Skip to main content
Erschienen in: Rheologica Acta 4/2010

01.04.2010 | Original Contribution

Thermo-rheological behavior of model protein–polysaccharide mixtures

verfasst von: R. J. Andrade, A. G. Azevedo, R. M. Musampa, João M. Maia

Erschienen in: Rheologica Acta | Ausgabe 4/2010

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The use of mixtures of pea protein isolate (PPI) and κ-carrageenan (κ-C) is increasing rapidly with the aim of increasing the stability and viscosity of food products. Recent works have studied their textural and thermal properties but few have studied the influence of the temperature and concentration on the rheological behavior of model systems. In the present work, we study the thermo-rheological properties in the linear and non-linear viscoelastic regimes, in both shear and extensional flows, of mixtures of PPI and κ-C with the aim of obtaining a model for the temperature-induced gelation of complex mixtures of globular vegetable proteins under linear and non-linear deformations. We analyzed the influence of temperature and protein-to-polysaccharide ratios and showed that there are strong changes in the mechanical properties. In shear flows, small-amplitude oscillatory shear was used to study the linear regime and large-amplitude oscillatory shear was used for the non-linear regime. In extensional flows, studies were carried out via the analysis of the dynamics of capillary thinning and breakup process in a filament-thinning rheometer.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Arntfield SD, Murray E, Ismond M (1986) Effect of salt on the thermal stability of storage proteins from faba bean (Vicia faba). J Food Sci 51(2):371–377CrossRef Arntfield SD, Murray E, Ismond M (1986) Effect of salt on the thermal stability of storage proteins from faba bean (Vicia faba). J Food Sci 51(2):371–377CrossRef
Zurück zum Zitat Bacon JR, Noel T, Lambert N (1990) Preparation of transparent pea protein gels: a comparison of isolation procedures. Int J Food Sci Technol 25:527–537 Bacon JR, Noel T, Lambert N (1990) Preparation of transparent pea protein gels: a comparison of isolation procedures. Int J Food Sci Technol 25:527–537
Zurück zum Zitat Belitz HD, Grosch W (1997) Química de los Alimentos, 2nd edn. Editorial Acribia, Zaragosa Belitz HD, Grosch W (1997) Química de los Alimentos, 2nd edn. Editorial Acribia, Zaragosa
Zurück zum Zitat Capron I, Nicolai T, Durand D (1999) Heat induced aggregation and gelation of beta-lactoglobulin in the presence of kappa-carrageenan. Food Hydrocoll 13(1):1–5CrossRef Capron I, Nicolai T, Durand D (1999) Heat induced aggregation and gelation of beta-lactoglobulin in the presence of kappa-carrageenan. Food Hydrocoll 13(1):1–5CrossRef
Zurück zum Zitat Chen Y, Liao M, Boger D, Dunstan D (2001) Rheological characterization of kappa-carrageenan/locust bean gum mixtures. Carbohydr Polym 46(2):117–124CrossRef Chen Y, Liao M, Boger D, Dunstan D (2001) Rheological characterization of kappa-carrageenan/locust bean gum mixtures. Carbohydr Polym 46(2):117–124CrossRef
Zurück zum Zitat Chen Y, Liao M, Dunstan DE (2002) The rheology of K+-κ-carrageenan as a weak gel. Carbohydr Polym 50:109–116CrossRef Chen Y, Liao M, Dunstan DE (2002) The rheology of K+-κ-carrageenan as a weak gel. Carbohydr Polym 50:109–116CrossRef
Zurück zum Zitat Clark AH (1995) Kinetics of biopolymer gelation—implications of a cascade theory description for the concentration, molecular-weight, and temperature dependences of the shear modulus and gel time. J Rheol 39(6):1429–1444CrossRefADS Clark AH (1995) Kinetics of biopolymer gelation—implications of a cascade theory description for the concentration, molecular-weight, and temperature dependences of the shear modulus and gel time. J Rheol 39(6):1429–1444CrossRefADS
Zurück zum Zitat Clark AH, Kavanagh G, Ross-Murphy S (2001) Globular protein gelation—theory and experiment. Food Hydrocoll 15:383–400CrossRef Clark AH, Kavanagh G, Ross-Murphy S (2001) Globular protein gelation—theory and experiment. Food Hydrocoll 15:383–400CrossRef
Zurück zum Zitat Dinkinson E (2006) Colloid science of mixed ingredients. Soft Matter 2(8):642–652CrossRef Dinkinson E (2006) Colloid science of mixed ingredients. Soft Matter 2(8):642–652CrossRef
Zurück zum Zitat Dunstan DE, Chen Y, Liao M, Salvatore R, Boger D, Prica M (2001) Structure and rheology of the kappa-carrageenan/locust bean gum gels. Food Hydrocoll 15(4–6):475–484CrossRef Dunstan DE, Chen Y, Liao M, Salvatore R, Boger D, Prica M (2001) Structure and rheology of the kappa-carrageenan/locust bean gum gels. Food Hydrocoll 15(4–6):475–484CrossRef
Zurück zum Zitat Eleya MMO, Turgeon S (2000) Rheology of kappa-carrageenan and beta-lactoglobulin mixed gels. Food Hydrocoll 14(1):29–40CrossRef Eleya MMO, Turgeon S (2000) Rheology of kappa-carrageenan and beta-lactoglobulin mixed gels. Food Hydrocoll 14(1):29–40CrossRef
Zurück zum Zitat Hyun K, Wilhelm M (2009) Establishing a new mechanical nonlinear coefficient Q from FT-rheology: first investigation of entangled linear and comb polymer model systems. Macromolecules 42(1):411–422CrossRefADS Hyun K, Wilhelm M (2009) Establishing a new mechanical nonlinear coefficient Q from FT-rheology: first investigation of entangled linear and comb polymer model systems. Macromolecules 42(1):411–422CrossRefADS
Zurück zum Zitat Hyun K, Nam J, Wilhelm M, Ahn K, Lee S (2006) Large amplitude oscillatory shear behavior of PEO-PPO-PEO triblock copolymer solutions. Rheol Acta 45:239–249CrossRef Hyun K, Nam J, Wilhelm M, Ahn K, Lee S (2006) Large amplitude oscillatory shear behavior of PEO-PPO-PEO triblock copolymer solutions. Rheol Acta 45:239–249CrossRef
Zurück zum Zitat Kinsela JE (1979) Functional properties of soy proteins. J Am Oil Chem Soc 56:242–258CrossRef Kinsela JE (1979) Functional properties of soy proteins. J Am Oil Chem Soc 56:242–258CrossRef
Zurück zum Zitat Mangione MR, Giacomazza D, Bulone D, Martorana V, San Biagio PL (2003) Thermoreversible gelation of kappa-Carrageenan: relation between conformational transition and aggregation. Biophys Chemist 104(1):95–105CrossRef Mangione MR, Giacomazza D, Bulone D, Martorana V, San Biagio PL (2003) Thermoreversible gelation of kappa-Carrageenan: relation between conformational transition and aggregation. Biophys Chemist 104(1):95–105CrossRef
Zurück zum Zitat Morris ER, Rees DA, Robinson G (1980) Cation-specific aggregation of carrageenan helices: domain model of polymer gel structure. J Mol Biol 138:349–362CrossRefPubMed Morris ER, Rees DA, Robinson G (1980) Cation-specific aggregation of carrageenan helices: domain model of polymer gel structure. J Mol Biol 138:349–362CrossRefPubMed
Zurück zum Zitat Musampa RM, Alves M, Maia J (2007) Phase separation, rheology and microstructure of pea protein-kappa-carrageenan mixtures. Food Hydrocoll 21(1):92–99CrossRef Musampa RM, Alves M, Maia J (2007) Phase separation, rheology and microstructure of pea protein-kappa-carrageenan mixtures. Food Hydrocoll 21(1):92–99CrossRef
Zurück zum Zitat Neidhofer T, Wilhelm M, Debbaut B (2003) Fourier-transform rheology experiments and finite-element simulation on linear polystyrene solutions. J Rheol 47(6):1351–1371CrossRefADS Neidhofer T, Wilhelm M, Debbaut B (2003) Fourier-transform rheology experiments and finite-element simulation on linear polystyrene solutions. J Rheol 47(6):1351–1371CrossRefADS
Zurück zum Zitat Nunes MC (2005) Interacções Proteina/polissacárido em Géis Proteicos de Origem Vegetal. Dissertation, University of Lisbon Nunes MC (2005) Interacções Proteina/polissacárido em Géis Proteicos de Origem Vegetal. Dissertation, University of Lisbon
Zurück zum Zitat Nunes MC, Batista P, Raymundo A, Alves M, Sousa I (2003) Vegetable proteins and milk puddings. Colloids Surf, B Biointerfaces 31(1–4):21–29CrossRef Nunes MC, Batista P, Raymundo A, Alves M, Sousa I (2003) Vegetable proteins and milk puddings. Colloids Surf, B Biointerfaces 31(1–4):21–29CrossRef
Zurück zum Zitat Owen AJ, Jones R (1998) Rheology of a simultaneously phase separating and gelling biopolymer mixture. Macromolecules 31(21):7336–7339CrossRefADS Owen AJ, Jones R (1998) Rheology of a simultaneously phase separating and gelling biopolymer mixture. Macromolecules 31(21):7336–7339CrossRefADS
Zurück zum Zitat Piculell L, Iliopoulos I, Linse P, Turquois T, Viebke C et al (1994) Association and segregation in ternary polymer solutions and gels. In: Phillips G, Williams PA, Wedlock DJ (eds) Gums and stabilisers for food industry, vol 7. Oxford University Press, Oxford, pp 309–322 Piculell L, Iliopoulos I, Linse P, Turquois T, Viebke C et al (1994) Association and segregation in ternary polymer solutions and gels. In: Phillips G, Williams PA, Wedlock DJ (eds) Gums and stabilisers for food industry, vol 7. Oxford University Press, Oxford, pp 309–322
Zurück zum Zitat Piculell L, Borgstrom J, Viebke C (1995) Characterization of kappa-carrageenan and iota-carrageenan coils and helices by MALLS/GPC. Carbohydr Polym 27(2):145–154CrossRef Piculell L, Borgstrom J, Viebke C (1995) Characterization of kappa-carrageenan and iota-carrageenan coils and helices by MALLS/GPC. Carbohydr Polym 27(2):145–154CrossRef
Zurück zum Zitat Renard D, Robert P, Garnier C, Dufour E, Lefebvre J (2000) Gelation by phase separation in a whey protein system: in-situ kinetics of aggregation. J Biotechnol 79:231–244CrossRefPubMed Renard D, Robert P, Garnier C, Dufour E, Lefebvre J (2000) Gelation by phase separation in a whey protein system: in-situ kinetics of aggregation. J Biotechnol 79:231–244CrossRefPubMed
Zurück zum Zitat Rochas C, RinaudoM(1984) On the mechanism of gel formation in kappa-carrageenan. Biopolymers 23:735–745CrossRef Rochas C, RinaudoM(1984) On the mechanism of gel formation in kappa-carrageenan. Biopolymers 23:735–745CrossRef
Zurück zum Zitat Rodd L, Scott T, Cooper-White J, McKlinley G (2005) Capillary break-up rheometry of low-viscosity elastic fluids. Appl Rheol 15(1):12–27 Rodd L, Scott T, Cooper-White J, McKlinley G (2005) Capillary break-up rheometry of low-viscosity elastic fluids. Appl Rheol 15(1):12–27
Zurück zum Zitat Schmitt C (1998) Structure and technofunctional properties of protein polysaccharide complexes: A review. Crit Rev Food Sci Nutr 38(8):689–753CrossRefPubMed Schmitt C (1998) Structure and technofunctional properties of protein polysaccharide complexes: A review. Crit Rev Food Sci Nutr 38(8):689–753CrossRefPubMed
Zurück zum Zitat Stading M, Langton M, Hermansson A (1993) Microstructure and rheological behavior of particulate beta-lactoglobulin gels. Food Hydrocoll 7(3):195–212CrossRef Stading M, Langton M, Hermansson A (1993) Microstructure and rheological behavior of particulate beta-lactoglobulin gels. Food Hydrocoll 7(3):195–212CrossRef
Zurück zum Zitat Stanley NF (1990) Carrageenans. In: Harris P (ed) Food gels. Elsevier Applied Science, London, pp 79–119 Stanley NF (1990) Carrageenans. In: Harris P (ed) Food gels. Elsevier Applied Science, London, pp 79–119
Zurück zum Zitat Tolstoguzov VB (1991) Functional properties of food proteins and role of protein–polysaccharide interaction. Food Hydrocoll 4(6):429–468CrossRef Tolstoguzov VB (1991) Functional properties of food proteins and role of protein–polysaccharide interaction. Food Hydrocoll 4(6):429–468CrossRef
Zurück zum Zitat Tolstoguzov VB (1993) Thermoplastic extrusion—the mechanism of the formation of extrudate structure and properties. J Am Oil Chem Soc 70(4):417–424CrossRef Tolstoguzov VB (1993) Thermoplastic extrusion—the mechanism of the formation of extrudate structure and properties. J Am Oil Chem Soc 70(4):417–424CrossRef
Zurück zum Zitat Wang CH, Damoradan S (1991) Thermal gelation of globular proteins: influence of protein conformation on gel strength. J Agric Food Chem 39:433–438CrossRef Wang CH, Damoradan S (1991) Thermal gelation of globular proteins: influence of protein conformation on gel strength. J Agric Food Chem 39:433–438CrossRef
Zurück zum Zitat Wilhelm M (2002) Fourier transform rheology. Macromol Mater Eng 287:83–105CrossRef Wilhelm M (2002) Fourier transform rheology. Macromol Mater Eng 287:83–105CrossRef
Zurück zum Zitat Yuguchi Y, Thi Thu Thuy T, Urakawa H, Kajiwara K (2002) Structural characteristics of carrageenan gels: temperature and concentration dependence. Food Hydrocoll 16:515–522CrossRef Yuguchi Y, Thi Thu Thuy T, Urakawa H, Kajiwara K (2002) Structural characteristics of carrageenan gels: temperature and concentration dependence. Food Hydrocoll 16:515–522CrossRef
Metadaten
Titel
Thermo-rheological behavior of model protein–polysaccharide mixtures
verfasst von
R. J. Andrade
A. G. Azevedo
R. M. Musampa
João M. Maia
Publikationsdatum
01.04.2010
Verlag
Springer-Verlag
Erschienen in
Rheologica Acta / Ausgabe 4/2010
Print ISSN: 0035-4511
Elektronische ISSN: 1435-1528
DOI
https://doi.org/10.1007/s00397-010-0431-3

Weitere Artikel der Ausgabe 4/2010

Rheologica Acta 4/2010 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.