail R, Saragoni G (2006) Sources and sinks of sediment-bound contaminants in the Gulf of Lions (NW Mediterranean Sea): a multi-tracer approach. Continental Shelf Res 26:1843–1857
Ruiz F (2001) Trace metals in estuarine sediments from the southwestern Spanish coast. Mar Pollut Bull 42(6):482–489
Rubio B, Nombela MA, Vilas F (2000) Geochemistry of major and trace elements in sediments of the Ria de Vigo(NW Spain): an assessment of metal pollution. Mar Pollut Bull 40:968–980
Selvaraj K, Mohan VR, Szefer P (2004) Evaluation of metal contamination in coastal sediments of the Bay of Bengal, India: geochemical and statistical approaches. Mar Pollut Bull 49(33):174–185
Shotyk W (1996) Peat bog archives of atmospheric metals deposition: geochemical assessment of peat profiles, natural variations in metal concentrations, and metals enrichment factors. Environ Rev 4(2):149–183
Shine JP, Ika RV, Ford TE (1995) Multivariate statistical examination of spatial and temporal patterns of heavy metal contamination in New Bedford Harbour marine sediments. Environ Sci Technol 29:1781–1788
Simeonov V, Massart DL, Andreev G, Tsakovski S (2000) Assessment of metal pollution based on multivariate statistical modeling of ‘hot spot’ sediments from the Black Sea. Chemosphere 41:1411–1417
The Chinese national criteria GB/T17318.5–1998, specification for oceanographic survey-Marine geology and geophysics investigation
Turekian KK, Wedepohl KH (1961) Distribution of the elements in some major units of the earth’s crust. Geol Soc Am Bull 72:175–192
Vald’es J, Vargas G, Sifeddine A, Ortlieb L, Guinez M (2005) Distribution and enrichment evaluation of heavy metals in Mejillones Bay (23°S), Northern Chile: geochemical and statistical approach. Mar Pollut Bull 50:1558–1568
Wang S (2006) Project design research of East Dam in the west shore of Jiti Men. Guangdong Water resource and Hydropower (in chinese)
Wang SJ, Hu D, Li CC (2006) The recent evolution of Modaomen Estuary and its effect on flood drainage. Mar Sci Bull 25(2):21–26
Willams TP, Bubb JM, Lester JN (1994). Metal accumulation within saltmarsh environments: a review. Mar Pollut Bull 28:277–290
Yang XW (1993) Sediment load sources and transportation process in Huang mao Hai bay west of Pearl Estuary. Mar Sci Bull 12(6):53–62
Yang XW, Wang WJ (1994) A statistical study on hydrodynamic sedimentation and sand movement Huangmaohai Estuary Bay. Ocean Eng 12(4):42–51
Yang XW, Yu HB, Sun ZX, Liang TM (1997) The modern dynamic geomorphological system and erosion–depositional process analysis of HuangmaoHai Bay, west of Pearl River estuary. Tropic oceanol 16(1):49–59
Yang L, Li CC, Tian XP (2006) Concentrations and content distribution of heavy metals in surface sediments in Modao Men distributary mouth of Pearl River estuary. Ecol Environ 15(3):490–494
Zhang J, Liu CL (2002) Riverine composition and estuarine geochemistry of particulate metals in China-Weathering features, anthropogenic impact and chemical fluxes. Estuar Coast Shelf Sci 54:1051–1070
Zhang GW, Ma DX, Xu MG, Zhou QW, Lan XH (1988) Sedimentary environments and structures of modern sediments in the mouth of Zhujiang river. Mar Geol Quaternary Geol 8(3):71–83
Zhang XZ, Bao ZY, Tang JH (2006) Application of the enrichment factor in evaluation of heavy metals contamination in the environmental geochemistry. Geol Sci Technol Information 25(1):65–72
Zhao HT (1983) Hydrological characteristics of the Zhujiang (pearl river) delta. Tropic Oceanol 2(2):108–117
Zhao YY, Yan MC (1994) Geochemistry of sediments of the China Shelf Sea [M]. Science Press, Beijing
Zhou HY, Peng XT, Pan JM (2004) Distribution, source and enrichment of some chemical elements in sediments of the Pearl River Estuary. China Continental Shelf Res 24:1857–1875
Zwolsman JJG, van Eck GTM, Burger G (1996) Spatial and temporal distribution of trace metals in sediments from the Scheldt Estuary, South-west Netherlands. Estuar Coast Shelf Sci 43(1):55–79
Acknowledgments
We thank Professer Zhigang Guo and Professer Dejian Fan of ocean University for their precious advice in editing the paper. This work was founded by the Research project: Envolvement, Sediment Record and Sutainable Development of Main Delta of China (908-02-02-05)and Six Framework Program, Sustainable Option for People, Catchment and Aquatic Resources (INCO-CT-2004-510706).
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Wang, S., Cao, Z., Lan, D. et al. Concentration distribution and assessment of several heavy metals in sediments of west-four Pearl River Estuary. Environ Geol 55, 963–975 (2008). https://doi.org/10.1007/s00254-007-1046-6
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DOI: https://doi.org/10.1007/s00254-007-1046-6