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Application and removal mechanism of ZnO/bentonite desulfurizer in the dry desulfurization

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Abstract

Dry desulfurization technology is one of the important means of flue gas desulfurization and SO2 control. In this paper, a series of desulfurizers with zinc oxide as the active component and bentonite as the carrier were prepared by the sol–gel method. The performance of the desulfurizers under different preparation process conditions were studied, and they were characterized by ICP, XRD, FTIR, BET and SEM. The result showed that active component loading, molar ratio to citric acid, calcination time and calcination temperature were all important factors that affected the efficiency of the desulfurizers. The desulfurizer prepared by the sol–gel method had a loading amount close to the theory, and the active components were uniformly loaded on the carrier.

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Acknowledgements

This research was funded by Key Research and Development Program of Shaanxi [Grant Number 2019ZDLSF05-05-01]; Natural Science Basic Research Program of Shaanxi [Grant Number 2019JL-01]; Xi'an Science and Technology Plan Project [Grant Number 2019217714GXRC013CG014-GXYD13.4]; Open Fund of Shaanxi Key Laboratory of Geological Support for Coal Green Exploitation [Grant Number DZBZ2020-03]; and Xi’an University of Science and Technology, State Key Laboratory of Coal Resources in Western China [Grant Number SKLCRKF20-15].

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Authors and Affiliations

  1. School of Geology and Environment, Xi’an University of Science and Technology, Xi’an, 710054, China

    Zhang Lei

  2. Institute of Water Resources and Hydro-Electric Engineering, Xi’an University of Technology, Xi’an, 710048, China

    Jia Yang & Shu Hao

  3. School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Bejing, China

    Xie Weiwei, Yan Yao & Lu Xi

  4. China National Heavy Machinery Research Institute Co, Ltd, Xi’an, 710032, China

    Lei Zhang

  5. State Key Laboratory of Coal Resources in Western China, Xi’an University of Science and Technology, Xi’an, 710000, China

    Song Qiang

  6. Beijing Building Materials Testing Academy Co., Ltd, Beijing, 100041, China

    Song Shuangyan

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  1. Zhang Lei
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Contributions

ZL(F) and LZ involved in conceptualization; XW involved in methodology; YY contributed to Software; LX and SQ participated in validation; SS investigated the study; SH involved in data curation; JY participated in writing—original draft preparation; JY and SS involved in writing—review & editing.

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Correspondence to Zhang Lei.

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Lei, Z., Yang, J., Weiwei, X. et al. Application and removal mechanism of ZnO/bentonite desulfurizer in the dry desulfurization. Appl. Phys. A 128, 146 (2022). https://doi.org/10.1007/s00339-021-05221-1

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