Abstract
ZrO2 nanopowders were synthesized by a glycine nitrate process route. These nanopowders exhibit a tetragonal major phase in a broad range of annealing temperature and annealing time. The photoluminescence spectra of the samples consist of a UV band centered at 385 nm and a blue band centered at 442 nm. Based on annealing experiments in different atmospheres, these two emission bands are tentatively ascribed to singly ionized oxygen-vacancy defects and singly ionized associated oxygen vacancy defects, respectively. Their photoluminescence properties and photoluminescence intensity change behaviors with annealing time as well as with annealing temperature are discussed.
Similar content being viewed by others
References
I.D. Licka, A. Carrascullb, M. Ponzi: Catal. Lett. 89, 179 (2003)
K.T. Jung, A.T. Bell: Catal. Lett. 80, 63 (2002)
K. Sayama, H. Arakawa: J. Phys. Chem. 97, 5316 (1993)
S. Wang, K. Murata Hayakawa: Chem. Commun. 1, 103 (1999)
K. Tanabe: Mater. Chem. 13, 347 (1985)
Z. Fu, B. Yang, L. Li, W. Dong: J. Phys.: Condens. Matter 15, 2867 (2003)
Y. Liu, R.O. Claus: J. Am. Chem. Soc. 119, 5273 (1997)
H. Zhou, W. Cai, L. Zhang: Appl. Phys. Lett. 75, 495 (1999)
C. Bonola, P. Camagni, N. Omemettp: J. Luminesc. 48–49, 797 (1991)
H.R. Chen, J.L. Shi, Y. Yang, D.S. Yan: Appl. Phys. Lett. 81, 2761 (2002)
W. Stichert, F. Schuth: Chem. Mater. 10, 2020 (1998)
N.L. Wu, T.F. Wu: J. Am. Ceram. Soc. 83, 3225 (2000)
J. Liang, Z. Deng, X. Jiang: Inorg. Chem. 41, 3602 (2002)
D.A. Ward, I.K.O. Edmond: Chem. Mater. 5, 956 (1993)
S. Tsunekawa, S. Ito, Y. Kawazoe: Nano Lett. 3, 871 (2003)
J. Joo, T. Yu, Y.W. Kim, H.M. Park: J. Am. Chem. Soc. 125, 6553 (2003)
P. Iacconi, D. Lapraz, R. Caruba: Phys. Status Solidi A 50, 275 (1978)
M. García-Hipólito, R. Martínez, O. Alvarez-Fregoso: J. Luminesc. 93, 9 (2001)
V.A. Emeline, N. Serpone: Chem. Phys. Lett. 345, 105 (2001)
W.C. Hsieh, C.S. Su: J. Phys. D: Appl. Phys. 27, 1763 (1994)
A. Emeline, G.V. Kataeva, A.S. Litke: Langmuir 14, 5011 (1998)
N.G. Petrik, D.P. Taylor, T.M. Orlando: J. Appl. Phys. 85, 6770 (1999)
E.I. Rashba, M.D. Sturge: Excitons (North-Holland, Amsterdam, New York, Oxford 1982)
Z. Wei, W. Zheng, F. Li: Chin. J. Luminesc. 23, 302 (2002)
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
78.55.-m; 81.20.Ka; 61.46.+w
Rights and permissions
About this article
Cite this article
Wang, Z., Yang, B., Fu, Z. et al. UV–blue photoluminescence from ZrO2 nanopowders prepared via glycine nitrate process. Appl. Phys. A 81, 691–694 (2005). https://doi.org/10.1007/s00339-005-3238-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-005-3238-9