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Erschienen in: Colloid and Polymer Science 2/2019

06.01.2019 | Short Communication

Use of anchoring amphiphilic diblock copolymers for encapsulation of hydrophilic actives in polymeric microcapsules: methodology and encapsulation efficiency

verfasst von: Markus Andersson Trojer, Asvad A. Gabul-Zada, Anna Ananievskaia, Lars Nordstierna, Marcus Östman, Hans Blanck

Erschienen in: Colloid and Polymer Science | Ausgabe 2/2019

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Abstract

Aqueous core-shell particles based on polystyrene, poly(methyl methacrylate) or polycaprolactone have been formulated using a facile double emulsion-based solvent evaporation method. The size distribution is narrow, and the morphology control is remarkable given the simple characteristics of the encapsulation method. The inner droplets are stabilized by oil-soluble poly(ethylene oxide)-based block copolymers which are anchored in the polymeric shell by using hydrophobic blocks of the same type as that of the shell-forming polymer. This facilitates the efficient encapsulation of dyes and hydrophilic biocides.

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Literatur
1.
Zurück zum Zitat Thies C (2005) Microencapsulation. In: Kroschwitz JI (ed) Kirk-Othmer encyclopedia of chemical technology. Wiley, N.Y Thies C (2005) Microencapsulation. In: Kroschwitz JI (ed) Kirk-Othmer encyclopedia of chemical technology. Wiley, N.Y
2.
Zurück zum Zitat Shlomo M, Alexander K (2007) Microencapsulation, Encyclopedia of Surface and Colloid Science, Second Edition, Taylor & Francis, pp. 3957–3969 Shlomo M, Alexander K (2007) Microencapsulation, Encyclopedia of Surface and Colloid Science, Second Edition, Taylor & Francis, pp. 3957–3969
3.
Zurück zum Zitat Finch CA, Bodmeier R (2002) Microencapsulation. In: Bohnet M (ed) Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH, Weinheim Finch CA, Bodmeier R (2002) Microencapsulation. In: Bohnet M (ed) Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH, Weinheim
4.
Zurück zum Zitat Lensen D, Vriezema DM, van Hest JCM (2008) Polymeric microcapsules for synthetic applications. Macromol Biosci 8(11):991–1005CrossRefPubMed Lensen D, Vriezema DM, van Hest JCM (2008) Polymeric microcapsules for synthetic applications. Macromol Biosci 8(11):991–1005CrossRefPubMed
5.
Zurück zum Zitat Ghosh SK (2006) Functional coatings and microencapsulation: a general perspective. In: Ghosh SK (ed) Functional coatings. Wiley-VCH, WeinheimCrossRef Ghosh SK (2006) Functional coatings and microencapsulation: a general perspective. In: Ghosh SK (ed) Functional coatings. Wiley-VCH, WeinheimCrossRef
6.
Zurück zum Zitat Nordstierna L, Abdalla AA, Masuda M, Skarnemark G, Nydén M (2010) Molecular release from painted surfaces: free and encapsulated biocides. Prog Org Coat 69(1):45–48CrossRef Nordstierna L, Abdalla AA, Masuda M, Skarnemark G, Nydén M (2010) Molecular release from painted surfaces: free and encapsulated biocides. Prog Org Coat 69(1):45–48CrossRef
7.
Zurück zum Zitat Paul RD, Polymers in controlled release technology, controlled release polymeric formulations, ACS1976, pp. 1–14 Paul RD, Polymers in controlled release technology, controlled release polymeric formulations, ACS1976, pp. 1–14
8.
Zurück zum Zitat Esser-Kahn AP, Odom SA, Sottos NR, White SR, Moore JS (2011) Triggered release from polymer capsules, macromolecules (Washington, DC). United States 44(14):5539–5553 Esser-Kahn AP, Odom SA, Sottos NR, White SR, Moore JS (2011) Triggered release from polymer capsules, macromolecules (Washington, DC). United States 44(14):5539–5553
9.
Zurück zum Zitat Andersson Trojer M, Andersson H, Li Y, Borg J, Holmberg K, Nyden M, Nordstierna L (2013) Charged microcapsules for controlled release of hydrophobic actives part III: effect of polyelectrolyte brush- and multilayers on sustained release. Phys Chem Chem Phys 15(17):6456–6466CrossRef Andersson Trojer M, Andersson H, Li Y, Borg J, Holmberg K, Nyden M, Nordstierna L (2013) Charged microcapsules for controlled release of hydrophobic actives part III: effect of polyelectrolyte brush- and multilayers on sustained release. Phys Chem Chem Phys 15(17):6456–6466CrossRef
10.
Zurück zum Zitat Andersson Trojer M, Li Y, Abrahamsson C, Mohamed A, Eastoe J, Holmberg K, Nyden M (2013) Charged microcapsules for controlled release of hydrophobic actives part I: encapsulation methodology and interfacial properties. Soft Matter 9(5):1468–1477CrossRef Andersson Trojer M, Li Y, Abrahamsson C, Mohamed A, Eastoe J, Holmberg K, Nyden M (2013) Charged microcapsules for controlled release of hydrophobic actives part I: encapsulation methodology and interfacial properties. Soft Matter 9(5):1468–1477CrossRef
11.
Zurück zum Zitat Andersson Trojer M, Nordstierna L, Nordin M, Nyden BM, Holmberg K (2013) Encapsulation of actives for sustained release. Phys Chem Chem Phys 15(41):17727–17741CrossRefPubMed Andersson Trojer M, Nordstierna L, Nordin M, Nyden BM, Holmberg K (2013) Encapsulation of actives for sustained release. Phys Chem Chem Phys 15(41):17727–17741CrossRefPubMed
12.
Zurück zum Zitat Nordstierna L, Abdalla AA, Nordin M, Nyden M (2010) Comparison of release behavior from microcapsules and microspheres. Prog Org Coat 69(1):49–51CrossRef Nordstierna L, Abdalla AA, Nordin M, Nyden M (2010) Comparison of release behavior from microcapsules and microspheres. Prog Org Coat 69(1):49–51CrossRef
13.
Zurück zum Zitat Bergek J, Andersson Trojer M, Uhr H, Nordstierna L (2016) Controlled release of a microencapsulated arduous semi-hydrophobic active from coatings: Superhydrophilic polyelectrolyte shells as globally rate-determining barriers. J Control Release 225:31–39CrossRefPubMed Bergek J, Andersson Trojer M, Uhr H, Nordstierna L (2016) Controlled release of a microencapsulated arduous semi-hydrophobic active from coatings: Superhydrophilic polyelectrolyte shells as globally rate-determining barriers. J Control Release 225:31–39CrossRefPubMed
14.
Zurück zum Zitat Andersson Trojer M, Li Y, Wallin M, Holmberg K, Nyden M (2013) Charged microcapsules for controlled release of hydrophobic actives part II: surface modification by LbL adsorption and lipid bilayer formation on properly anchored dispersant layers. J Colloid Interface Sci 409(1):8–17CrossRef Andersson Trojer M, Li Y, Wallin M, Holmberg K, Nyden M (2013) Charged microcapsules for controlled release of hydrophobic actives part II: surface modification by LbL adsorption and lipid bilayer formation on properly anchored dispersant layers. J Colloid Interface Sci 409(1):8–17CrossRef
15.
Zurück zum Zitat Andersson Trojer M, Wendel A, Holmberg K, Nydén M (2012) The effect of pH on charge, swelling and desorption of the emulsifier poly(methacrylic acid) from poly(methyl methacrylate) microcapsules. J Colloid Interface Sci 375(1):213–215CrossRefPubMed Andersson Trojer M, Wendel A, Holmberg K, Nydén M (2012) The effect of pH on charge, swelling and desorption of the emulsifier poly(methacrylic acid) from poly(methyl methacrylate) microcapsules. J Colloid Interface Sci 375(1):213–215CrossRefPubMed
17.
Zurück zum Zitat Andersson Trojer M, Nordstierna L, Bergek J, Blanck H, Holmberg K, Nyden BM (2015) Use of microcapsules as controlled release devices for coatings. Adv Colloid Interf Sci 222(Reinhard Miller, Honorary Issue):18–43CrossRef Andersson Trojer M, Nordstierna L, Bergek J, Blanck H, Holmberg K, Nyden BM (2015) Use of microcapsules as controlled release devices for coatings. Adv Colloid Interf Sci 222(Reinhard Miller, Honorary Issue):18–43CrossRef
18.
Zurück zum Zitat Atkin R, Davies P, Hardy J, Vincent B (2004) Preparation of aqueous core/polymer shell microcapsules by internal phase separation. Macromolecules 37(21):7979–7985CrossRef Atkin R, Davies P, Hardy J, Vincent B (2004) Preparation of aqueous core/polymer shell microcapsules by internal phase separation. Macromolecules 37(21):7979–7985CrossRef
19.
Zurück zum Zitat Caruso F, Caruso RA, Moehwald H (1998) Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science (Washington, D. C) 282(5391):1111–1114CrossRef Caruso F, Caruso RA, Moehwald H (1998) Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating. Science (Washington, D. C) 282(5391):1111–1114CrossRef
20.
Zurück zum Zitat Kim S-H, Abbaspourrad A, Weitz DA (2011) Amphiphilic crescent-moon-shaped microparticles formed by selective adsorption of colloids. J Am Chem Soc 133(14):5516–5524CrossRefPubMed Kim S-H, Abbaspourrad A, Weitz DA (2011) Amphiphilic crescent-moon-shaped microparticles formed by selective adsorption of colloids. J Am Chem Soc 133(14):5516–5524CrossRefPubMed
21.
Zurück zum Zitat Zhang J, Coulston RJ, Jones ST, Geng J, Scherman OA, Abell C (2012) One-step fabrication of supramolecular microcapsules from microfluidic droplets. Science (Washington, DC, United States) 335(6069):690–694CrossRef Zhang J, Coulston RJ, Jones ST, Geng J, Scherman OA, Abell C (2012) One-step fabrication of supramolecular microcapsules from microfluidic droplets. Science (Washington, DC, United States) 335(6069):690–694CrossRef
22.
Zurück zum Zitat Shim JW, Kim S-H, Jeon S-J, Yang S-M, Yi G-R (2010) Microcapsules with tailored nanostructures by microphase separation of block copolymers. Chem Mater 22(19):5593–5600CrossRef Shim JW, Kim S-H, Jeon S-J, Yang S-M, Yi G-R (2010) Microcapsules with tailored nanostructures by microphase separation of block copolymers. Chem Mater 22(19):5593–5600CrossRef
23.
Zurück zum Zitat Benichou A, Aserin A, Garti N (2004) Double emulsions stabilized with hybrids of natural polymers for entrapment and slow release of active matters. Adv Colloid Interf Sci 108-109:29–41CrossRef Benichou A, Aserin A, Garti N (2004) Double emulsions stabilized with hybrids of natural polymers for entrapment and slow release of active matters. Adv Colloid Interf Sci 108-109:29–41CrossRef
24.
Zurück zum Zitat Garti N (1997) Double emulsions - scope, limitations and new achievements. Colloids Surf A Physicochem Eng Asp 123-124:233–246CrossRef Garti N (1997) Double emulsions - scope, limitations and new achievements. Colloids Surf A Physicochem Eng Asp 123-124:233–246CrossRef
25.
Zurück zum Zitat Garti N, Lutz R (2012) Double emulsions, Encyclopedia of surface and colloid science (2nd edition) 1816-1845, 30 pp. Garti N, Lutz R (2012) Double emulsions, Encyclopedia of surface and colloid science (2nd edition) 1816-1845, 30 pp.
26.
Zurück zum Zitat Bengtsson-Palme J, Hammaren R, Pal C, Oestman M, Bjoerlenius B, Flach C-F, Fick J, Kristiansson E, Tysklind M, Larsson DGJ (2016) Elucidating selection processes for antibiotic resistance in sewage treatment plants using metagenomics. Sci Total Environ 572:697–712CrossRefPubMed Bengtsson-Palme J, Hammaren R, Pal C, Oestman M, Bjoerlenius B, Flach C-F, Fick J, Kristiansson E, Tysklind M, Larsson DGJ (2016) Elucidating selection processes for antibiotic resistance in sewage treatment plants using metagenomics. Sci Total Environ 572:697–712CrossRefPubMed
27.
Zurück zum Zitat Lundstroem SV, Oestman M, Bengtsson-Palme J, Rutgersson C, Thoudal M, Sircar T, Blanck H, Eriksson KM, Tysklind M, Flach C-F, Larsson DGJ (2016) Minimal selective concentrations of tetracycline in complex aquatic bacterial biofilms. Sci Total Environ 553:587–595CrossRef Lundstroem SV, Oestman M, Bengtsson-Palme J, Rutgersson C, Thoudal M, Sircar T, Blanck H, Eriksson KM, Tysklind M, Flach C-F, Larsson DGJ (2016) Minimal selective concentrations of tetracycline in complex aquatic bacterial biofilms. Sci Total Environ 553:587–595CrossRef
28.
Zurück zum Zitat Garti N, Benichou A (2004) Recent developments in double emulsions for food applications, Food Science and Technology (New York, NY, United States) 132 (Food Emulsions (4th Edition)) 353–412 Garti N, Benichou A (2004) Recent developments in double emulsions for food applications, Food Science and Technology (New York, NY, United States) 132 (Food Emulsions (4th Edition)) 353–412
29.
Zurück zum Zitat Pence HE, Williams A (2010) ChemSpider: an online chemical information resource. J Chem Educ 87(11):1123–1124CrossRef Pence HE, Williams A (2010) ChemSpider: an online chemical information resource. J Chem Educ 87(11):1123–1124CrossRef
30.
Zurück zum Zitat Bolton EE, Wang Y, Thiessen PA, Bryant SH (2008) PubChem: integrated platform of small molecules and biological activities. Ann Rep Comput Chem 4:217–241CrossRef Bolton EE, Wang Y, Thiessen PA, Bryant SH (2008) PubChem: integrated platform of small molecules and biological activities. Ann Rep Comput Chem 4:217–241CrossRef
31.
Zurück zum Zitat Goodman J (2009) Computer software review: Reaxys, J. Chem Inf Model. 49(Copyright (C) 2013 American Chemical Society (ACS). All Rights Reserved.) 2897–2898 Goodman J (2009) Computer software review: Reaxys, J. Chem Inf Model. 49(Copyright (C) 2013 American Chemical Society (ACS). All Rights Reserved.) 2897–2898
32.
Zurück zum Zitat Andersson Trojer M, Holmberg K, Nydén M (2012) The importance of proper anchoring of an amphiphilic dispersant for colloidal stability. Langmuir 28(9):4047–4050CrossRef Andersson Trojer M, Holmberg K, Nydén M (2012) The importance of proper anchoring of an amphiphilic dispersant for colloidal stability. Langmuir 28(9):4047–4050CrossRef
33.
Zurück zum Zitat Karlström G (2000) On the origin of the solution behaviour of ethyleneoxide containing polymers A2 - Alexandridis, Paschalis. In: Lindman B (ed) Amphiphilic block copolymers, Elsevier science B.V., Amsterdam, pp 41–55CrossRef Karlström G (2000) On the origin of the solution behaviour of ethyleneoxide containing polymers A2 - Alexandridis, Paschalis. In: Lindman B (ed) Amphiphilic block copolymers, Elsevier science B.V., Amsterdam, pp 41–55CrossRef
34.
Zurück zum Zitat Andersson Trojer M, Ananievskaia A, Gabul-Zada AA, Nordstierna L, Blanck H (2018) Polymer core-polymer shell particle formation enabled by ultralow interfacial tension via internal phase separation: morphology prediction using the Van Oss formalism. Colloid Interface Sci Commun 25:36–40CrossRef Andersson Trojer M, Ananievskaia A, Gabul-Zada AA, Nordstierna L, Blanck H (2018) Polymer core-polymer shell particle formation enabled by ultralow interfacial tension via internal phase separation: morphology prediction using the Van Oss formalism. Colloid Interface Sci Commun 25:36–40CrossRef
35.
Zurück zum Zitat Liu R, Ma G, Meng F-T, Su Z-G (2005) Preparation of uniform-sized PLA microcapsules by combining Shirasu porous glass membrane emulsification technique and multiple emulsion-solvent evaporation method. J Control Release 103(1):31–43CrossRefPubMed Liu R, Ma G, Meng F-T, Su Z-G (2005) Preparation of uniform-sized PLA microcapsules by combining Shirasu porous glass membrane emulsification technique and multiple emulsion-solvent evaporation method. J Control Release 103(1):31–43CrossRefPubMed
36.
Zurück zum Zitat O'Donnell PB, McGinity JW (1997) Preparation of microspheres by the solvent evaporation technique. Adv Drug Deliv Rev 28(1):25–42CrossRefPubMed O'Donnell PB, McGinity JW (1997) Preparation of microspheres by the solvent evaporation technique. Adv Drug Deliv Rev 28(1):25–42CrossRefPubMed
37.
Zurück zum Zitat Skirtach AG, Yashchenok AM, Moehwald H (2011) Encapsulation, release and applications of LbL polyelectrolyte multilayer capsules. Chem Commun 47(48):12736–12746CrossRef Skirtach AG, Yashchenok AM, Moehwald H (2011) Encapsulation, release and applications of LbL polyelectrolyte multilayer capsules. Chem Commun 47(48):12736–12746CrossRef
38.
Zurück zum Zitat Andersson M, Hansson O, Oehrstroem L, Idstroem A, Nyden M (2011) Vinylimidazole copolymers: coordination chemistry, solubility, and cross-linking as function of Cu2+ and Zn2+ complexation. Colloid Polym Sci 289(12):1361–1372CrossRef Andersson M, Hansson O, Oehrstroem L, Idstroem A, Nyden M (2011) Vinylimidazole copolymers: coordination chemistry, solubility, and cross-linking as function of Cu2+ and Zn2+ complexation. Colloid Polym Sci 289(12):1361–1372CrossRef
Metadaten
Titel
Use of anchoring amphiphilic diblock copolymers for encapsulation of hydrophilic actives in polymeric microcapsules: methodology and encapsulation efficiency
verfasst von
Markus Andersson Trojer
Asvad A. Gabul-Zada
Anna Ananievskaia
Lars Nordstierna
Marcus Östman
Hans Blanck
Publikationsdatum
06.01.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 2/2019
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-018-04463-5

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