Abstract
Fluid inclusions have been studied in minerals infilling fissures (quartz, calcite, fluorite, anhydrite) hosted by Carboniferous and Permian strata from wells in the central and eastern part of the North German Basin in order to decipher the fluid and gas migration related to basin tectonics. The microthermometric data and the results of laser Raman spectroscopy reveal compelling evidence for multiple events of fluid migration. The fluid systems evolved from a H2O–NaCl±KCl type during early stage of basin subsidence to a H2O–NaCl–CaCl2 type during further burial. Locally, fluid inclusions are enriched in K, Cs, Li, B, Rb and other cations indicating intensive fluid–rock interaction of the saline brines with Lower Permian volcanic rocks or sediments. Fluid migration through Carboniferous sediments was often accompanied by the migration of gases. Aqueous fluid inclusions in quartz from fissures in Carboniferous sedimentary rocks are commonly associated with co-genetically trapped CH4–CO2 inclusions. P–T conditions estimated, via isochore construction, yield pressure conditions between 620 and 1,650 bar and temperatures between 170 and 300°C during fluid entrapment. The migration of CH4-rich gases within the Carboniferous rocks can be related to the main stage of basin subsidence and stages of basin uplift. A different situation is recorded in fluid inclusions in fissure minerals hosted by Permian sandstones and carbonates: aqueous fluid inclusions in calcite, quartz, fluorite and anhydrite are always H2O–NaCl–CaCl2-rich and show homogenization temperatures between 120 and 180°C. Co-genetically trapped gas inclusions are generally less frequent. When present, they show variable N2–CH4 compositions but contain no CO2. P–T reconstructions indicate low-pressure conditions during fluid entrapment, always below 500 bar. The entrapment of N2–CH4 inclusions seems to be related to phases of tectonic uplift during the Upper Cretaceous. A potential source for nitrogen in the inclusions and reservoirs is Corg-rich Carboniferous shales with high nitrogen content. Intensive interaction of brines with Carboniferous or even older shales is proposed from fluid inclusion data (enrichment in Li, Ba, Pb, Zn, Mg) and sulfur isotopic compositions of abundant anhydrite from fissures. The mainly light δ34S values of the fissure anhydrites suggest that sulfate is either derived through oxidation and re-deposition of biogenic sulfur or through mixing of SO 2−4 -rich formation waters with variable amounts of dissolved biogenic sulfide. An igneous source for nitrogen seems to be unlikely since these rocks have low total nitrogen content and, furthermore, even extremely altered volcanic rocks from the study area do not show a decrease in total nitrogen content.
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References
Bandlowa T (1998) Erdgasführung im Karbon-Perm-Trias-Komplex der mitteleuropäischen Senke. Geol Jb A 151:3–65
Banks DA, Giuliani G, Yardley BDW, Cheilletz A (2000) Emerald mineralisation in Colombia: fluid chemistry and the role of brine mixing. Miner Deposita 35:699–713
Banks DA, Boyce AJ, Samson IM (2002) Constraints on the origins of fluids forming Irish Zn-Pb-Ba deposits: evidence from the composition of fluid inclusions. Econ Geol 97:471–480
BGR, BGS, GEUS, TNO, PGI (1998) NW European Gas Atlas. In: Lokhurst (ed), ISBN 90–72869–60–5
Brown PE, Hagemann SG (1994) MacFlinCor: a computer program for fluid inclusion data reduction and manipulation. In: De Vivo B, Frezotti ML (eds) Fluid Inclusions in minerals: methods and applications. IMA Short C, pp 231–250
Davis DW, Lowenstein TK, Spencer RJ (1990) Melting behavior of fluid inclusions in laboratory-grown halite crystals in the systems NaCl–H2O, NaCl–KCl–H2O, NaCl–MgCl2–H2O, and NaCl–CaCl2–H2O. Geochim Cosmoschim Acta 54:591–601
Davisson ML and Criss RE (1996) Na–Ca–Cl relations in basinal fluids. Geochim et Cosmochim Acta 60:2743–2752
Everlien G (1990) Das Verhalten des in Mineralen gebundenen Stickstoffs während der Diagenese und Metamorphose von Sedimenten. PhD Thesis, TU Braunschweig, pp 1–88
Fontes JC, Matray JM (1993) Geochemistry and origin of formation brines from the Paris Basin, France. 1. Brines associated with Triasssic salts. Chem Geol 109:149–175
Gerling P, Kockel F, Krull P (1999) Das Kohlenwasserstoffpotential des Präwestfals im Norddeutschen Becken. DGMK Forschungsb 433:1–107
Gerling P, Lokhorst A, Nicholson RA, Kotarba M (1998) Natural gas from Pre-Westphalian sources in Northwest Europe – a new exploration target. – Int. Gas Research Conf., Proceedings, 219–229, San Diego
Günther D, Audetat A, Frischknecht R, Heinrich CA (1998) Quantitative analysis of major, minor and trace elements in fluid inclusions using laser ablation inductively coupled plasma mass spectrometry. J Anal Atom Spec 13(4):263–270
Goldstein RH (2001) Fluid inclusions in sedimentary and diagenetic systems. Lithos 55:159–193
Goldstein RH, Reynolds TJ (1994) Systematics of fluid inclusions in diagenetic minerals. SEPM Short C 31, pp 1–199
Heinrich CA, Pettke T, Halter WE, Aigner-Torres M, Audétat A, Günther D, Hattendorf B, Bleiner D, Guillong M, Horn I (2003) Quantitative multi-element analysis of minerals, fluid and melt inclusions by laser-ablation inductively-coupled-plasma mass-spectrometry. Geochim Cosmochim Acta 67:3473–3496
Hoth P (1997) Fazies und Diagenese von Präperm-Sedimenten der Geotraverse Harz - Rügen. Schriftenr Geowiss 4:1–139
Krooss BM, Littke R, Müller B, Frielingsdorf J, Schwochau K, Idiz EF (1995) Generation of nitrogen and methane from sedimentary organic matter: implications on the dynamics of natural gas accumulations. Chem Geol 126:291–318
Littke R, Krooss BM, Idiz EF, Frielingsdorf J (1995) Molecular nitrogen in natural gas accumulations: generation from sedimentary organic matter at high temperatures. Am Assoc Pet Geol Bull 79:410–430
Lüders V, Möller P (1992) Fluid evolution and ore deposition in the Harz Mountains (Germany). Eur J Mineral 4:1053–1068
Lüders V, Stedingk K, Franzke HJ (1993) Review of geological setting and mineral paragenesis. In: Möller P, Lüders V (eds) Formation of hydrothermal vein deposits—a case study of the Pb-Zn, barite and fluorite deposits of the Harz Mountains, Mono Ser Min Dep 30:5–11
Lüders V, Hoth P, Reutel C (1999) Fluid- and gas migration in the eastern part of the North German Basin. Terra Nostra 99/6:193–195
Mingram B, Hoth P, Lüders V, Harlov D (2005) The significance of fixed ammonium in Paleozoic sediments for the generation of nitrogen rich natural gases in the North German Basin (NGB). This issue
Nielsen H (1979) Sulfur isotopes in nature. In: Jäger E, Hunziker J (eds) Lectures in isotope geology. Springer, Berlin Heidelberg New York, pp 283–312
Ohmoto H (1972) Systematics of sulfur and carbon isotopes in hydrothermal ore deposits. Econ Geol 67:551–579
Ohmoto H, Lasaga AC (1982) Kinetics of reactions between aqueous sulfates and sulfides in hydrothermal systems. Geochim Cosmochim Acta 46:1727–1745
Ohmoto H, Rye RO (1979) Isotopes of sulfur and carbon. In: Barnes HL (ed) Geochemistry of hydrothermal ore deposits, 2nd edn. Wiley, New York, pp 509–567
Pettke T, Halter WE, Webster JD, Aigner-Torres M, Heinrich CA (2004) Accurate quantification of melt inclusion chemistry by LA-ICPMS: A comparison with EMP and SIMS and advantages and possible limitations of these methods. Lithos 78:333–361
Reutel C, Lüders V (1998) Fluid-Evolution und Gasmigration im südlichen Randbereich des Nordostdeutschen Beckens – Untersuchungen an Flüssigkeitseinschlüssen in Kluftmineralisationen und im Werra-Anhydrit. Geol Jb A 149:169–183
Reutel C, Lüders V, Hoth P, Idiz EF (1995) Gas migration and accumulation along lineament structures – Lower Saxony Basin (NW Germany). Bol Soc Espan Min 18:205–206
Rieken R (1988) Lösungs-Zusammensetzung und Migrationsprozesse von Paläo-Fluidsystemen in Sedimentgesteinen des Nordwestdeutschen Beckens. PhD Thesis, Univ Göttingen, GAGP 37, pp 1–116
Rieken R, Gaupp R (1991) Fluideinschluß-Untersuchungen an Sandsteinen des Gasfeldes Thönse. Nds Akad Geowiss Veröfftl 6:68–99
Roedder E (1984) Fluid inclusions. Mineral Soc Am Rev Mineral 12:1–644
Schmidt Mumm A, Wolfgramm M (2004) Fluid systems and mineralisation in the North German and Polish Basin. Geofluids 4:315–328
Scholten SO (1991) The distribution of nitrogen isotopes in sediments. Geol Ultraiectina 81:1–101
Spencer RJ, Møller N, Weare JH (1990) The prediction of mineral solubilities in natural water: A chemical equilibrium model for the Na–K–Ca–Mg–Cl–SO4–H2O system at temperatures below 25°C. Geochim Cosmochim Acta 54:575–590
Stedingk K, Ehling B-C, Knoth W, Germann K, Schwab M (1995) Epigenetic mineralizing processes in the Northeastern Rhenohercynian Belt (Harz Mountains, Flechtingen-Rosslau Block). In: Pašava J, Kříbek B, Žák K (eds) Mineral Deposits: from their origin to their environmental impacts, pp 79–82
Thiéry R, Vidal J, Dubessy J (1994) Phase equilibria modelling applied to fluid inclusions. Liquid-vapour eqilibria and calculation of the molar volume in the CO2–CH4–N2system. Geochim Cosmochim Acta 58:1073–1082
Verma SP, Santoyo E (1997) New improved equations for Na/K, Na/Li and SiO2 geothermometers by outlier detection and rejection. J Volcanol Geotherm Res 79:9–23
Wolfgramm M (2002) Fluidentwicklung und Diagenese im Nordostdeutschen Becken – Petrographie, Mikrothermometrie und Geochemie stabiler Isotope. PhD thesis, Univ Halle, pp 1–170
Acknowledgements
This paper benefited significantly from reviews by Rudy Svennen (Leuven) and a (nearly) unknown reviewer of the International Journal of Sciences (Geologische Rundschau). We are indebted to EEG Berlin/Gaz de France, BEB Hannover and ExxonMobil Hannover/Celle for providing sample material. The study received financial support from the Deutsche Forschungsgesellschaft (DFG) Bonn.
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Lüders, V., Reutel, C., Hoth, P. et al. Fluid and gas migration in the North German Basin: fluid inclusion and stable isotope constraints. Int J Earth Sci (Geol Rundsch) 94, 990–1009 (2005). https://doi.org/10.1007/s00531-005-0013-2
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DOI: https://doi.org/10.1007/s00531-005-0013-2