Abstract
Experimental study of non-linear scattering (NLS) in nominally pure, Mg- and Zr-doped LiNbO3 crystals with a varying dopant concentration are reported in this paper. The study is undertaken by Z-scan technique with a cw-excitation at 514.5 nm. A modified open-aperture Z-scan experimental setup is used to evaluate the contributions of NLS in the observed transmission attenuation. Study of these open-aperture Z-scan traces shows that NLS has marked magnitude at moderate and high light intensities in undoped, strongly Zr-doped and Mg-doped LiNbO3, and a very significant magnitude in the moderately Zr-doped LiNbO3 crystals even at low intensities. NLS is related to the photoinduced light scattering (PILS), which is explained by holographic amplification of the seed scattering due to photorefractive effect.
Similar content being viewed by others
References
Q. Wang Song, C.P. Zhang, P.J. Talbot, Self-defocusing, self-focusing, and speckle in LiNbO3 and LiNbO3Fe crystals. Appl. Opt. 32, 7266–7271 (1993)
M. Sheik-Bahae, A.A. Said, T.-H. Wei, D.J. Hagan, E.W. Van Stryland, Sensitive measurement of optical nonlinearities using a single beam. IEEE J. Quantum Electron. 26, 760–769 (1990)
R. DeSalvo, A. Said, D. Hagan, E. Van Stryland, M. Sheik-Bahae, Infrared to ultraviolet measurements of two-photon absorption and n2 in wide bandgap solids. IEEE J. Quantum Electron. 32, 1324–1333 (1996)
B. Gu, J. Wang, J. Chen, Y.-X. Fan, J. Ding, H.-T. Wang, Z-scan theory for material with two- and three-photon absorption. Opt. Express 13, 9230–9234 (2005)
M. Rumi, J.W. Perry, Two-photon absorption: an overview of measurements and principles. Adv. Opt. Photonics 2, 451–518 (2010)
R. de Nalda, R. del Coso, J. Requejo-Isidro, J. Olivares, A. Suarez-Garcia, J. Solis, C.N. Afonso, Limits to the determination of the nonlinear refractive index by the Z-scan method. J. Opt. Soc. Am. B 19, 289–296 (2002)
S.M. Kostritskii, M. Aillerie, E. Kokanyan, Investigation of nonlinear refraction and absorption in Mg- and Zr-doped LiNbO3 with the aid of Z-scan techniques. Proc. SPIE 9065, 906508 (2013)
F.Z. Henari, K. Cazzini, F.E. Akkari, W.J. Blau, Beam waist changes in lithium niobate during Z-scan measurement. Appl. Phys. Lett. 78, 1373–1375 (1995)
MdM Parvez, Experimental studies on the nonlinear optical properties of LiNbO3 crystals. Am. J. Sci. Ind. Res. 6, 69–73 (2015)
L. Palfalvi, J. Hebling, G. Almasi, A. Peter, K. Polgar, K. Lengyel, R. Szipcs, Nonlinear refraction and absorption of Mg doped stoichiometric and congruent LiNbO3. J. Appl. Phys. 95, 902–908 (2004)
Y. Chen, S.W. Liu, D. Wang, T. Chen, M. Xiao, Measurement of laser-induced refractive index change of inverted ferroelectric domain LiNbO3. Appl. Opt. 46, 7693–7696 (2007)
S.M. Kostritskii, M. Aillerie, Z-scan study of nonlinear absorption in reduced LiNbO3 crystals. J. Appl. Phys. 111, 103504 (2012)
S.M. Kostritskii, M. Aillerie, Optical damage in reduced Z-cut LiNbO3 crystals caused by longitudinal photovoltaic and pyroelectric fields. J. Appl. Phys. 111, 013519 (2012)
Q.Q. Wang, J. Shi, B.F. Yang, H.L. Liu, G.G. Xiong, Q.H. Gong, Q.K. Xue, A Z-scan study of LiNbO3 thin film. Chin. Phys. Lett. 19, 677–679 (2002)
N.Y. Kamber, G. Zhang, S. Liu, S.M. Mikha, W. Haidong, Study of the self-defocusing in LiNbO3:Fe, Mg crystals. Opt. Commun. 184, 475–483 (2000)
J. Wen, ChY Gao, H.T. Yu, M. Zhao, J.J. Shang, X.L. Li, Investigation on third-order nonlinear optical properties of undoped LiNbO3 by modified Z-scan technique. Appl. Phys. B 123, 85 (2017)
L. Palfalvi, K. Lengyel, A. Peter, J.A. Fulop, T. Reiter, J. Hebling, Theoretical and experimental development of the Z-scan method and its application for the characterization of LiNbO3. Proc. SPIE 7501, 75010F (2009)
N. Venkatram, R.S.S. Kumar, D.N. Rao, Nonlinear absorption and scattering properties of cadmium sulphide nanocrystals with its application as a potential optical limiter. J. Appl. Phys. 100, 074309 (2006)
V. Joudrier, P. Bourdon, F. Hache, C. Flytzanis, Nonlinear light scattering in a two-component medium: optical limiting application. Appl. Phys. B 67, 627 (1998)
Y. Kong, S. Liu, Y. Zhao, H. Liu, S. Chen, J. Xu, Highly optical damage resistant crystal: Zirconium-oxide doped lithium niobate. Appl. Phys. Lett. 91, 081908 (2007)
V. Degiorgio, P. Minzioni, G. Nava, I. Cristiani, W. Yan, D. Grando, N. Argiolas, M. Bazzan, M.V. Ciampolillo, A.M. Zaltron, C. Sada, Photorefractivity of zirconium-doped lithium niobate. Proc. SPIE 8071, 80710R (2011)
S. González-Martínez, J. Castillo-Torres, J.A. Hernández, H.S. Murrieta, J.G. Murillo, R. Farias, Experimental evidence of a non-relationship between photorefractive inhibition and photoconductivity increase in LiNbO3:Mg. Opt. Commun. 282, 1212–1219 (2009)
E. Kokanyan, E.J. Dieguez, New perspectives of lithium niobate crystals. Optoelectr. Adv. Mater. 2, 205–214 (2000)
https://goochandhousego.com/wp-content/uploads/2013/12/PPLN_DS.pdf
https://goochandhousego.com/wp-content/uploads/2013/12/LNmatProperties.pdf
http://www.roditi.com/SingleCrystal/LiNbO3/Magnesium-Doped.html
J.-J. Liu, P.P. Banerjee, Q. Wang Song, Role of diffusive, photovoltaic, and thermal effects in beam fanning in LiNbO3. J. Opt. Soc. Am. B 11, 1688–1693 (1994)
M.R.R. Gesualdi, C. Jacinto, T. Catunda, M. Muramatsu, V. Pilla, Thermal lens spectrometry in pyroelectric lithium niobate crystals. Appl. Phys. B 93, 879–883 (2008)
F. Lüdtke, N. Waasem, K. Buse, B. Sturman, Light-induced charge-transport in undoped LiNbO3 crystals. Appl. Phys. B 105, 35–50 (2011)
S.M. Kostritskii, O.G. Sevostyanov, Influence of defects on light-induced changes in refractive index of lithium niobate. Appl. Phys. B 65, 527–533 (1997)
R. Ganeev, I. Kulagin, A. Ryasnyansky, R. Tugushev, T. Usmanov, Characterization of nonlinear optical parameters of KDP, LiNbO3 and BBO crystals. Opt. Commun. 229, 403–412 (2004)
H. Li, F. Zhou, X. Zhang, W. Ji, Picosecond Z-scan study of bound electronic Kerr effect in LiNbO3 crystal associated with two-photon absorption. Appl. Phys. B 64, 659–662 (1997)
R.K. Choubey, R. Trivedi, M. Das, P.K. Sen, P. Sen, S. Kar, K.S. Bartwal, R.A. Ganeev, Growth and study of nonlinear refraction and absorption in Mg doped LiNbO3 single crystals. J. Crys. Growth 311, 2597–2601 (2009)
H. Badorreck, S. Nolte, F. Freytag, P. Bäune, V. Dieckmann, M. Imlau, Scanning nonlinear absorption in lithium niobate over the time regime of small polaron formation. Opt. Mater. Express 5, 2729–2741 (2015)
H. Qiao, J. Xu, Q. Wu, X. Yu, Q. Sun, X. Zhang, G. Zhang, T.R. Volk, An increase of photorefractive sensitivity in In:LiNbO3 crystal. Opt. Mater. 23, 269–272 (2003)
G. Zhang, Q. Li, P. Ho, S. Liu, Z. Wu, R.R. Alfano, Dependence of specklon size on laser beam size via photo-induced light scattering in LiNbO3:Fe. Appl. Opt. 25, 2955–2958 (1986)
M. Goulkov, M. Imlau, Th Woike, Photorefractive parameters of lithium niobate crystals from photoinduced light scattering. Phys. Rev. B 77, 235110 (2008)
M.A. Ellabban, M. Fally, R.A. Rupp, T. Woike, M. Imlau, Holographic scattering and its applications, in Recent Research Developments in Applied Physics, vol. 4, ed. by S. Pandalai (Transworld Publishing, India, 2001), pp. 241–275
M. Imlau, Th. Woike, M. Fally, M. Ellaban, R. A. Rupp and M. Goulkov, Non-linear light scattering in polar oxides at the example of strontium-barium-niobate. in R. Wasser, U. Bottger, S. Tiedke (Editors) Proceedings of POLECER Conference, Chapter VII, 148 (2003)
O. Althoff, E. Kratzig, Strong light-induced refractive index changes in LiNbO3. Proc. SPIE 1273, 12–19 (1990)
I. Turek, N. Tarjányi, Opt. Express 15, 10782 (2007)
L. Wan, Y. Yuan, G. Assanto, Switching and self-pulsing with dynamic holographic gratings in photorefractive waveguides. Opt. Commun. 74, 361–364 (1990)
J. Sathian, E. Jaatinen, Reducing residual amplitude modulation in electro-optic phase modulators by erasing photorefractive scatter. Opt. Express 21, 12309–12317 (2013)
Acknowledgments
S.M. Kostritskii, O.G. Sevostyanov, and E. Kokonyan thank the RFBR for support under Grant no. 18-52-05012.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kostritskii, S., Aillerie, M., Kokanyan, E. et al. Non-linear light scattering in photorefractive LiNbO3 crystals studied by Z-scan technique. Appl. Phys. B 125, 160 (2019). https://doi.org/10.1007/s00340-019-7274-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00340-019-7274-0