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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 3/2015

01.03.2015 | Original Contribution

A multistimuli-responsive supramolecular vesicle constructed by cyclodextrins and tyrosine

verfasst von: Mingfang Ma, Shengguang Xu, Pengyao Xing, Shangyang Li, Xiaoxiao Chu, Aiyou Hao

Erschienen in: Colloid and Polymer Science | Ausgabe 3/2015

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Abstract

Stimuli-responsive vesicle is a significant self-assembly. The supramolecular amphiphile strategy provides a simple way to construct the vesicles. Here, we report a β-cyclodextrin/tyrosine supramolecular vesicle based on host-guest recognition. Tyrosine, which is a nontoxic amino acid, is used as the vesicles building blocks. The β-cyclodextrin/tyrosine vesicles were identified by transmission electron microscopy (TEM), scanning electron microscopy (SEM), and dynamic light scattering (DLS). X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible (UV-vis) spectrum, hydrogen-1 nuclear magnetic resonance (1H NMR), and two-dimensional nuclear magnetic resonance spectroscopy rotating frame nuclear Overhauser effect spectroscopy (2D NMR ROESY) were further employed to elucidate the vesicle formation mechanism. Furthermore, different host molecules, including α-cyclodextrin and γ-cyclodextrin, can all form vesicles with tyrosine. Finally, the vesicles can respond to multiple external stimuli. Competitive guest molecules and copper ions can all disrupt the vesicles’ architectures.
Vorheriger Artikel Langmuir and Langmuir-Blodgett films of Cl-PPV mixed with stearic acid: implication of the morphology on the surface and spectroscopy properties
Nächster Artikel Effects of nanometer-size Laponite disks on thermal conductivity and specific heat of water and ice, and the gelation time

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Metadaten
Titel
A multistimuli-responsive supramolecular vesicle constructed by cyclodextrins and tyrosine
verfasst von
Mingfang Ma
Shengguang Xu
Pengyao Xing
Shangyang Li
Xiaoxiao Chu
Aiyou Hao
Publikationsdatum
01.03.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 3/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3424-4

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