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Colloid and Polymer Science

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01.07.2016 | Original Contribution

Crystallization kinetics of polyamide 11 in the presence of sepiolite and montmorillonite nanofillers

verfasst von: Katalee Jariyavidyanont, Walter Focke, René Androsch

Erschienen in: Colloid and Polymer Science | Ausgabe 7/2016

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Abstract

The crystallization kinetics of polyamide 11 (PA 11) in the presence of sepiolite and organo-modified montmorillonite nanofillers has been studied in a wide range of temperatures and cooling rates by conventional differential scanning calorimetry (DSC) and fast scanning chip calorimetry (FSC). The presence of the nanofillers has a negligible effect on the crystallization temperature of PA 11 at low cooling rates. However, at rapid cooling conditions a distinct nucleating effect of the nanofillers is detected. The critical cooling rate to suppress crystallization increases from 600 K s⁻¹ to about 1000 and 3000 K s⁻¹ in nanocomposites containing sepiolite and montmorillonite, respectively. Regardless of the cooling rate applied for solidification of the melt, in the nanocomposites the crystallinity of PA 11 is 5–10 % higher than in neat PA 11, with the highest values obtained for the montmorillonite-containing system. The nucleating effect of the nanofillers onto the crystallization of the PA 11 is confirmed by analysis of the half-times of isothermal crystallization and by analysis of the spherulitic superstructure. All measurements proved a saturation of the nucleation efficiency at a loading of the nanofiller of 2.5 m%.

Vorheriger Artikel Electrophoresis and electric conduction in a suspension of charged soft particles

Nächster Artikel Effects of triphenyl phosphate on styrene suspension polymerization process and flame retardance properties of polystyrene/triphenyl phosphate nanocomposite

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Brazel CS, Rosen SL (2012) Fundamental principles of polymeric materials. Wiley

Mollova A, Androsch R, Mileva D, Schick C, Benhamida A (2013) Effect of supercooling on crystallization of polyamide 11. Macromolecules 46:828–835CrossRef

Kargin VA, Sogolova TI, Rapoport N, Kurbanova II (1967) Effect of artificial nucleating agents on polymers structure and properties. J Polym Sci Polym Symp 16:1609–1617CrossRef

Paul DR, Robeson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49:3187–3204CrossRef

Fornes TD, Paul DR (2003) Modeling properties of nylon 6/clay nanocomposites using composite theories. Polymer 44:4993–5013CrossRef

Mathias LJ, Powell DG, Autran JP, Porter RS (1990) ¹⁵N NMR characterization of multiple crystal forms and phase transitions in polyundecanamide (nylon 11). Macromolecules 23:963–967CrossRef

Nair SS, Ramesh C, Tashiro K (2006) Polymorphism in nylon 11: characterization using HTWAXS and HTFTIR. Macromol Symp 242:216–226CrossRef

Newman BA, Sham TP, Pae KD (1977) A high-pressure X-ray study of nylon 11. J Appl Phys 48:4092–4098CrossRef

10.

Schmidt GF, Stuart HA (1958) Gitterstrukturen mit räumlichen Wasserstoffbrückensystemen und Gitterumwandlungen bei Polyamiden. Zeitschr Naturforschung (A) 13:222–225

11.

Gogolewski S (1979) Effect of annealing on thermal properties and crystalline structure of polyamides. nylon 11 (polyundecaneamide). Colloid Polym Sci 257:811–819CrossRef

12.

Zhang Q, Mo Z, Zhang H, Liu S, Cheng SZD (2001) Crystal transitions of nylon 11 under drawing and annealing. Polymer 42:5543–5547CrossRef

13.

Brill R (1956) Beziehungen zwischen Wasserstoffbindung und einigen Eigenschaften von Polyamiden. Makromol Chem 18:294–309CrossRef

14.

Zhang Q, Mo Z, Liu S, Zhang H (2000) Influence of annealing on structure of nylon 11. Macromolecules 33:5999–6005CrossRef

15.

Wunderlich B (1995) The ATHAS database on heat capacities of polymers. See on WWW URL: http://www.springermaterials.com/docs/athas.html. Pure Appl Chem 67(6):1019–1026CrossRef

16.

Inoue M (1963) Studies on crystallization of high polymers by differential thermal analysis. J Polym Sci A 1:2697–2709

17.

Magill JH (1969) Formation of spherulites in polyamides. IV. Even-odd polyamides and poly(ω-aminocarboxylic acids). J Polym Sci A 7:123–142CrossRef

18.

Androsch R, Schick C (2015) Crystal nucleation of polymers at high supercooling of the melt. Adv Polym Sci. doi:10.1007/12_2015_325

19.

Xu W, Ge M, He P (2002) Nonisothermal crystallization kinetics of polypropylene/montmorillonite nanocomposites. J Polym Sci Polym Phys 40:408–414CrossRef

20.

Maiti P, Nam PH, Okamoto M (2002) Influence of crystallization on intercalation, morphology, and mechanical properties of polypropylene/clay nanocomposites. Macromolecules 35:2042–2049CrossRef

21.

Yuan Q, Awate S, Misra RDK (2006) Nonisothermal crystallization behavior of polypropylene-clay nanocomposites. Eur Polym J 42:1994–2003CrossRef

22.

Xu W, Ge M, He P (2001) Nonisothermal crystallization kinetics of polyoxymethylene/montmorillonite nanocomposite. J Appl Polym Sci 82:2281–2289CrossRef

23.

Wang Y, Gao J, Ma Y, Agarwal US (2006) Study on mechanical properties, thermal stability and crystallization behavior of PET/MMT nanocomposites. Compos Part B 37:399–407CrossRef

24.

Wu D, Zhou C, Fan X, Mao D, Bian Z (2006) Nonisothermal crystallization kinetics of poly(butylene terephthalate)/montmorillonite nanocomposites. J Appl Polym Sci 99:3257–3265CrossRef

25.

Mollova A, Kolesov I, Androsch R, Labuschagne J, Focke W, Funari SS (2013) Crystallization of nanocomposites of an isotactic random butene-1/ethylene copolymer and layered double hydroxide. Polym Bull 70:3115–3128CrossRef

26.

Liu X, Wu Q, Berglund LA (2002) Polymorphism in polyamide 66/clay nanocomposites. Polymer 43:4967–4972CrossRef

27.

Wu Z, Zhou C, Zhu N (2002) The nucleating effect of montmorillonite on crystallization of nylon 1212/montmorillonite nanocomposites. Polym Test 21:479–483CrossRef

28.

Wu Q, Liu X, Berglund A (2001) An unusual crystallization behavior in polyamide 6/montmorillonite nanocomposites. Macromol Rapid Commun 22:1438–1440CrossRef

29.

Liu X, Wu Q, Berglund LA (2002) Investigation on unusual crystallization behavior in polyamide 6/montmorillonite nanocomposites. Macromol Mat Eng 287:515–522CrossRef

30.

Liu X, Wu Q (2002) Non-isothermal crystallization behaviors of polyamide 6/clay nanocomposites. Eur Polym J 38:1383–1389CrossRef

31.

Lincoln DM, Vaia RA (2004) Isothermal crystallization of nylon-6/montmorillonite nanocomposites. Macromolecules 37:4554–4561CrossRef

32.

Lincoln DM, Vaia RA, Wang ZG, Hsiao BS, Krishnamoorti R (2001) Temperature dependence of polymer crystalline morphology in nylon 6/montmorillonite nanocomposites. Polymer 42:9975–9985CrossRef

33.

Tjong SC, Bao SP (2004) Preparation and nonisothermal crystallization behavior of polyamide 6/montmorillonite nanocomposites. J Polym Sci Polym Phys 42:2878–2891CrossRef

34.

Liu L, Qi Z, Zhu X (1999) Studies on nylon 6/clay nanocomposites by melt-intercalation process. J Appl Polym Sci 71:1133–1138CrossRef

35.

Fornes TD, Paul DR (2003) Crystallization behavior of nylon 6 nanocomposites. Polymer 44:3945–3961CrossRef

36.

Mileva D, Monami A, Cavallo D, Alfonso GC, Portale G, Androsch R (2013) Crystallization of a polyamide 6/montmorillonite nanocomposite at rapid cooling. Macromol Mat Eng 298:938–943CrossRef

37.

Ishisue T, Okamoto M, Tashiro K (2010) Real-time investigation of crystallization in nylon 6-clay nano-composite probed by infrared spectroscopy. Polymer 51:5585–5591CrossRef

38.

Katoh Y, Okamoto M (2009) Crystallization controlled by layered silicates in nylon 6-clay nano-composites. Polymer 50:4718–4726CrossRef

39.

Mathias LJ, Davis RD, Jarrett WL (1999) Observation of α and γ crystal forms and amorphous regions on nylon 6-clay nanocomposites using solid-state ¹⁵N nuclear magnetic resonance. Macromolecules 32:7958–7960CrossRef

40.

Wurm A, Ismail M, Kretschmar B, Pospiech D, Schick C (2010) Retarded crystallization in polyamide/layered silicates nanocomposites caused by an immobilized interphase. Macromolecules 43:1480–1487CrossRef

41.

Homminga DS, Goderis B, Mathot VBF, Groeninckx G (2006) Crystallization behavior of polymer/montmorillonite nanocomposites. Part III. Polyamide-6/montmorillonite nanocomposites, influence of matrix molecular weight, and of montmorillonite type and concentration. Polymer 47:1630–1639CrossRef

42.

Zhang Q, Yu M, Fu Q (2004) Crystal morphology and crystallization kinetics of polyamide-11/clay nanocomposites. Polym Int 53:1941–1949CrossRef

43.

Fornes TD, Paul DR (2004) Structure and properties of nanocomposites based on nylon 11 and nylon 12 compared with those based on nylon 6. Macromolecules 37:7698–7709CrossRef

44.

Liu T, Lim KP, Tjiu WC, Pramoda KP, Chen ZK (2003) Preparation and characterization of nylon 11/organoclay nanocomposites. Polymer 44:3529–3535CrossRef

45.

Halim KAA, Farrell JB, Kennedy JE (2013) Preparation and characterization of polyamide 11/montmorillonite (MMT) nanocomposites for use in angioplasty balloon application. Mat Chem Phys 143:336–348CrossRef

46.

Kolesov I, Androsch R, Mileva D, Lebek W, Benhamida A, Kaci M, Focke W (2013) Crystallization of polyamide 11/organo-modified montmorillonite nanocomposite at rapid cooling. Colloid Polym Sci 291:2541–2549CrossRef

47.

Xie S, Zhang S, Wang F, Yang M, Séguéla R, Levebre JM (2007) Preparation, structure and thermomechanical properties of nylon-6 nanocomposites with lamella-type and fiber-type sepiolite. Compos Sci Technol 67:2334–2341CrossRef

48.

Bilotti E, Zhang R, Deng H, Quero F, Fischer HR, Peijs T (2009) Sepiolite needle-like clay for PA6 nanocomposites: an alternative to layered silicates? Compos Sci Technol 69:2587–2595CrossRef

49.

Fukushima K, Tabuani D, Camino G (2009) Nanocomposites of PLA and PCL based on montmorillonite and sepiolite. Mater Sci Eng C29:1433–1441CrossRef

50.

Cloisite® 30B, Product bulletin, Southern Clay Products, Inc.

51.

Wunderlich B (1976) Macromolecular physics, vol. 2, crystal nucleation, growth, annealing. Academic Press, New York

52.

Hoffmann JD, Davis GT, Lauritzen JI Jr (1976) The rate of crystallization of linear polymers with chain folding. In: Hannay HB (ed) Treatise on solid state chemistry, crystalline and noncrystalline solids, vol 3. Plenum Press, New York

53.

Androsch R, Monami A, Kucera J (2014) Effect of an alpha-phase nucleating agent on the crystallization kinetics of a propylene/ethylene random copolymer at largely different supercooling. J Crystal Growth 408:91–96CrossRef

54.

Mollova A, Androsch R, Mileva D, Gahleitner M, Funari SS (2013) Crystallization of isotactic polypropylene containing beta-phase nucleating agent at rapid cooling. Eur Polym J 49:1057–1065CrossRef

Titel: Crystallization kinetics of polyamide 11 in the presence of sepiolite and montmorillonite nanofillers
verfasst von: Katalee Jariyavidyanont
Walter Focke
René Androsch
Publikationsdatum: 01.07.2016
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 7/2016
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-016-3874-y

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