Abstract
57Fe Mössbauer spectra of iron bearing alumino-silicate glasses are analysed by two complementary methods (SID and x-VBF) especially adapted for the analysis of disordered systems by taking into account distributions of hyperfine Mössbauer parameters. Qualitative and quantitative information about the oxidation state of iron are obtained as well as information about the distribution of local environments of iron. The possibility to separate the signal of ferric iron from that of ferrous iron allows to derive precise redox ratio in favourable cases but also to analyse more sharply the different contributions to Mössbauer spectra. Using two different glass series (feldspar composition, haplo-tonalitic composition), the characteristics of the two methods are described and employed to study the effect of composition, water incorporation and oxidation state on the glass structure. Optical absorption spectroscopy is used to support the interpretation of the Mössbauer spectra in case of the feldspar glasses.
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Acknowledgments
The authors thank A. Bezos who kindly provided the natural MORB Mössbauer spectrum. Furthermore we would like to thank S. Hafner and D. Burkhard for assistance in collection of Mössbauer spectra at the university of Marburg. Special thanks to F. Farges who provides the authors with a review of this manuscript and to T. Berkover for his mathematical help. Authors thank B. Mysen and an anonymous reviewer for their constructive remarks.
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Rossano, S., Behrens, H. & Wilke, M. Advanced analyses of 57Fe Mössbauer data of alumino-silicate glasses. Phys Chem Minerals 35, 77–93 (2008). https://doi.org/10.1007/s00269-007-0200-8
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DOI: https://doi.org/10.1007/s00269-007-0200-8