Abstract.
Quantitative analysis by electron probe micro analysis (EPMA) is usually carried out by reference to materials of known composition (standards) but because of the low X-ray yield arising from electron bombardment of low atomic number elements there is a particular problem when analysing these elements. This paper addresses the problem by describing briefly the production and certification of reference materials for two elements, carbon and nitrogen. Cementite (Fe3C), a line compound, was chosen as a suitable material for carbon and γ′-Fe4N for nitrogen. The compounds were produced by, respectively, carburising or nitriding pure iron under carefully controlled conditions. Particular emphasis is placed on a homogeneity study, background correction methods and methodology validation using these reference materials. A linear relationship was established between the certified content of the material and zero. Certified values (6.69±k 0.13 wt% C and 5.77±k 0.094 wt% N) were assigned for the composition, where k is the coverage factor.
Similar content being viewed by others
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Saunders, S., Karduck, P. & Sloof, W. Certified Reference Materials for Micro-Analysis of Carbon and Nitrogen. Microchim. Acta 145, 209–213 (2004). https://doi.org/10.1007/s00604-003-0155-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00604-003-0155-5