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Polymer Bulletin
Erschienen in: Polymer Bulletin 7/2010

01.04.2010 | Original Paper

Synthesis and characterization of novel comb-type amphiphilic graft copolymers containing polypropylene and polyethylene glycol

verfasst von: Murat Balcı, Abdulkadir Allı, Baki Hazer, Olgun Güven, Kevin Cavicchi, Mukerrem Cakmak

Erschienen in: Polymer Bulletin | Ausgabe 7/2010

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Abstract

Amphiphilic comb-type graft copolymers containing polypropylene (PP) and polyethylene glycol (PEG) have been prepared. Polypropylene-g-polyethylene glycol comb-type thermoplastic amphiphilic copolymers were synthesized by the reaction between chlorinated polypropylene and polyethylene glycol in the presence of a base via a “grafting to” technique. A series of graft copolymers containing PEGs with molecular weights of 600 and 2,000 Da in the range of 4–34 mol% PEG were obtained. The amphiphilic graft copolymers with PEG segments in range between 20 and 30 mol% PEG displayed good film properties with elongation at break 275–440%. The hydrophilicity of the amphiphilic copolymers increases with the increasing PEG content in the copolymer while the mechanical properties decrease. Therefore, PP-g-PEG2000 with PEG contents in the range of 20–30 mol% PEG should be useful for medical and industrial applications where good film properties are needed.
Vorheriger Artikel Preparation and rheological properties of SEM-25 containing associative thickener latexes and their mechanisms of thickening
Nächster Artikel Effect of heating process on the formation of nanoparticles of elastin model polypeptide, (GVGVP)251, by gamma-ray crosslinking

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Metadaten
Titel
Synthesis and characterization of novel comb-type amphiphilic graft copolymers containing polypropylene and polyethylene glycol
verfasst von
Murat Balcı
Abdulkadir Allı
Baki Hazer
Olgun Güven
Kevin Cavicchi
Mukerrem Cakmak
Publikationsdatum
01.04.2010
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 7/2010
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-009-0211-3

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