Abstract
In the present work, third-order nonlinear optical parameters of lithium potassium borate (LiKB4O7) crystal, a potential NLO material, are determined along the three crystallographic axes using Z-scan technique. The high value of nonlinear refractive index (n 2) obtained along c-axis is −7.582 × 10−11 cm2/W, and the corresponding third-order nonlinear susceptibility (χ 3) is 4.858 × 10−9 esu. The measured nonlinear refractive indices reveal the self-defocusing effect of LiKB4O7 crystals.
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References
D.A. Keszler, Borates for optical frequency conversion. Curr. Opin. Solid State Mater. Sci 1, 204 (1996)
T. Sasaki, Y. Mori, M. Yoshimura, Y.K. Yap, T. Kamimura, Recent development of nonlinear optical borate crystals: key materials for generation of visible and UV light. Mater. Sci. Eng. R 30, 1 (2000)
C.T. Chen, L. Bai, Z.Z. Wang, R.K. Li, Development of new NLO crystals for UV and IR applications. J. Cryst. Growth 292, 169 (2006)
C. Chen, Z. Lin, Z. Wang, The development of new borate-based UV nonlinear optical crystals. Appl. Phys. B 80, 1 (2005)
R. Komatsu, T. Sugawara, K. Sassa, N. Sarukura, Z. Liu, S. Izumida, Y. Segawa, S. Uda, T. Fukuda, K. Yamanouchi, Growth and ultraviolet application of Li2B4O7 crystals: generation of the fourth and fifth harmonics of Nd:Y3Al5O12 lasers. Appl. Phys. Lett. 70, 3492 (1997)
I. Nikolov, D. Perlov, S. Livneh, E. Sanchez, P. Czechowicz, V. Kondilenko, D. Loiacono, Growth and morphology of large LiB3O5 single crystals. J. Cryst. Growth 331, 1 (2011)
E.F. Dolzhenkova, M.F. Dubovik, A.V. Tolmachev, R.P. Yavetskii, Macro- and microdefects in Czochralski-grown Li6GdB3O9 and Li6−xNaxGdB3O9 single crystals. Inorg. Mater. 40, 856 (2004)
Z. Lin, J. Lin, Z. Wang, C. Chen, M.H. Lee, Mechanism for linear and nonlinear optical effects in LiB3O5, CsB3O5, and CsLiB6O10 crystals. Phys. Rev. B 62, 1757 (2000)
Y. Mori, Y.K. Yap, T. Kamimura, M. Yoshimura, T. Sasaki, Recent development of nonlinear optical borate crystals for UV generation. Opt. Mater. 19, 1 (2002)
C.T. Chen, G.L. Wang, X.Y. Wang, Z.Y. Xu, Deep-UV nonlinear optical crystal KBe2BO3F2—discovery, growth, optical properties and applications. Appl. Phys. B 97, 9 (2009)
T. Sasaki, Y. Mori, M. Yoshimura, Progress in the growth of a CsLiB6O10 crystal and its application to ultraviolet light generation. Opt. Mater. 23, 343 (2003)
C.-K. Sun, Y.-L. Huang, J.-C. Liang, J.-C. Wang, K.-G. Gan, F.-J. Kao et al., Large near resonance third order nonlinearity in GaN. Opt. Quantum Electron. 32, 619 (2000)
C. Chen, Y. Wu, R. Li, The development of new NLO crystals in the borate series. J. Cryst. Growth 99, 790 (1990)
Y. Ono, M. Nakaya, T. Sugawara, N. Watanabe, H. Siraishi, R. Komatsu, T. Kajitani, Structural study of LiKB4O7 and LiRbB4O7: new nonlinear optical crystals. J. Cryst. Growth 229, 472 (2001)
Y. Ono, M. Nakaya, T. Kajitani, T. Sugawara, N. Watanabe, H. Shiraishi, R. Komatsu, Lithium potassium borate and lithium rubidium borate: new non-linear optical crystals. Acta Crystallogr. C 56, 1413 (2000)
V.T. Adamiv, Y.V. Burak, I.M. Teslyuk, Growth and properties of new nonlinear LiKB4O7 single crystals. J. Cryst. Growth 289, 157 (2006)
M. Sukumar, R. Ramesh Babu, K. Ramamurthi, G. Bhagavannarayana, Structural and optical properties of LiKB4O7 single crystals grown by Czochralski technique. Mater. Chem. Phys. 160, 369–374 (2015)
V.T. Adamiv, Optical, mechanical, and thermal properties of nonlinear LiKB4O7 crystals. Crystallogr. Rep. 53, 488 (2008)
V.T. Adamiv, O.T. Antonyak, Y.V. Burak, I.M. Teslyuk, X-ray and thermoluminescence of LiKB4O7 single crystals. J. Lumin. 128, 549 (2008)
V.T. Adamiv, Y.V. Burak, M.M. Romanyuk, G.M. Romanyuk, I.M. Teslyuk, New nonlinear optical LiKB4O7 single crystals: dispersion of refractive indices. Opt. Mater. 29, 1501 (2007)
K. Nouneh, I.V. Kityk, K. Michalska-Małecka, K. Ozga, V.T. Adamiv, Y.V. Burak, I.M. Teslyuk, Temperature dependences of the second-harmonic generation in LiKB4O7 single crystals. Laser Phys. 18, 965 (2008)
P. Smok, H. Seinert, I.V. Kityk, J. Berdowski, Band structure and optical properties of LiKB4O7 single crystal. Mater. Lett. 57, 4394 (2003)
V.T. Adamiv, Y. Burak, I. Teslyuk, Low-temperature change of lattice parameters in LiKB4O7 single crystals. Phys. Status Solidi B 246, 361 (2009)
R. DeSalvo, M. Sheik-Bahae, A.A. Said, D.J. Hagan, E.W. Van Stryland, Z-scan measurements of the anisotropy of nonlinear refraction and absorption in crystals. Opt. Lett. 18, 194 (1993)
R. DeSalvo, H. Vanherzeele, D.J. Hagan, M. Sheik-Bahae, G. Stegeman, E.W. Van Stryland, Self-focusing and self-defocusing by cascaded second-order effects in KTP. Opt. Lett. 17, 28 (1992)
W.S. Pelouch, P.E. Powers, C.L. Tang, High-repetition-rate femtosecond optical parametric oscillator. Opt. Lett. 17, 1070 (1992)
R. DeSalvo, A.A. Said, D.J. Hagan, E.W. Van Stryland, M. Sheik-Bahae, Infrared to ultraviolet measurements of two-photon absorption and n2 in wide bandgap solids. IEEE J. Quantum Electron. 32, 1324 (1996)
J. Wang, M. Sheik-Bahae, A.A. Said, D.J. Hagan, E.W. Van Stryland, Z-scan measurements of optical nonlinearities. J. Opt. Soc. Am. B 11, 1009 (1994)
V. Vasudevan, R. Ramesh Babu, K. Ramamurthi, Unidirectional growth of l-lysine l-lysinium dichloride nitrate (l-LLDN) single crystals by the SR method. Phys. B 406, 936 (2011)
S. Dinakaran, S. Verma, S.J. Das, G. Bhagavannarayana, S. Kar, K.S. Bartwal, Determination of crystalline perfection, optical indicatrix, birefringence and refractive-index homogeneity of ZTS crystals. Appl. Phys. B 103, 345 (2011)
P. Srinivasan, A.Y. Nooraldeen, T. Kanagasekaran, A.N. Dhinaa, P.K. Palanisamy, R. Gopalakrishnan, Z-scan determination of the third-order optical nonlinearity of L-asparaginium picrate (LASP) crystal. Laser Phys. 18, 790 (2008)
R.A. Ganeev, I.A. Kulagin, A.I. Ryasnyansky, R.I. Tugushev, T. Usmanov, Characterization of nonlinear optical parameters of KDP, LiNbO3 and BBO crystals. Opt. Commun. 229, 403 (2004)
S. Miller, F. Rotermund, G. Xu, F. Noack, V. Panyutin, V. Petrov, Polarization-dependent nonlinear refractive index of BiB3O6. Opt. Mater. 30, 1469 (2008)
M. Sheik-Bahae, M. Ebrahimzadeh, Measurements of nonlinear refraction in the second-order χ(2) materials KTiOPO4, KNbO3, β-BaB2O4, and LiB3O5. Opt. Commun. 142, 294 (1997)
J.N.B. Reddy, V.B. Naik, S. Elizabeth, H.L. Bhat, N. Venkatram, D.N. Rao, Multiphoton absorption in CsLiB6O10 with femtosecond infrared laser pulses. J. Appl. Phys. 104, 053108 (2008)
F.Q. Li, N. Zong, F.-F. Zhang, J. Yang, F. Yang, Q.-J. Peng et al., Investigation of third-order optical nonlinearity in KBe2BO3F2 crystal by Z-scan. Appl. Phys. B 108, 301 (2012)
Acknowledgments
The authors would like to thank Prof. D. Sastikumar, Department of Physics, National Institute of Technology, Tiruchirappalli, India, for providing facility for Z-scan measurement. One of the authors M. Sukumar is grateful to UGC-SAP, India, for the award of meritorious Research Fellowship Grant [No. F. 4-1/2006(BSR)/7-197/2008(BSR) dated 23.09.2010].
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Sukumar, M., Ramesh Babu, R. & Ramamurthi, K. Linear and third-order nonlinear optical properties of LiKB4O7 single crystals. Appl. Phys. B 121, 369–373 (2015). https://doi.org/10.1007/s00340-015-6239-1
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DOI: https://doi.org/10.1007/s00340-015-6239-1