Skip to main content
Log in

Study of anti-clockwise bipolar resistive switching in Ag/NiO/ITO heterojunction assembly

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

The anti-clockwise bipolar resistive switching in Ag/NiO/ITO (Indium–Tin–Oxide) heterojunctional thin film assembly is investigated. A sequential voltage sweep in 0 → V max → 0 → −V min → 0 order shows intrinsic hysteresis behaviour and resistive switching in current density (J)–voltage (V) measurements at room temperature. Switching is induced by possible rupture and recovery of the conducting filaments in NiO layer mediated by oxygen ion migration and interfacial effects at NiO/ITO junction. In the high-resistance OFF-state space charge limited current passes through the filamentary path created by oxygen ion vacancies. In OFF-state, the resistive switching behaviour is attributed to trapping and detrapping processes in shallow trap states mostly consisting of oxygen vacancies. The slope of Log I vs Log V plots, in shallow trap region of space charge limited conduction is ~2 (I ∝ V 2) followed by trap-filled and trap-free conduction. In the low-resistance ON-state, the observed electrical features are governed by the ohmic conduction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Y.C. Yang, F. Pan, F. Zeng, M. Liu, J. Appl. Phys. 106, 123705-5 (2009)

    ADS  Google Scholar 

  2. A. Sawa, Mater. Today 11, 28–36 (2008)

    Article  Google Scholar 

  3. K.M. Kim, D.S. Jeong, C.S. Hwang, Nanotechnology 22, 254002 (2011)

    Article  ADS  Google Scholar 

  4. C.Y. Lin, C.Y. Wu, C.Y. Wu, C.T. Lee, F.L. Yang, C. Hu, T.Y. Tseung, IEEE Elect. Dev. Lett. 28(5), 366 (2007)

    Article  ADS  Google Scholar 

  5. J.Y. Son, Y.H. Shin, Appl. Phys. Lett. 92, 222106-3 (2008)

    ADS  Google Scholar 

  6. B.J. Choi, D.S. Jeong, S.K. Kim, C. Rohde, S. Choi, J.H. Oh, H.J. Kim, C.S. Hwang, K. Szot, R. Waser, B. Reichenberg, S. Tiedke, J. Appl. Phys. 98, 033715-10 (2005)

    ADS  Google Scholar 

  7. D.H. Kwon, K.M. Kim, J.H. Jang, J.M. Jeon, M.H. Lee, G.H. Kim, X.S. Li, G.S. Park, B. Lee, S. Han, M. Kim, C.S. Hwang, Nat. Nanotech. 5, 148–153 (2010)

    Article  ADS  Google Scholar 

  8. J.P. Strachan, M.D. Pickett, J.J. Yang, S. Aloni, A.L.D. Kilcoyne, G. Medeiros-Ribeiro, R.S. Williams, Adv. Mater. 22, 3573–3577 (2010)

    Article  Google Scholar 

  9. J.J. Yang, F. Miao, M.D. Pickett, D.A.A. Ohlberg, D.R. Stewart, C.N. Lau, R.S. Williams, Nanotechnology 20, 215201 (2010)

    Article  Google Scholar 

  10. J.J. Huang, C.W. Kuo, W.C. Chang, T.H. Hou, Appl. Phys. Lett. 96, 262901-3 (2010)

    ADS  Google Scholar 

  11. J.F. Gibbons, W.E. Beadle, Solid-State Electron 7, 785–790 (1964)

    Article  ADS  Google Scholar 

  12. A. Chen, S. Haddad, W. Yi-Ching, F. Tzu-Ning, L. Zhida, S. Avanzino, S. Pangrle, M. Buynoski, M. Rathor, C. Wei, N. Tripsas, C. Bill, M. VanBuskirk, M. Taguchi, IEDM Tech. Dig. IEEE Int. (2005). doi:10.1109/IEDM.2005.1609461

    Google Scholar 

  13. L.D. Bozano, B.W. Kean, M. Beinhoff, K.R. Carter, P.M. Rice, J.C. Scott, Adv. Funct. Mater. 15, 1933–1939 (2005)

    Article  Google Scholar 

  14. H. Schroeder, D.S. Jeong, Microelectron Eng. 84, 1982–1985 (2007)

    Article  Google Scholar 

  15. N. Xu, L.F. Liu, X. Sun, C. Chen, Y. Wang, D.D. Han, X.Y. Liu, R.Q. Han, J.F. Kang, B. Yu, Semicond. Sci. Technol. 23, 075019-4 (2008)

    Article  ADS  Google Scholar 

  16. K.M. Kim, G.H. Kim, S.J. Song, J.Y. Seok, M.H. Lee, J.H. Yoon, C.S. Hwang, Nanotechnology 21, 305203-3 (2010)

    ADS  Google Scholar 

  17. K.S. Vasu, S. Sampath, A.K. Sood, Solid State Commun. 151, 1084–1087 (2011)

    Article  ADS  Google Scholar 

  18. M.H. Lee, C.S. Hwang, Nanoscale 3, 490–502 (2011)

    Article  ADS  Google Scholar 

  19. K.L. Lin, T.H. Hou, J. Shieh, J.H. Lin, C.T. Chou, Y.J. Lee, J. Appl. Phys. 109, 084104–084107 (2011)

    Article  ADS  Google Scholar 

  20. A. Lamperti, S. Spiga, H.L. Lu, C. Wiemer, M. Perego, E. Cianci, M. Alia, M. Fanciulli, Microelectron Eng. 85, 2425–2429 (2008)

    Article  Google Scholar 

  21. W. Shen, Investigation of resistive switching in barium strontium titanate thin films for memory applications (Forschungszentrum Jülich GmbH, Germany, 2009), p. 81

    Google Scholar 

  22. A. Zydor, S.D. Elliott, J. Phys. Chem. A 114, 1879–1886 (2010)

    Article  Google Scholar 

  23. J.H. Hur, M.J. Lee, C.B. Lee, Y.B. Kim, C.J. Kim, Phys. Rev. B 82, 155321–155325 (2010)

    Article  ADS  Google Scholar 

  24. K. Kinoshtia, T. Okutani, H. Tanaka, T. Hinoki, K. Yazawa, K. Ohmi, S. Kishida, Appl. Phys. Lett. 96, 143505-3 (2010)

    Article  ADS  Google Scholar 

  25. C. Liu, F. Kurnia, Hadiyawarman, C.U. Jung, S.B. Lee, S.M. Yang, H.W. Park, S.J. Song, C.S. Hwang, J. Kor, Phys. Soc. 57, 1856–1861 (2010)

    Google Scholar 

  26. K.M. Kim, J.C. Byung, S.H. Cheol, Appl. Phys. Lett. 90, 242906-3 (2007)

    ADS  Google Scholar 

  27. International Centre for Diffraction Data (ICDD). Joint Committee on Powder Diffraction Standards (JCPDS) file number 44-1159, NiO, wavelength 1.54056, space group R\( {\bar 3} \)m [166], a = 2.955, c = 7.227, CAS No. 1313-99-1 (2003)

  28. K.P. Biju, X. Liu, M. Siddik, S. Kim, J. Shin, I. Kim, A. Ignatiev, H. Hwang, J. Appl. Phys. 110, 064505–064507 (2011)

    Article  ADS  Google Scholar 

  29. Y.T. Tsai, T.C. Chang, W.L. Huang, C.W. Huang, Y.E. Syu, S.C. Chen, M.S. Sze, M.J. Tsai, T.Y. Tseng, Appl. Phys. Lett. 99, 092106-3 (2011)

    ADS  Google Scholar 

  30. Q. Wang, D.S. Shang, Z.H. Wu, L.D. Chen, X.M. Li, Appl. Phys. A Mater. Sci. Process 86, 357–360 (2007)

    Article  ADS  Google Scholar 

  31. V.A. Gnatyuk, T. Aoki, Y. Hatanaka, O.I. Vlasenko, Appl. Surf. Sci. 244, 528–532 (2005)

    Article  ADS  Google Scholar 

  32. Sung-Wook Chung, Yu. Jae-Young, R. James, Heath Appl. Phys. Lett. 76, 2068–2070 (2000)

    Article  ADS  Google Scholar 

  33. J.C. de Berne`, S. Houari, D. Nguyen, P.Y. Jouan, A. Khelil, A. Mokrani, L. Cattin, P. Predeep, Phys. Status Solidi A 209(7), 1291–1297 (2012)

    Article  ADS  Google Scholar 

  34. P.S. Abthagir, R. Saraswathi, J. Appl. Polym. Sci. 81, 2127–2135 (2001)

    Article  Google Scholar 

  35. S. Das, J.-H. Kim, Y.-K. Park, Y.-B. Hahn, Appl. Phys. Lett. 98, 202102 (2011)

    Article  ADS  Google Scholar 

  36. G. Greco, P. Prystawko, M. Leszczyński, R. Lo Nigro, V. Raineri, F. Roccafort, J. Appl. Phys. 110, 123703 (2011)

    Article  ADS  Google Scholar 

  37. C.B. Lee, B.S. Kang, A. Benayad, M.J. Lee, S.E. Ahn, K.H. Kim, G. Stefanovich, Y. Park, I.K. Yoo, Appl. Phys. Lett. 93, 042115-3 (2008)

    ADS  Google Scholar 

  38. K.K. Chiang, J.S. Chen, J.J. Wu, Appl. Mater. Interfaces 4, 4237–4245 (2012)

    Article  Google Scholar 

  39. S. Seo, M.J. Lee, D.C. Kim, S.E. Ahn, B.-H. Park, Y.S. Kim, I.K. Yoo, I.S. Byun, I.R. Hwang, S.H. Kim, J.-S. Kim, J.S. Choi, J.H. Lee, S.H. Jeon, S.H. Hong, B.H. Park, Appl. Phys. Lett. 87, 263507-3 (2005)

    ADS  Google Scholar 

  40. S. Das, T. Ghoshal, P.M.G. Nambissan, Phys. Status Solidi 6(11), 2569–2571 (2009)

    Article  Google Scholar 

  41. J.S. Kwak, Y.H. Do, Y.C. Bae, H.S. Im, J.H. Yoo, M.G. Sung, Y.T. Hwang, J.P. Hong, Appl. Phys. Lett. 96, 223502–223503 (2010)

    Article  ADS  Google Scholar 

  42. S.H. Phark, R. Jung, Y.J. Chang, T.W. Noh, D.W. Kim, Appl. Phys. Lett. 94, 022906-3 (2009)

    Article  ADS  Google Scholar 

  43. M. Kawai, K. Ito, Y. Shimakawa, Appl Phys Lett 95, 012109-3 (2009)

    ADS  Google Scholar 

  44. S.R. Lee, K. Char, D.C. Kim, R. Jung, S. Seo, X.S. Li, G.-S. Park, I.K. Yoo, Appl. Phys. Lett. 91, 202115-3 (2007)

    ADS  Google Scholar 

  45. B.V. Mistry, P. Bhatt, K.H. Bhavsar, S.J. Trivedi, U.N. Trivedi, U.S. Joshi, Thin Solid Films 519, 3840–3843 (2011)

    Article  ADS  Google Scholar 

  46. H. Sawada, K. Kawakami, J. Appl. Phys. 86, 956 (1999)

    Article  ADS  Google Scholar 

  47. R. Ramprasad, J. Appl. Phys. 94, 5609 (2003)

    Article  ADS  Google Scholar 

  48. Y.H. Do, J.S. Kwak, Y.C. Bae, K. Jung, H. Im, J.P. Hong, Appl. Phys. Lett. 95, 093507 (2009)

    Article  ADS  Google Scholar 

  49. S.E. Ahn, B.S. Kang, Curr. Appl. Phys. 11, S349–S351 (2011)

    Article  ADS  Google Scholar 

  50. X.L. Jiang, Y.G. Zhao, Y.S. Chen, D. Li, Y.X. Luo, D.Y. Zhao, Z. Sun, J.R. Sun, H.W. Zhao, Appl. Phys. Lett. 102, 253507 (2013)

    Article  ADS  Google Scholar 

  51. L. Goux, P. Czarnecki, Y.Y. Chen, L. Pantisano, X.P. Wang, R. Degraeve, B. Govoreanu, M. Jurczak, D.J. Wouters, L. Altimime, Appl. Phys. Lett. 97, 243509 (2010)

    Article  ADS  Google Scholar 

  52. L. Goux, Y.Y. Chen, L. Pantisano, X.P. Wang, G. Groeseneken, M. Jurczak, D.J. Wouters, Electrochem. Solid-State Lett. 13, G54 (2010)

    Article  Google Scholar 

  53. S. Yu, X. Guan, H.S.P. Wong, Appl. Phys. Lett. 99, 063507 (2011)

    Article  Google Scholar 

  54. M.C. Chen, T.C. Chang, S.Y. Huang, S.C. Chen, C.W. Hu, C.T. Tsai, S.M. Sze, Electrochem Solid State Lett. 13, H191–H193 (2010)

    Article  Google Scholar 

  55. Y.H. Tseng, W.C. Shen, C.J. Lin, J. Appl. Phys. 111, 073701–073705 (2012)

    Article  ADS  Google Scholar 

  56. B.T. Phan, C. Jung, T. Choi, J. Lee, J. Kor, Phys. Soc. 51(2), 664–668 (2007)

    Google Scholar 

Download references

Acknowledgments

SM would like to thank Department of Science and Technology (Nano Science & Technology Project, IIIrd Series) for providing fund. Special thanks to Prof. S. Bhunia for providing with laboratory facility for electrical characterization of the present samples.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Subarna Mitra.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mitra, S., Chakraborty, S. & Menon, K.S.R. Study of anti-clockwise bipolar resistive switching in Ag/NiO/ITO heterojunction assembly. Appl. Phys. A 115, 1173–1179 (2014). https://doi.org/10.1007/s00339-013-8105-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-013-8105-5

Keywords

Navigation