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Synergistic nanomaterials: zinc sulfide-polyaniline for ciprofloxacin electrochemical sensing

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Abstract

Ciprofloxacin (CIP) is a fluoroquinolone antibiotic with a broad spectrum of activity, frequently employed in the treatment of diverse bacterial infections. Improper disposal practices of CIP can result in the accumulation of this substance within the natural environment. Hence, it has become imperative to establish expeditious and reliable techniques for the identification of CIP in order to effectively monitor its concentrations and uphold public health security. The electrochemical properties of zinc sulfide-polyaniline (ZnS-PANI) nanocomposite-modified electrodes were thoroughly examined in a systematic manner for the purpose of detecting CIP. This investigation was conducted using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) methodologies. The optimal experimental conditions, including scan rate and varying concentrations, were selected in order to attain the highest possible sensitivity and stability of the electrode. The nanocomposite exhibited improved electrochemical activity within a linear range spanning from 50  to 0.75 μM, and a limit of detection of 0.5 µM. The experiment involved the detection of CIP in an environment of interfering substances, namely enrofloxacin (ENR), levofloxacin (LEV), and ofloxacin (OFL), and found to be selective for CIP.

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The data presented in this study are available from the corresponding author upon reasonable request.

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Acknowledgements

The authors extend their appreciation to the Deputyship for Research & Innovation, Ministry of Education in Saudi Arabia for funding this research work through the project number RUP3-4.

Funding

Deputyship for Research & Innovation, Ministry of Education in Saudi Arabia, project number RUP3-4.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Jazan University, P.O. Box 2097, 45142, Jazan, Saudi Arabia

    Syed Kashif Ali, Waleed M. Alamier & Nazim Hasan

  2. Department of Metallurgical and Materials Engineering, Indian Institute of Technology Jodhpur, Jodhpur, Rajasthan, 342030, India

    Shahzad Ahmed & Arshiya Ansari

  3. Department of Chemical Engineering, College of Engineering, Jazan University, P.O. Box. 706, 45142, Jazan, Saudi Arabia

    Mohd Imran

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Contributions

SKA: Conceptualisation, investigation, writing —original draft, visualization reviewing, and editing. WMA: Conceptualisation, investigation, writing—original draft, visualization reviewing, and editing. NH: Conceptualisation, data curation, and investigation. SA: Supervision, conceptualization, visualization—reviewing, and editing. AA: Supervision, conceptualization, visualization—reviewing, and editing. MI: Data curation, investigation, review, and editing.

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Ali, S.K., Alamier, W.M., Hasan, N. et al. Synergistic nanomaterials: zinc sulfide-polyaniline for ciprofloxacin electrochemical sensing. Appl. Phys. A 129, 859 (2023). https://doi.org/10.1007/s00339-023-07124-9

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