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Erschienen in: Polymer Bulletin 2/2009

01.02.2009 | Original Paper

Synthesis, characterization, and properties of novel aromatic polyamides containing phthalazinone moiety

verfasst von: Jiahui Tan, Chenyi Wang, Weiya Peng, Guang Li, Jian-Ming Jiang

Erschienen in: Polymer Bulletin | Ausgabe 2/2009

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Abstract

A unsymmetrical and kink non-coplanar heterocyclic dicarboxylic acid monomer, 4-[4-(4-carboxy phenoxy)-naphthyl]-2-(4-carboxyphenyl)phthalazin-1-one (3) was successfully synthesized with high purity and high yields. A series of novel polyamides containing phthalazinone were prepared from the newly synthesized dicarboxylic acid with various aromatic diamines by means of the phosphorylation polycondensation reaction. Molecular weights of the obtained polyamides were evaluated viscometrically, and the inherent viscosities (ηinh) measured were in the range 0.54–0.69 dL/g. These polyamides were amorphous and readily soluble in many organic solvents, such as N-methyl-2-pyrrolidone, N,N-dimethylacetamide, N,N-dimetheylformamide, dimethyl sulfoxide, pyridine, and m-cresol etc., and they could easily be solution-cast into transparent, flexible films with good mechanical properties, with tensile strength ranging from 63.9 to 81.6 MPa and elongation at break from 7.2 to 11.4%. These polymers still kept good thermal stability with high-glass transition temperatures in the range of 283–338 °C, and the decomposition temperature in nitrogen for a 10% weight-loss temperatures in excess of 490 °C, and char yield at 800 °C in nitrogen ranged from 56 to 63%. Furthermore, the polyamides films were essentially colorless; their cut-off wavelengths were between 365 and 379 nm.

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Metadaten
Titel
Synthesis, characterization, and properties of novel aromatic polyamides containing phthalazinone moiety
verfasst von
Jiahui Tan
Chenyi Wang
Weiya Peng
Guang Li
Jian-Ming Jiang
Publikationsdatum
01.02.2009
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 2/2009
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-008-0013-z

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