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Carbonyl groups development on degraded cellulose. Correlation between spectroscopic and chemical results

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Abstract

Cellulose undergoing accelerated hydrothermal ageing gives a pattern of carbonyl groups whose vibrational modes were observed in UV/VI/NIR, FTIR and Raman spectra. Indirectly their presence in degraded samples was observed traced by the changes in the degree of polymerization (DP) and acidity (pH). Conjugated ketonic groups found in FTIR and Raman spectra after accelerated ageing were correlated to the chromophores detected by UV/VIS. A simple model describing the formation of chromophores was put forward and verified by experiments.

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Authors and Affiliations

  1. Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060, Kraków, Poland

    J. Łojewska, K. Ziȩba & L.M. Proniewicz

  2. Istituto centrale per la patologia del libro, Dipartimento per la ricerca e l’innovazione, Ministero per i beni e le attività culturali, v. Milano 76, 00184, Rome, Italy

    M. Missori

  3. Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, 30-239, Kraków, Poland

    A. Lubańska

  4. Dipartimento di Fisica, Università di Roma “La Sapienza”, P.A. Moro 5, 00185, Rome, Italy

    P. Grimaldi & A. Congiu Castellano

Authors
  1. J. Łojewska
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  2. M. Missori
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  3. A. Lubańska
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  4. P. Grimaldi
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  5. K. Ziȩba
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  6. L.M. Proniewicz
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  7. A. Congiu Castellano
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Corresponding author

Correspondence to J. Łojewska.

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PACS

81.05.-t; 82.20.Wt; 36.20.Kd; 36.20.Ng

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Łojewska, J., Missori, M., Lubańska, A. et al. Carbonyl groups development on degraded cellulose. Correlation between spectroscopic and chemical results. Appl. Phys. A 89, 883–887 (2007). https://doi.org/10.1007/s00339-007-4220-5

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  • DOI: https://doi.org/10.1007/s00339-007-4220-5

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