Abstract
Y2O3:Eu3+ luminescent thin films have been studied as a potential red phosphor thin film for application in field emission display. Y2O3:Eu3+ and Li-doped Y2O3:Eu3+ films have been grown on Al2O3(0001) substrates using a pulsed laser deposition technique at substrate temperature of 600 °C under the various oxygen pressures. The cathodoluminescent intensity of the Y2O3:Eu3+ films were highly dependent not only on the crystallinity, but also on the surface roughness of the films. Cathodoluminescent spectra for both Y2O3:Eu3+ and Li-doped Y2O3:Eu3+ films were dominated by the red emission peak at 612 nm radiated by the transition of 5D0-7F2 within europium and the brightness of the Li-doped films was increased by a factor of 1.4 in comparison with that of the Y2O3:Eu3+ films. It is understood that Li ions affect the luminescence of the Y2O3:Eu3+ films by influencing its crystallinity and surface roughness. The cathodoluminescent intensity and surface roughness had similar behavior as a function of oxygen pressure.
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References
S. Itoh, T. Kimizuka, T. Tonegawa, J. Electrochem. Soc. 136, 1819 (1989)
T.H.C. Swart, J.S. Sebasebian, T.A. Tronier, S.L. Jones, P.H. Holloway, J. Vac. Sci. Technol. A 13, 1697 (1996)
R.K. Singh, J. Narayan, Phys. Rev. B 41, 8843 (1991)
A. Gupta, in: Pulsed Laser Deposition of Thin Films, ed. by D.B. Chrisey, G.K. Hubbler (Wiley, New York, 1994), p. 265
A. Greer, M. Tahal, Mater. Res. Soc. Symp. Proc. 341, 87 (1994)
S.S. Yi, J. Korean Phys. Soc. 45, 1625 (2004)
F.K. Shan, B.C. Shin, S.C. Kim, Y.S. Yu, J. Korean Phys. Soc. 42, S1174 (2003)
J.H. Jeong, J.S. Bae, S.-S. Yi, J.-C. Park, Y.S. Kim, J. Phys.: Condens. Matter 15, 567 (2003)
S.-S. Yi, J.S. Bae, K.S. Shim, J.H. Jeong, J.-C. Park, P.H. Holloway, Appl. Phys. Lett. 84, 353 (2004)
S.S. Yi, J.S. Bae, K.S. Shim, B.K. Moon, H.J. Seo, J.H. Jeong, J.H. Kim, Appl. Phys. A 80, 727 (2005)
S.S. Yi, J.S. Bae, B.K. Moon, J.H. Jeong, J.H. Kim, Appl. Phys. Lett. 86, 1921 (2005)
K.C. Misbra, J.K. Berkowitz, K.H. Johnson, P.C. Schmidt, Phys. Rev. B 45, 10902 (1992)
O.A. Lopez, J. McKittrick, L.E. Shea, J. Luminesc. 71, 1 (1997)
D. Hommel, H. Hartmann, J. Cryst. Growth 72, 346 (1985)
S.M. Yeh, C.S. Su, Mater. Sci. Eng. B 38, 245 (1996)
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78.20.-e; 78.55.-m; 78.66.-w
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Yi, S., Shim, K., Yang, H. et al. Improved cathodoluminescent characteristics of Y2O3:Eu3+ thin films by Li-doping. Appl. Phys. A 87, 667–671 (2007). https://doi.org/10.1007/s00339-007-3945-5
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DOI: https://doi.org/10.1007/s00339-007-3945-5