Skip to main content
SpringerLink
Log in

Study of A-site doping of SrBi4Ti4O15 Bi-layered compounds using micro-Raman spectroscopy

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The temperature-dependent Raman spectra of Mg- and La-doped SrBi4Ti4O15 (SBT) were studied in the range 40–590 °C. A quantum chemistry calculation was employed to estimate these two substitution states. It was found that A-site doping in this study not only caused multiplicative substitution states, but also the Raman spectra changed with the substitution amount. In a La-doped perovskite-like layer, La would occupy the Bi site when x>0.10 and the 314 and 550 cm-1 modes related to the rotating and tilting of the TiO6 octahedron firstly became wide and then became sharp. With the increase of the substitution amount, both substitution states of Mg-doped SBT lead to the widening of 270 and 520 cm-1 peaks.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P.S. Dobal, R.R. Das, B. Roy, R.S. Katiyar, S. Jain, D.C. Agrawal, J. Raman Spectrosc. 31, 965 (2000)

    Article  Google Scholar 

  2. C.H. Hervoches, A. Snedden, R. Riggs, S.H. Kilcoyne, P. Manuel, P. Lightfoot, J. Solid State Chem. 164, 280 (2002)

    Article  ADS  Google Scholar 

  3. I. Brett, A. Hunter, B.J. Kennedy, Solid State Ionics 112, 281 (1998)

    Article  Google Scholar 

  4. R.Z. Hou, X.M. Chen, Solid State Commun. 130, 469 (2004)

    Article  ADS  Google Scholar 

  5. C.H. Hervoches, P. Lightfoot, J. Solid State Chem. 153, 66 (2000)

    Article  ADS  Google Scholar 

  6. A. Tkach, P.M. Vilarinho, A. Kholkin, Appl. Phys. A 79, 2013 (2003)

    ADS  Google Scholar 

  7. J. Wang, G.X. Cheng, S.T. Zhang, H.W. Cheng, Y.F. Chen, Physica B 344, 368 (2004)

    Article  ADS  Google Scholar 

  8. P.S. Dobal, R.S. Katiyar, J. Raman Spectrosc. 33, 405 (2002)

    Article  Google Scholar 

  9. S. Kojima, R. Imaizumi, S. Hamazaki, M. Takashige, J. Mol. Struct. 348, 37 (1995)

    Article  ADS  Google Scholar 

  10. F. Lanciotti Jr., P.S. Pizani, I.A. Santos, C.V. do Carmo, D. Garcia, J.A. Eiras, J. Phys. Chem. Solids 62, 1247 (2001)

    Article  ADS  Google Scholar 

  11. S. Kojima, I. Saitoh, Physica B 263–264, 653 (1999)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 430070, Wuhan, P.R. China

    H. Hao & H.X. Liu

  2. School of Material Science and Engineering, Key Laboratory for Silicate Materials Science and Engineering, Wuhan University of Technology, 430070, Wuhan, P.R. China

    H. Hao, H.X. Liu, M.H. Cao, X.M. Min & S.X. Ouyang

Authors
  1. H. Hao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H.X. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M.H. Cao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. X.M. Min
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S.X. Ouyang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. Hao.

Additional information

PACS

78.30.-J; 77.84.-s

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hao, H., Liu, H., Cao, M. et al. Study of A-site doping of SrBi4Ti4O15 Bi-layered compounds using micro-Raman spectroscopy. Appl. Phys. A 85, 69–73 (2006). https://doi.org/10.1007/s00339-006-3651-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-006-3651-8

Keywords

Search

Navigation