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Phase behavior of ABC-triblock copolymers with two inherently miscible blocks

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Abstract

 The phase behavior of ternary poly-1,4-isoprene-block-poly-1,2-butadiene-block-polystyrene (ABC) triblock copolymers based on a compatible diblock copolymer attached to an incompatible C-block of different lengths is investigated by differential scanning calorimetry, transmission electron microscopy and dynamic mechanical analysis. It is shown that the system behaves like a binary diblock copolymer of a mixed AB-block and a microphase separated C-block.

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Authors and Affiliations

  1. Makromolekulare Chemie II Universität Bayreuth 95440 Bayreuth Germany, , , , , , DE

    C. Neumann, V. Abetz & R. Stadler

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  1. C. Neumann
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  2. V. Abetz
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  3. R. Stadler
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Received: 10 June 1997 Accepted: 19 August 1997

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Neumann, C., Abetz, V. & Stadler, R. Phase behavior of ABC-triblock copolymers with two inherently miscible blocks. Colloid Polym Sci 276, 19–27 (1998). https://doi.org/10.1007/s003960050203

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  • DOI: https://doi.org/10.1007/s003960050203

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