Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 1/2009

01.01.2009 | Invited Review

Nanocomposite polymer hydrogels

verfasst von: Patrick Schexnailder, Gudrun Schmidt

Erschienen in: Colloid and Polymer Science | Ausgabe 1/2009

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The technological need for new and better soft materials as well as the drive for new knowledge and fundamental understanding has led to significant advances in the field of nanocomposite gels. A variety of complex gel structures with unique chemical, physical, and biological properties have been engineered or discovered at the nanoscale. The possibility to form self-assembled and supramolecular morphologies makes organic polymers and inorganic nanoparticles desirable building blocks for the design of water based gels. In this review, we highlight the most recent (2004–2008) accomplishments and trends in the field of nanocomposite polymer hydrogels with a focus on creative approaches to generating structures, properties, and function within mostly biotechnological applications. We examine the impact of published work and conclude with an outline on future directions and challenges that come with the design and engineering of new nanocomposite gels.
Nächster Artikel Synthesis and aggregation study of tin nanoparticles and colloids obtained by chemical liquid deposition

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Lovinger AJ (2005) Nano-, bio-, multi-, inter-,…: polymer research in an era of prefixes. J Macromol Sci, Part C 45(3):195–199CrossRef
2.
Weiss RG, Terech P (2006) Molecular gels: materials with self-assembled fibrillar networks. Springer, Berlin, p 978
3.
Peppas NA, Hilt JZ, Khademhosseini A, Langer R (2006) Hydrogels in biology and medicine: From molecular principles to bionanotechnology. Adv Mater 18(11):1345–1360CrossRef
4.
Nelson A, Cosgrove T (2004) Dynamic light scattering studies of poly(ethylene oxide) adsorbed on Llaponite: layer conformation and its effect on particle stability. Langmuir 20(24):10382–10388CrossRef
5.
Nelson A, Cosgrove T (2004) A small-angle neutron scattering study of adsorbed poly(ethylene oxide) on laponite. Langmuir 20(6):2298–2304CrossRef
6.
Pozzo D, Walker L (2004) Reversible shear gelation of polymer–clay dispersions. Colloids Surf, A Physicochem Eng Asp 240(1–3):187–198CrossRef
7.
Can V, Okay O (2005) Shake gels based on Laponite–PEO mixtures: effect of polymer molecular weight. Des Monomers Polym 8(5):453–462CrossRef
8.
Baghdadi H, Sardinha H, Bhatia S (2005) Rheology and gelation kinetics in Laponite dispersions containing poly(ethylene oxide). J Polym Sci, B, Polym Phys 43(2):233–240CrossRef
9.
Loizou E, Butler P, Porcar L, Kesselman E, Talmon Y, Dundigalla A, Schmidt G (2005) Large scale structures in nanocomposite hydrogels. Macromolecules 38(6):2047–2049CrossRef
10.
Li J, Jiang J, Li C, Lin M, Schwarz S, Rafailovich M, Sokojov J (2006) Effect of temperature on shear-induced anisotropic structure in polymer clay hydrogels. Macromol Rapid Commun 27(20):1787–1791CrossRef
11.
Baghdadi HA, Jensen EC, Easwar N, Bhatia SR (2008) Evidence for re-entrant behavior in Laponite–PEO systems. Rheologica Acta 47(2):121–127CrossRef
12.
Daga VK, Wagner NJ (2006) Linear viscoelastic master curves of neat and Laponite-filled poly(ethylene oxide)–water solutions. Rheologica Acta 45(6):813–824CrossRef
13.
Loizou E, Butler P, Porcar L, Schmidt G (2006) Dynamic responses in nanocomposite hydrogels. Macromolecules 39(4):1614–1619CrossRef
14.
Lin-Gibson S, Kim H, Schmidt G, Han CC, Hobbie EK (2004) Shear-induced structure in polymer–clay nanocomposite solutions. J Colloid Interface Sci 274(2):515–525CrossRef
15.
de Bruyn JR, Pignon F, Tsabet E, Magnin A (2008) Micron-scale origin of the shear-induced structure in Laponite–poly(ethylene oxide) dispersions. Rheologica Acta 47(1):63–73CrossRef
16.
Takahashi T, Yamada Y, Kataoka K, Nagasaki Y (2005) Preparation of a novel peg–clay hybrid as a DDS material: dispersion stability and sustained release profiles. J Control Release 107(3):408–416CrossRef
17.
Lagaly G, Ziesmer S (2006) Sol–gel transitions of sodium montmorillonite dispersions by cationic end-capped poly(ethylene oxides) (surface modification of bentonites, iv). Colloid Polym Sci 284(9):947–956CrossRef
18.
Pozzo DC, Walker LM (2007) Shear orientation of nanoparticle arrays templated in a thermoreversible block copolymer micellar crystal. Macromolecules 40(16):5801–5811CrossRef
19.
Pozzo DC, Walker LM (2008) Macroscopic alignment of nanoparticle arrays in soft crystals of cubic and cylindrical polymer micelles. Eur Phys J, E Soft Matter 26(1/2):183–189
20.
Nelson A, Cosgrove T (2005) Small-angle neutron scattering study of adsorbed Pluronic tri-block copolymers on Laponite. Langmuir 21(20):9176–9182CrossRef
21.
Gorelikov I, Field LM, Kumacheva E (2004) Hybrid microgels photoresponsive in the near-infrared spectral range. J Am Chem Soc 126(49):15938–15939CrossRef
22.
Nayak S, Lyon LA (2004) Photoinduced phase transitions in poly(n-isopropylacrylamide) microgels. Chem Mater 16(13):2623–2627CrossRef
23.
Zhao X, Ding X, Deng Z, Zheng Z, Peng Y, Long X (2005) Thermoswitchable electronic properties of a gold nanoparticle/hydrogel composite. Macromol Rapid Commun 26(22):1784–1787CrossRef
24.
Haraguchi K, Takehisa T, Ebato M (2006) Control of cell cultivation and cell sheet detachment on the surface of polymer/clay nanocomposite hydrogels. Biomacromolecules 7(11):3267–3275CrossRef
25.
Cho EC, Kim JW, Fernandez-Nieves A, Weitz DA (2008) Highly responsive hydrogel scaffolds formed by three-dimensional organization of microgel nanoparticles. Nano Lett 8(1):168–172CrossRef
26.
Hou Y, Matthews AR, Smitherman AM, Bulick AS, Hahn MS, Hou H, Han A, Grunlan MA (2008) Thermoresponsive nanocomposite hydrogels with cell-releasing behavior. Biomaterials 29(22):3175–3184CrossRef
27.
Satarkar NS, Hilt ZJ (2008) Hydrogel nanocomposites as remote-controlled biomaterials. Acta Biomaterialia 4(1):11–16CrossRef
28.
Zhu M, Liu Y, Sun B, Zhang W, Liu X, Yu H, Zhang Y, Kuckling D, Adler HJP (2006) A novel highly resilient nanocomposite hydrogel with low hysteresis and ultrahigh elongation. Macromol Rapid Commun 27(13):1023–1028CrossRef
29.
Haraguchi K, Li HJ, Matsuda K, Takehisa T, Elliott E (2005) Mechanism of forming organic/inorganic network structures during in-situ free-radical polymerization in PNIPA-clay nanocomposite hydrogels. Macromolecules 38(8):3482–3490CrossRef
30.
Haraguchi K, Li HJ (2006) Mechanical properties and structure of polymer–clay nanocomposite gels with high clay content. Macromolecules 39(5):1898–1905CrossRef
31.
Haraguchi K, Li HJ (2005) Control of the coil-to-globule transition and ultrahigh mechanical properties of PNIPA in nanocomposite hydrogels. Angewandte Chemie 44(40):6500–6504CrossRef
32.
Nie J, Du B, Oppermann W (2006) Dynamic fluctuations and spatial inhomogeneities in poly(n-isopropylacrylamide)/clay nanocomposite hydrogels studied by dynamic light scattering. J Phys Chem, Part B 110(23):11167–11175CrossRef
33.
Nie J, Du B, Oppermann W (2005) Swelling, elasticity, and spatial inhomogeneity of poly(n-isopropylacrylamide)/clay nanocomposite hydrogels. Macromolecules 38(13):5729–5736CrossRef
34.
Okay O, Oppermann W (2007) Polyacrylamide–clay nanocomposite hydrogels: rheological and light scattering characterization. Macromolecules 40(9):3378–3387CrossRef
35.
Mu J, Zheng S (2007) Poly(n-isopropylacrylamide) nanocrosslinked by polyhedral oligomeric silsesquioxane: temperature-responsive behavior of hydrogels. J Colloid Interface Sci 307(2):377–385CrossRef
36.
Zhang J, Wang A (2007) Study on superabsorbent composites. IX: synthesis, characterization and swelling behaviors of polyacrylamide/clay composites based on various clays. React Funct Polym 67(8):737–745CrossRef
37.
Ziesmer S, Stock N (2008) Synthesis of bifunctional core–shell particles with a porous zeolite core and a responsive polymeric shell. Colloid Polym Sci 286(6):831–836CrossRef
38.
Kokabi M, Sirousazar M, Hassan ZM (2007) PVA–clay nanocomposite hydrogels for wound dressing. Eur Polym J 43(3):773–781CrossRef
39.
Liu J, Hoffmann H (2004) Hydrogels in aqueous phases of polyvinylalcohol (PVA), surfactants and clay minerals. Colloid Polym Sci 283(1):24–32CrossRef
40.
Paranhos CM, Soares BG, Oliveira RN, Pessan LA (2007) Poly(vinyl alcohol)/clay-based nanocomposite hydrogels: Swelling behavior and characterization. Macromol Mater Eng 292(5):620–626CrossRef
41.
Paranhos CM, Soares BG, Machado JC, Windmöller D, Pessan LA (2007) Microstructure and free volume evaluation of poly(vinyl alcohol) nanocomposite hydrogels. Eur Polym J 43:4882–4890CrossRef
42.
Matos MA, White LR, Tilton RD (2006) Electroosmotically enhanced mass transfer through polyacrylamide gels. J Colloid Interface Sci 300(1):429–436CrossRef
43.
Hill RJ (2007) Electric-field-enhanced transport in polyacrylamide hydrogel nanocomposites. J Colloid Interface Sci 316(2):635–644CrossRef
44.
Wang C, Flynn NT, Langer R (2004) Controlled structure and properties of thermoresponsive nanoparticle–hydrogel composites. Adv Mater 16(13):1074–1079CrossRef
45.
Tokarev I, Tokareva I, Minko S (2008) Gold-nanoparticle-enhanced plasmonic effects in a responsive polymer gel. Adv Mater 20(14):2730–2734CrossRef
46.
Mohan YM, Premkumar T, Lee K, Geckeler KE (2006) Fabrication of silver nanoparticles in hydrogel networks. Macromol Rapid Commun 27(16):1346–1354CrossRef
47.
Mohan YM, Lee K, Premkumar T, Geckeler KE (2007) Hydrogel networks as nanoreactors: a novel approach to silver nanoparticles for antibacterial applications. Polymer 48(1):158–164CrossRef
48.
Xiang Y, Chen D (2007) Preparation of a novel pH-responsive silver nanoparticle/poly(HEMA–PEGMA–MAA) composite hydrogel. Eur Polym J 43(10):4178–4187CrossRef
49.
Saravanan P, Padmanabha Raju M, Alam S (2007) A study on synthesis and properties of Ag nanoparticles immobilized polyacrylamide hydrogel composites. Mater Chem Phys 103(2–3):278–282CrossRef
50.
Murthy PSK, Murali Mohan Y, Varaprasad K, Sreedhar B, Mohana Raju K (2008) First successful design of semi-IPN hydrogel-silver nanocomposites: a facile approach for antibacterial application. J Colloid Interface Sci 318(2):217–224CrossRef
51.
Basit H, Pal A, Sen S, Bhattacharya S (2008) Two-component hydrogels comprising fatty acids and amines: structure, properties, and application as a template for the synthesis of metal nanoparticles. Chemistry—A European Journal 14(21):6534–6545CrossRef
52.
Lu Y, Spyra P, Mei Y, Ballauff M, Pich A (2007) Composite hydrogels: robust carriers for catalytic nanoparticles. Macromolecular Chemistry and Physics 208(3):254–261CrossRef
53.
Sahiner N (2006) In situ metal particle preparation in cross-linked poly(2-acrylamido-2-methyl-1-propansulfonic acid) hydrogel networks. Colloid Polym Sci 285(3):283–292CrossRef
54.
Cohen Stuart MA (2008) Supramolecular perspectives in colloid science. Colloid Polym Sci 286(8):855–864CrossRef
55.
Schmidt AM (2007) Thermoresponsive magnetic colloids. Colloid Polym Sci 285(9):953–966CrossRef
56.
Heim E, Harling S, Ludwig F, Menzel H, Schilling M (2008) Fluxgate magnetorelaxometry for characterization of hydrogel polymerization kinetics and physical entrapment capacity. J Phys Condens Matter 20(20):204106CrossRef
57.
Liu T-Y, Hu S-H, Liu K-H, Liu D-M, Chen S-Y (2008) Study on controlled drug permeation of magnetic-sensitive ferrogels: effect of fe3o4 and PVA. J Control Release 126(3):228–236CrossRef
58.
Sunderland CJ, Steiert M, Talmadge JE, Derfus AM, Barry SE (2006) Targeted nanoparticles for detecting and treating cancer. Drug Dev Res 67(1):70–93CrossRef
59.
Ramanujan RV, Lao LL (2006) The mechanical behavior of smart magnet–hydrogel composites. Smart Mater Struc 15(4):952–956CrossRef
60.
Mitra RN, Das PK (2008) In situ preparation of gold nanoparticles of varying shape in molecular hydrogel of peptide amphiphiles. J Phys Chem, Part C 112(22):8159–8166CrossRef
61.
Cooper CL, Dubin PL, Kayitmazer AB, Turksen S (2005) Polyelectrolyte–protein complexes. Curr Opin Colloid interface Sci 10(1–2):52–78CrossRef
62.
Shchipunov YA, Karpenko TY, Krekoten AV, Postnova IV (2005) Gelling of otherwise nongelable polysaccharides. J Colloid Interface Sci 287(2):373–378CrossRef
63.
Wang G, Zhang L (2007) Manipulating formation and drug-release behavior of new sol–gel silica matrix by hydroxypropyl guar gum. J Phys Chem, Part B 111(36):10665–10670CrossRef
64.
Ma J, Xu Y, Zhang Q, Zha L, Liang B (2007) Preparation and characterization of ph-and temperature-responsive semi-IPN hydrogels of carboxymethyl chitosan with poly(n-isopropyl acrylamide) crosslinked by clay. Colloid Polym Sci 285(4):479–484CrossRef
65.
Ma J, Xu Y, Fan B, Liang B (2007) Preparation and characterization of sodium carboxymethylcellulose/poly(n-isopropylacrylamide)/clay semi-IPN nanocomposite hydrogels. Eur Polym J 43(6):2221–2228CrossRef
66.
Pich AZ, Adler HJP (2007) Composite aqueous microgels: an overview of recent advances in synthesis, characterization and application. Polym Int 56(3):291–307CrossRef
67.
Dimitrov I, Trzebicka B, Müller AHE, Dworak A, Tsvetanov CB (2007) Thermosensitive water-soluble copolymers with doubly responsive reversibly interacting entities. Prog Polym Sci 32(11):1275–1343CrossRef
68.
Das M, Zhang H, Kumacheva E (2006) Microgels: old materials with new applications. Annu Rev Mater Res 36:117–142CrossRef
69.
Nayak S, Lyon LA (2005) Soft nanotechnology with soft nanoparticles. Angew Chem Int Ed Engl 44:7686–7708CrossRef
70.
Soddemann M, Richtering W (2004) Hydrogels filled with thermosensitive microgel particles. Prog Colloid Polym Sci 129:88–94
71.
Musch J, Schneider S, Lindner P, Richtering W (2008) Unperturbed volume transition of thermosensitive poly-(n-isopropylacrylamide) microgel particles embedded in a hydrogel matrix. J Phys Chem, Part B 112(20):6309–6314CrossRef
72.
Webb AR, Kumar VA, Ameer GA (2007) Biodegradable poly (diol citrate) nanocomposite elastomers for soft tissue engineering. J Mater Chem 17(9):900–906CrossRef
73.
Zheng JP, Wang CZ, Wang XX, Wang HY, Zhuang H, Yao KD (2007) Preparation of biomimetic three-dimensional gelatin/montmorillonite–chitosan scaffold for tissue engineering. React Funct Polym 67(9):780–788CrossRef
74.
Leeuwenburgh SCG, Jansen JA, Mikos AG (2007) Functionalization of oligo (poly(ethylene glycol) fumarate) hydrogels with finely dispersed calcium phosphate nanocrystals for bone-substituting purposes. J Biomater Sci, Polym Ed 18(12):1547–1564
75.
Yu Y, Xu Y, Ning H, Zhang S (2008) Swelling behaviors of thermoresponsive hydrogels cross-linked with acryloyloxyethylaminopolysuccinimide. Colloid Polym Sci 286:1165–1171CrossRef
76.
Lee WF, Chen YC (2004) Effect of bentonite on the physical properties and drug-release behavior of poly (AA-CO-PEGMEA)/bentonite nanocomposite hydrogels for mucoadhesive. J Appl Polym Sci 91(5):2934–2941CrossRef
77.
Lynch I, de Gregorio P, Dawson KA (2005) Simultaneous release of hydrophobic and cationic solutes from thin-film “plum-pudding” gels: A multifunctional platform for surface drug delivery. J Phys Chem, Part B 109(13):6257–6261CrossRef
78.
Salvati A, Soderman O, Lynch I (2007) Plum-pudding gels as a platform for drug delivery: Understanding the effects of the different components on the diffusion behavior of solutes. J Phys Chem, Part B, 111(25):7367–7376CrossRef
Metadaten
Titel
Nanocomposite polymer hydrogels
verfasst von
Patrick Schexnailder
Gudrun Schmidt
Publikationsdatum
01.01.2009
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 1/2009
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-008-1949-0

Weitere Artikel der Ausgabe 1/2009

Colloid and Polymer Science 1/2009 Zur Ausgabe

Original Contribution

Synthesis and aggregation study of tin nanoparticles and colloids obtained by chemical liquid deposition

Original Contribution

Urea-induced demicellization of Pluronic L64 in water

Short Communication

Anti-Hofmeister series properties found for a polymer having a π electron system and acidic protons

Short Communication

Synthesis of polyaspartate macromonomer having a vinyl end group and application to dispersion copolymerization of styrene

Original Contribution

Preparation of raspberry-like polystyrene/carbon black composite microsphere via π–π interactions

Short Communication

Reactivity ratio of novel acrylic copolymer by NMR spectroscopy

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise