Abstract
ZnO micro-hexagons with controllable morphologies were synthesized with the assist of benzenedicarboxylic acid (BDC) from zinc hydroxide nanostrands at 120 °C. With increasing the concentration of BDC, the structures evolved from hexagonal disks to hexagonal pyramids and eventually to coarse hexagonal pyramid flakes. The reason was that the growth along the c axis was preferentially suppressed at relatively low BDC concentration, while at higher concentration, the BDC could uniformly adsorbed on the whole surface. The photoluminescence properties of the obtained ZnO hexagons were also investigated at room and low temperature. The ZnO hexagonal disks with lowest defect showed the best optical performance.
Similar content being viewed by others
References
D.P. Norton, Y.W. Heo, M.P. Ivill, K. Ip, S.J. Pearton, M.F. Chisholm, T. Steiner, Materialstoday 7, 34 (2004)
B.Q. Sun, H. Sirringhaus, J. Am. Chem. Soc. 128, 6231 (2006)
A. Manekkathodi, M.Y. Lu, C.W. Wang, L.J. Chen, Adv. Mater. 22, 4059 (2010)
J.J. Cole, X.Y. Wang, R.J. Knuesel, H.O. Jacobs, Nano Lett. 8, 1478 (2008)
M.H. Huang, S. Mao, H. Feick, H.Q. Yan, Y.Y. Wu, H. Kind, E. Weber, R. Russo, P.D. Yang, Science 292, 1897 (2001)
J.H. Choy, E.S. Jang, J.H. Won, J.H. Chung, D.J. Jang, Y.W. Kim, Adv. Mater. 15, 1911 (2003)
R. Chen, B. Ling, X.W. Sun, H.D. Sun, Adv. Mater. 23, 2199 (2011)
M. Law, L.E. Greene, J.C. Johnson, R. Saykally, P.D. Yang, Nat. Mater. 4, 455 (2005)
Q.F. Zhang, C.S. Dandeneau, X.Y. Zhou, G.Z. Cao, Adv. Mater. 21, 4087 (2009)
Z.L. Wang, J.H. Song, Science 312, 242 (2006)
S. Xu, Y. Qin, C. Xu, Y.G. Wei, R.S. Yang, Z.L. Wang, Nat. Nanotech. 5, 366 (2010)
Y.F. Hu, J. Zhou, P.H. Yeh, Z. Li, T.Y. Wei, Z.L. Wang, Adv. Mater. 22, 3327 (2010)
A. Mclaren, T. Valdes-Solis, G.Q. Li, S.C. Tsang, J. Am. Chem. Soc. 131, 12540 (2009)
Y.C. Qiu, K.Y. Yan, H. Deng, S.H. Yang, Nano Lett. 12, 407 (2012)
H.M. Xiong, Adv. Mater. 25, 5329 (2013)
Z.L. Wang, J. Phys. Condens. Matter 16, 829 (2004)
A.B. Djurisic, X.Y. Chen, Y.H. Leung, A.M.C. Ng, J. Mater. Chem. 22, 6526 (2012)
C.X. Xu, X.W. Sun, Z.L. Dong, M.B. Yu, Appl. Phys. Lett. 85, 3878 (2004)
Z.W. Pan, J.D. Budai, Z.R. Dai, W.J. Liu, M.P. Paranthaman, S. Dai, Adv. Mater. 21, 890 (2009)
S. Xu, Z.L. Wang, Nano Res. 4, 1013 (2011)
B. Liu, H.C. Zeng, J. Am. Chem. Soc. 125, 4430 (2003)
B. Cheng and E. T. Samulski, Chem. Commun., 986 (2004)
C. Pacholski, A. Kornowski, H. Weller, Angew. Chem. Int. Ed. 41, 1188 (2002)
J. Joo, S.G. Kwon, J.H. Yu, T. Hyeon, Adv. Mater. 17, 1873 (2005)
M. Fu, J. Zhou, Q.F. Xiao, B. Li, R.L. Zong, W. Chen, J. Zhang, Adv. Mater. 18, 1001 (2006)
M. Distaso, M. Mackovic, E. Spiecker, W. Peukert, Chem. Eur. J. 18, 13265 (2012)
H.J. Zhou, S.S. Wong, ACS Nano 2, 944 (2008)
G.C. Yi, C. Wang, W. Park II, Semicond Sci. Technol. 20, 22 (2005)
J. Goniakowski, F. Finocchi, C. Noguera, Rep. Prog. Phys. 71, 016501 (2008)
K. Govender, D.S. Boyle, P.B. Kenway, P. O’Brien, J. Mater. Chem. 14, 2575 (2004)
S.H. Yu, H. Colfen, J. Mater. Chem. 14, 2124 (2004)
F.C. Meldrum, H. Colfen, Chem. Rev. 108, 4332 (2008)
L. Vayssieres, Adv. Mater. 15, 464 (2003)
F. Lu, W.P. Cai, Y.G. Zhang, Adv. Funct. Mater. 18, 1047 (2008)
J.H. Zhang, H.Y. Liu, Z.L. Wang, N.B. Ming, Z.R. Li, A.S. Biris, Adv. Funct. Mater. 17, 3897 (2007)
F. Li, Y. Ding, P.X. Gao, X.Q. Xin, Z.L. Wang, Angew. Chem. Int. Ed. 43, 5238 (2004)
F. Li, F.L. Gong, Y.H. Xiao, A.Q. Zhang, J.H. Zhao, S.M. Fang, D.Z. Jia, ACS Nano 7, 10482 (2013)
Z.R.R. Tian, J.A. Voigt, J. Liu, B. Mckenzie, M.J. Mcdermott, M.A. Rodriguez, H. Konishi, H.F. Xu, Nat. Mater. 2, 821 (2003)
E.S. Jang, J.H. Won, S.J. Hwang, J.H. Choy, Adv. Mater. 18, 3309 (2006)
L.P. Bauermann, A. del Campo, J. Bill, F. Aldinger, Chem. Mater. 18, 2016 (2006)
R. Zhang, L.L. Kerr, J. Solid State Chem. 180, 988 (2007)
J. Joo, B.Y. Chow, M. Prakash, E.S. Boyden, J.M. Jacobson, Nature 10, 596 (2011)
J. Manna, R.K. Rana, Chem. Eur. J. 18, 498 (2012)
Y. Zhou, W.B. Wu, G.D. Hu, H.T. Wu, S.G. Cui, Mater. Res. Bull. 43, 2113 (2008)
J. Zhang, L.D. Sun, J.L. Yin, H.L. Su, C.S. Liao, C.H. Yan, Chem. Mater. 14, 4172 (2002)
L. Guo, Y.L. Ji, H.B. Xu, J. Am. Chem. Soc. 124, 14864 (2002)
M. Umetsu, M. Mizuta, K. Tsumoto, S. Ohara, S. Takami, H. Watanabe, I. Kumagai, T. Adschiri, Adv. Mater. 17, 2571 (2005)
M. Yang, G.S. Pang, L.F. Jiang, S.H. Feng, Nanotechnology 17, 206 (2006)
X. S. Peng, J. Jin, N. Kobayashi, W. Schmitt and I. Ichinose, Chem. Commun., 1904 (2008)
Y.L. Ying, T. Song, H.W. Huang, X.S. Peng, Appl. Phys. A 110, 351 (2013)
S.S. Kaye, A. Dailly, O.M. Yaghi, J.R. Long, J. Am. Chem. Soc. 129, 14176 (2007)
M. Scepanovic, M. Grujic-Brojcin, K. Vojisavljevic, S. Bernik, T. Sreckovic, J. Raman Spectrosc. 41, 914 (2010)
H.K. Yadav, K. Sreenivas, V. Gupta, R.S. Katiyar, J. Raman Spectrosc. 40, 381 (2009)
X.H. Han, G.Z. Wang, J.S. Jie, W.C.H. Choy, Y. Luo, T.I. Yuk, J.G. Hou, J. Phys. Chem. B 109, 2733 (2005)
J.A. Marqusee, J. Ross, J. Chem. Phys. 79, 373 (1983)
Y.H. Tseng, H.Y. Lin, M.H. Liu, Y.F. Chen, C.Y. Mou, J. Phys. Chem. C 113, 18053 (2009)
W. Chen, D. Yu, H. Ruan, D.Z. Li, Y. Hu, Y.B. Chen, Y.H. He, X.Z. Fu, Y. Shao, J. Am. Ceram. Soc. 95, 2322 (2012)
K.X. Yao, R. Sinclair, H.C. Zeng, J. Phys. Chem. C 111, 2032 (2007)
B.K. Meyer, H. Alves, D.M. Hofmann, W. Kriegseis, D. Forster, F. Bertram, J. Christen, A. Hoffmann, M. Straßburg, M. Dworzak, U. Haboeck, A.V. Rodina, Phys. Status Solidi (B) 241, 231 (2004)
A.B. Djurisic, Y.H. Leung, Small 2, 944 (2006)
E.S. Jang, J.Y. Bae, J. Yoo, W. Park II, D.W. Kim, G.C. Yi, T. Yatsui, M. Ohtsu, Appl. Phys. Lett. 88, 023102 (2006)
J. Xia, X.H. Lu, C.S. Wang, Y.X. Tong, L.P. Chen, J. Electrochem. Soc. 158, D244 (2011)
C.H. Ahn, Y.Y. Kim, D.C. Kim, S.K. Mohanta, H.K. Cho, J. Appl. Phys. 105, 013502 (2009)
C.C. Lin, H.P. Chen, H.C. Liao, S.Y. Chen, Appl. Phys. Lett. 86, 183103 (2005)
S.J. Lee, S.K. Park, C.R. Park, J.Y. Lee, J. Park, Y.R. Do, J. Phys. Chem. C 111, 11793–11801 (2007)
C. Chen, H.P. He, Y.F. Lu, K.W. Wu, Z.Z. Ye, ACS Appl. Mater. Interfaces 5, 6354 (2013)
C.L. Yang, J.N. Wang, W.K. Ge, L. GUo, S.H. Yang, D.Z. Shen, J. Appl. Phys. 90, 4489 (2001)
S.J. Lee, S.K. Park, C.R. Park, J.Y. Lee, J. Park, Y.R. Do, J. Phys. Chem. C 111, 11793 (2007)
Y.H. Tong, Y.C. Liu, L. Dong, D.X. Zhao, J.Y. Zhang, Y.M. Lu, D.Z. Shen, X.W. Fan, J. Phys. Chem. B 110, 20263 (2006)
Acknowledgments
This work was supported by the National Nature Science Foundations of China (NSFC 21271154), and Doctoral Fund of Ministry of Education of China (20110101110028).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, J., Mao, Y., Cao, W. et al. Benzenedicarboxylic acid-assisted synthesis of ZnO micro-hexagons from zinc hydroxide nanostrands and their photoluminescence properties. Appl. Phys. A 118, 683–690 (2015). https://doi.org/10.1007/s00339-014-8780-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-014-8780-x