Skip to main content
Log in

Structural, morphologic and optical characterization of In(2−x)Al x S3

  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

Aluminum-doped indium sulfide thin films are deposited on glass by spray pyrolysis technique. The structure and the surface morphology of these films were characterized by X-ray diffraction and atomic force microscopy. The effects of aluminum ratio z and substrate temperature T s, on the film structure and grain size are discussed. The influence of aluminum ratio on surface morphology is revealed by scanning electron microscope. Besides, energy dispersive spectrometry technique is used to compare atomic aluminum concentration in the film with aluminum ratio z in spray solution. Optical properties are studied by a spectrophotometer in the wavelength range 350–850 nm, at room temperature. Optical transmission and grain size are found to be maximal for z = 1.8 %. Moreover, band-gap energy is found to increase with aluminum ratio.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. T. Asikainen, M. Ritala, M. Leskala, Appl. Surf. Sci. 82, 122 (1994)

    Article  ADS  Google Scholar 

  2. B.I. Sysoev, V.D. Linnik, S.A. Titov, O.I. Kordenko, Phys. Stat. Sol. A 143, 71 (1994)

    Article  ADS  Google Scholar 

  3. G. Shang, K. Kunze, M.J. Hampden-Smith, E.N. Duesler, Chem. Vap. Depos 2, 242 (1996)

    Article  Google Scholar 

  4. N. Barreau, Sol. Energy 83, 363 (2009)

    Article  ADS  Google Scholar 

  5. B. Asenjo, A.M. Chaparro, M.T. Gutierrez, J. Herrero, J. Klaer, Sol. Energy Mater. Sol. C 87, 647 (2005)

    Article  Google Scholar 

  6. T.T. John, C.S. Kartha, K.P. Vijayakumar, T. Abe, Y. Kashiwaba, Vacuum 80, 870 (2006)

    Article  Google Scholar 

  7. T.T. John, M. Mathew, C.S. Kartha, K.P. Vijayakumar, T. Abe, Y. Kashiwaba, Sol. Energy Mater. Sol. C 89, 27 (2005)

    Article  Google Scholar 

  8. T. Sebastian, M. Gopinath, C.S. Kartha, K.P. Vijayakumar, T. Abe, Y. Kashiwaba, Sol. Energy 83, 1683 (2009)

    Article  ADS  Google Scholar 

  9. M. Zervos, P. Papageorgiou, A. Othonos, J. Cryst. Growth 312, 656 (2010)

    Article  ADS  Google Scholar 

  10. N. Revathi, P. Prathap, K.T.R. Reddy, Solid State Sci. 11, 1288 (2009)

    Article  ADS  Google Scholar 

  11. A.S. Cherian, M. Mathew, C.S. Kartha, K.P. Vijayakumar, Thin Solid Films 518, 1779–1783 (2010)

    Article  ADS  Google Scholar 

  12. N. Jebbari, B. Ouertani, M. Ramonda, C. Guasch, N. K. Turki, R. Bennaceur; European Materials Research Society E-MRS; 8–12 June 2009, Strasbourg, France

  13. N. Jebbari, N. Kamoun, R. Bennaceur, A. T. Saugnac, B. Jouffrey. 19th European photovoltaic solar energy conference and exhibition; 7–11 June 2004 Paris, France

  14. M. Dachraoui, S. Belgacem, R. Bennaceur, H. Latrous, J. Soc. Chim. Tunisie 2, 59 (1985)

    Google Scholar 

  15. N. Kamoun, R. Bennaceur, M. Amlouk, S. Belgacem, N. Mliki, J.M. Frigerio, M.L. Theye, Phys. Status Solidi A 169, 97 (1998)

    Article  ADS  Google Scholar 

  16. L. Soonckindt, J. Bonnet, L. Lassabatère, Thin Solid Films 78, 167–176 (1981)

    Article  ADS  Google Scholar 

  17. M. Amlouk, M.A.B. Said, N. Kamoun, S. Belgacem, N. Brunet, D. Barjon, Jap J. Appl. Phys. 38, 17–21 (1999)

    Article  ADS  Google Scholar 

  18. L. Bhira, H. Essaidi, S. Belgacem, G. Couturier, J. Salardenne, N. Barreaux, J.C. Brenède, Phys. Status Solidi A 181, 427 (2000)

    Article  ADS  Google Scholar 

  19. M.A.B. Said, S. Belgacem, M. Dachraoui, R. Bennaceur, H. Bouchriha, Rev. Phys. Appl. 21, 407 (1986)

    Article  Google Scholar 

  20. N. Kamoun, S. Belgacem, M. Amlouk, R. Bennaceur, K. Abdelmoula, A.B. Amara, J. Phys. III 4, 473 (1994)

    Google Scholar 

  21. L. Bhira, T.B. Nasrallah, J.C. Brenède, S. Belgacem, Mater. Chem. Phys. 72, 320 (2001)

    Google Scholar 

  22. N. Jebbari, N. Kamoun, C. Guasch, R. Bennaceur; 22nd European photovoltaic solar energy conference; 3–7 September 2007, Milan, Italy

  23. N. Jebbari, M. Castgné, N. Kamoun Turki, R. Bennaceur; European materials research society E-MRS; 8–12 June 2009, Strasbourg, France

  24. N. Kamoun, S. Belgacem, M. Amlouk, R. Bennaceur, J. Appl. Phys. 89, 4 (2001)

    Article  Google Scholar 

  25. http://en.wikipedia.org/wiki/NH4Cl. Accessed 2 April 2014

  26. N. Bouguila, H. Bouzouita, E. Lacaze, A. Belhadj Amara, H. Bouchriha, A. Dhouib, J. Phys. III 7, 1647 (1997)

    Google Scholar 

  27. P.S. Vincett, Thin Solid Films 100, 371 (1983)

    Article  ADS  Google Scholar 

  28. J. George, K.S. Joseph, B. Pradeep, T.I. Palson, Phys. Stat. Sol. l06, 123 (1988)

    Article  ADS  Google Scholar 

  29. A. Likforman, M. Guittard, A. Tomas, J. Flahaut, J. Sol. Stat. Chem. 34, 353 (1980)

    Article  ADS  Google Scholar 

Download references

Acknowledgments

The authors wish to thank the Comité Mixte de Cooperation Universitaire for financial support under the project number 07S/1304 as well as Egide France under the Project Hubert Curien Utique number 07S/1304. We also would like to thank Dr Mohamed Mondher Jebari for the helpful discussion.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. Jebbari.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jebbari, N., Saadallah, F., Guasch, C. et al. Structural, morphologic and optical characterization of In(2−x)Al x S3 . Appl. Phys. A 116, 2011–2017 (2014). https://doi.org/10.1007/s00339-014-8387-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-014-8387-2

Keywords

Navigation