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Mg-based compounds for hydrogen and energy storage

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Abstract

Magnesium-based alloys attract significant interest as cost-efficient hydrogen storage materials allowing the combination of high gravimetric storage capacity of hydrogen with fast rates of hydrogen uptake and release and pronounced destabilization of the metal–hydrogen bonding in comparison with binary Mg–H systems. In this review, various groups of magnesium compounds are considered, including (1) RE–Mg–Ni hydrides (RE = La, Pr, Nd); (2) Mg alloys with p-elements (X = Si, Ge, Sn, and Al); and (3) magnesium alloys with d-elements (Ti, Fe, Co, Ni, Cu, Zn, Pd). The hydrogenation–disproportionation–desorption–recombination process in the Mg-based alloys (LaMg12, LaMg11Ni) and unusually high-pressure hydrides synthesized at pressures exceeding 100 MPa (MgNi2H3) and stabilized by Ni–H bonding are also discussed. The paper reviews interrelations between the properties of the Mg-based hydrides and p–T conditions of the metal–hydrogen interactions, chemical composition of the initial alloys, their crystal structures, and microstructural state.

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Acknowledgments

This work is a part of the activities within IEA Task 32 Hydrogen-based Energy Storage. We are grateful for the operating agent Dr. Michael Hirscher and all the experts from the Task 32 for the fruitful collaboration.

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Authors and Affiliations

  1. Université Paris Est, ICMPE (UMR 7182), CNRS, UPEC, 2 rue Henri Dunant, Thiais, F-94320, France

    J.-C. Crivello & M. Latroche

  2. Institute for Energy Technology and Norwegian University of Science and Technology, Kjeller and Trondheim, Norway

    R. V. Denys & V. A. Yartys

  3. Helmholtz-Zentrum Geesthacht, Zentrum für Material- und Küstenforschung GmbH, Geesthacht, Germany

    M. Dornheim

  4. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470, Mülheim an der Ruhr, Germany

    M. Felderhoff

  5. Nottingham University, Nottingham, UK

    D. M. Grant & G. S. Walker

  6. Hydrogen Research Institute, Université du Québec à Trois-Rivières, 3351 Boulevard des Forges, Trois-Rivières, QC, Canada

    J. Huot

  7. Department of Chemistry, Interdisciplinary Nanoscience Center, Aarhus University, Langelandsgade 140, 8000, Aarhus C, Denmark

    T. R. Jensen

  8. Debye Institute for Nanomaterials Science, Utrecht University, Utrecht, Netherlands

    P. de Jongh

  9. Queensland Micro- and Nanotechnology Centre, Griffith University, Brisbane, Australia

    C. J. Webb

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  1. J.-C. Crivello
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Crivello, JC., Denys, R.V., Dornheim, M. et al. Mg-based compounds for hydrogen and energy storage. Appl. Phys. A 122, 85 (2016). https://doi.org/10.1007/s00339-016-9601-1

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