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Erschienen in: Polymer Bulletin 6/2013

01.06.2013 | Original Paper

One-pot synthesis of branched alternating copolymers P(St-alt-MAn) via free radical polymerization in the presence of chain transfer monomer

verfasst von: Jingcheng Liu, Xiaomei Xiong, Ren Liu, Jinqiang Jiang, Xiaoya Liu

Erschienen in: Polymer Bulletin | Ausgabe 6/2013

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Abstract

Novel branched alternating copolymers poly(styrene-alt-maleic anhydride) (BPSMA) were synthesized through free radical polymerization with styrene, maleic anhydride, and chain transfer monomer, 4-vinyl benzyl thiol. The successful synthesis of BPSMA was confirmed by a triple detection system including gel permeation chromatography, multiangle laser light scattering, and differential viscosity detectors, as well as thermal analysis (differential scanning calorimetry). This methodology proposes good prospects for scaling-up and thereby offers a wide range of branched alternating copolymers at low cost.

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Literatur
1.
Zurück zum Zitat Go C, Yan D (2004) Hyperbranched polymers: from synthesis to applications. Prog Polym Sci 29:183–275CrossRef Go C, Yan D (2004) Hyperbranched polymers: from synthesis to applications. Prog Polym Sci 29:183–275CrossRef
2.
Zurück zum Zitat Ishizu K, Takahashi D, Takeda H (2000) Novel synthesis and characterization of hyperbranched polymers. Polymer 41:6081–6086CrossRef Ishizu K, Takahashi D, Takeda H (2000) Novel synthesis and characterization of hyperbranched polymers. Polymer 41:6081–6086CrossRef
3.
Zurück zum Zitat Shi J, Jim CKW, Mahtab F, Liu J, Lam JWY, Sung HHY, Williams ID, Dong YP, Tang BZ (2010) Ferrocene-functionalized hyperbranched polyphenylenes: synthesis, redox activity, light refraction, transition-metal complexation, and precursors to magnetic ceramics. Macromolecules 43:680–690CrossRef Shi J, Jim CKW, Mahtab F, Liu J, Lam JWY, Sung HHY, Williams ID, Dong YP, Tang BZ (2010) Ferrocene-functionalized hyperbranched polyphenylenes: synthesis, redox activity, light refraction, transition-metal complexation, and precursors to magnetic ceramics. Macromolecules 43:680–690CrossRef
4.
Zurück zum Zitat Tang Y, Jim CKW, Liu Y, Ye L, Qin A, Lam JWY, Zhao C, Tang BZ (2010) Synthesis and curing of hyperbranched poly(triazole)s with click polymerization for improved adhesion Strength. ACS Appl Mater Interfaces 2:566–574CrossRef Tang Y, Jim CKW, Liu Y, Ye L, Qin A, Lam JWY, Zhao C, Tang BZ (2010) Synthesis and curing of hyperbranched poly(triazole)s with click polymerization for improved adhesion Strength. ACS Appl Mater Interfaces 2:566–574CrossRef
5.
Zurück zum Zitat Jikei M, Kakimoto M (2001) Hyperbranched polymer: a promising new class of materials. Prog Polym Sci 26:1233–1285CrossRef Jikei M, Kakimoto M (2001) Hyperbranched polymer: a promising new class of materials. Prog Polym Sci 26:1233–1285CrossRef
6.
Zurück zum Zitat Fréchet JMJ, Henmi M, Gitsov I, Aoshima S, Leduc M, Grubbs RB (1995) Self condensing vinyl polymerization: a new approach to dendritic materials. Science 269:1080–1083CrossRef Fréchet JMJ, Henmi M, Gitsov I, Aoshima S, Leduc M, Grubbs RB (1995) Self condensing vinyl polymerization: a new approach to dendritic materials. Science 269:1080–1083CrossRef
7.
Zurück zum Zitat Hawker CJ, Bosman AW, Harth E (2001) New polymer synthesis by nitroxide mediated living radical polymerizations. Chem Rev 101:3661–3688CrossRef Hawker CJ, Bosman AW, Harth E (2001) New polymer synthesis by nitroxide mediated living radical polymerizations. Chem Rev 101:3661–3688CrossRef
8.
Zurück zum Zitat Bally F, Ismailova E, Brochon C, Serra CA, Hadziioannou G (2011) Mechanistic study of atom transfer radical polymerization in the presence of an inimer: toward highly branched controlled macromolecular architectures through one-pot reaction. Macromolecules 44:7124–7131CrossRef Bally F, Ismailova E, Brochon C, Serra CA, Hadziioannou G (2011) Mechanistic study of atom transfer radical polymerization in the presence of an inimer: toward highly branched controlled macromolecular architectures through one-pot reaction. Macromolecules 44:7124–7131CrossRef
9.
Zurück zum Zitat Lv MQ, Shi Y, Yang WT, Fu ZF (2012) Synthesis of amphiphilic heteroarm star-shaped polymer via free radical polymerization using polyfunctional chain transfer agent and its self-assembly behavior. J Appl Polym Sci. doi:10.1002/APP.38173 Lv MQ, Shi Y, Yang WT, Fu ZF (2012) Synthesis of amphiphilic heteroarm star-shaped polymer via free radical polymerization using polyfunctional chain transfer agent and its self-assembly behavior. J Appl Polym Sci. doi:10.​1002/​APP.​38173
10.
Zurück zum Zitat Liu W, Dong CM (2010) Versatile strategy for the synthesis of hyperbranched poly(ε-caprolactone)s and polypseudorotaxanes thereof. Macromolecules 43:8447–8455CrossRef Liu W, Dong CM (2010) Versatile strategy for the synthesis of hyperbranched poly(ε-caprolactone)s and polypseudorotaxanes thereof. Macromolecules 43:8447–8455CrossRef
11.
Zurück zum Zitat Isaure F, Cormack PAG, Sherrington DC (2004) Synthesis of branched poly (methyl methacrylate)s: effect of the branching comonomer structure. Macromolecules 37:2096–2105CrossRef Isaure F, Cormack PAG, Sherrington DC (2004) Synthesis of branched poly (methyl methacrylate)s: effect of the branching comonomer structure. Macromolecules 37:2096–2105CrossRef
12.
Zurück zum Zitat Graham S, Cormack PAG, Sherrington DC (2005) One-pot synthesis of branched poly(methacrylic acid)s and suppression of the rheological “polyelectrolyte effect”. Macromolecules 38:86–90CrossRef Graham S, Cormack PAG, Sherrington DC (2005) One-pot synthesis of branched poly(methacrylic acid)s and suppression of the rheological “polyelectrolyte effect”. Macromolecules 38:86–90CrossRef
13.
Zurück zum Zitat Baudry R, Sherrington DC (2006) Facile synthesis of branched poly(vinyl alcohol)s. Macromolecules 39:5230–5237CrossRef Baudry R, Sherrington DC (2006) Facile synthesis of branched poly(vinyl alcohol)s. Macromolecules 39:5230–5237CrossRef
14.
Zurück zum Zitat Liu J, Wang Y, Fu Q, Zhu X, Shi W (2008) Branched polymer via free radical polymerization of chain transfer monomer: a theoretical and experimental investigation. J Polym Sci A 46:1449–1459CrossRef Liu J, Wang Y, Fu Q, Zhu X, Shi W (2008) Branched polymer via free radical polymerization of chain transfer monomer: a theoretical and experimental investigation. J Polym Sci A 46:1449–1459CrossRef
15.
Zurück zum Zitat Jiang L, Huang WY, Xue XQ, Yang HJ, Jiang B–B et al (2012) Radical polymerization in the presence of chain transfer monomer: an approach to branched vinyl polymers. Macromolecules 45:4092–4100CrossRef Jiang L, Huang WY, Xue XQ, Yang HJ, Jiang B–B et al (2012) Radical polymerization in the presence of chain transfer monomer: an approach to branched vinyl polymers. Macromolecules 45:4092–4100CrossRef
16.
Zurück zum Zitat Liu XY, Yi CL, Zhu Y, Jiang JQ, Jiang M (2010) Pickering emulsions stabilized by self-assembled colloidal particles of copolymers of P(St-alt-MAn)-co-P(VM-alt-MAn). J Colloid Interface Sci 351:315–322CrossRef Liu XY, Yi CL, Zhu Y, Jiang JQ, Jiang M (2010) Pickering emulsions stabilized by self-assembled colloidal particles of copolymers of P(St-alt-MAn)-co-P(VM-alt-MAn). J Colloid Interface Sci 351:315–322CrossRef
17.
Zurück zum Zitat Liu JC, Wang BQ, Luo J, Liu XY (2012) Aqueous dispersions of carbon nanotubes with self-assembled micelles of photosensitive amphiphilic random copolymer containing coumarin. Chem Lett 41:50–52CrossRef Liu JC, Wang BQ, Luo J, Liu XY (2012) Aqueous dispersions of carbon nanotubes with self-assembled micelles of photosensitive amphiphilic random copolymer containing coumarin. Chem Lett 41:50–52CrossRef
18.
Zurück zum Zitat Peng M, Qi J, Zhou Z, Liao ZJ, Zhu ZM, Guo HL (2010) Carbon nanotubes noncovalently functionalized by an organic–inorganic hybrid: new building blocks for constructing superhydrophobic conductive coatings. Langmuir 26:13062–13064CrossRef Peng M, Qi J, Zhou Z, Liao ZJ, Zhu ZM, Guo HL (2010) Carbon nanotubes noncovalently functionalized by an organic–inorganic hybrid: new building blocks for constructing superhydrophobic conductive coatings. Langmuir 26:13062–13064CrossRef
19.
Zurück zum Zitat Zhu MQ, Wei LH, Li M, Jiang L, Du FS, Li ZC, Li FM (2001) A unique synthesis of a well-defined block copolymer having alternating segments constituted by maleic anhydride and styrene and the self-assembly aggregating behavior thereof. Chem Commun 365–366 Zhu MQ, Wei LH, Li M, Jiang L, Du FS, Li ZC, Li FM (2001) A unique synthesis of a well-defined block copolymer having alternating segments constituted by maleic anhydride and styrene and the self-assembly aggregating behavior thereof. Chem Commun 365–366
20.
Zurück zum Zitat Jiang JQ, Jia XL, Chen X, Liu XY, Chen MQ (2011) A novel approach to branched polymers via latent thiol chain-transfer polymerization. Chem Lett 12:1378–1380CrossRef Jiang JQ, Jia XL, Chen X, Liu XY, Chen MQ (2011) A novel approach to branched polymers via latent thiol chain-transfer polymerization. Chem Lett 12:1378–1380CrossRef
21.
Zurück zum Zitat Burchard W (1999) Solution properties of branched macromolecules. In: Roovers J (ed) branched polymers II. Advances in polymer science series, vol. 143. Springer, Berlin, pp. 113–194. doi:10.1007/3-540-49780-3_3 Burchard W (1999) Solution properties of branched macromolecules. In: Roovers J (ed) branched polymers II. Advances in polymer science series, vol. 143. Springer, Berlin, pp. 113–194. doi:10.​1007/​3-540-49780-3_​3
22.
Zurück zum Zitat Zimm BH, Stockmayer WH (1949) The dimensions of chain molecules containing branches and rings. J Chem Phys 17:1301CrossRef Zimm BH, Stockmayer WH (1949) The dimensions of chain molecules containing branches and rings. J Chem Phys 17:1301CrossRef
Metadaten
Titel
One-pot synthesis of branched alternating copolymers P(St-alt-MAn) via free radical polymerization in the presence of chain transfer monomer
verfasst von
Jingcheng Liu
Xiaomei Xiong
Ren Liu
Jinqiang Jiang
Xiaoya Liu
Publikationsdatum
01.06.2013
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 6/2013
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-013-0922-3

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